• Membrane Journal
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• v.7 no.4
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• pp.191-198
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• 1997

Membrane formation mechanism by the phase inversion has been investigated in order to control the membrane morphology. It was found that finger-like structures were obtained when the heat of mixing between the solvent and non-solvent is exothermic, while sponge-like structures were obtained when they are endothermic in polystyrenes as well as in polyimides (Torlon and polyimide made frorn 3,3'4,4'-benzophenontetracarboxylic diahmydride and 1,4-phenylene diarnine) membranes. This concept was applied to control the morphology of polysulfone membranes simply by adding a solvent additive by adjusting the heat of mixing. A crude, but simple, relationship between the heat of mixing and the exchange rate of the solvent with non-solvent has been also developed.

• 한국도로학회:학술대회논문집
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• 2010.03a
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• pp.241-246
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• 2010

• Proceedings of the Korean Society of Computer Information Conference
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• 2015.01a
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• pp.289-290
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• 2015

본 연구에서는 인쇄회로기판(PCB)용 재료로 널리 사용되는 고분자에 대해서 와이블 분포 방정식의 시뮬레이션을 수행하여 절연 신뢰도 특성 데이터를 분석하였다. 와이블 분포에 대한 분석 시뮬레이션을 통하여 일반적으로 허용 절연 파괴 확률을 0.1[%] 이하라고 설정하였을 때, 첨가제 배합비를 5종으로 구분한 각 시편에 대해서 인가 전계의 허용치를 각각 계산할 수 있었다.

• Journal of Energy Engineering
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• v.7 no.2
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• pp.163-171
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• 1998

Degradation of polymer additives is enhanced at higher temperature of the test solutions. The degradation of Co-polymer solution was investigated experimentally in a closed loop at the temperature of 6$0^{\circ}C$ and 8$0^{\circ}C$ with various polymer concentrations of 100, 200, 400, 600 ppm in order to see the effect of temperature and polymer concentration with time. The degradation effect were found to be more dependent on temperature than mechanical shear. The friction factor versus Reynolds number curves show that in the range of Reynolds number number 50,000~150,000 the friction was decreased as Reynolds number increased and the friction of solution at low temperature approached to Virk's maximum drag reduction asymptote. For constant flowrates and temperatures the degradation effect was found to be less likely in higher polymer concentration. For constant flowrates and polymer concentrations the degradation rates are affected mainly by temperature. At the temperature of 8$0^{\circ}C$ and polymer concentration of 100 ppm, drag reduction effect was disappeared after 4 hours. However, this thermal degradation could be avoided with additional materials such as surfactants which are supposed to enhance the bonding forces between polymer molecules.

• Polymer(Korea)
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• v.25 no.5
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• pp.754-758
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• 2001

In order to use vesicle as a space of polymerization, monomer and cross-linking agent were put into hydrophobic part of vesicle. The vesicle solution of dimethyldioctadecylammonium bromide was formed by ultrasonication. Styrene and divinylbenzene were put into this solution and polymerization was conducted by adding AIBN. The polymer with sphere-shaped structure was obtained by removing all of the surfactant by extraction of ethanol And using methyl methacrylate and ethylene glycol dimethacrylate, this sphere-shaped polymer structure was also formed.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1989.06b
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• pp.29-34
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• 1989

고분자 복합재료들은 오늘날 광범위하게 마찰 부위들에 응용되고 있다. 다양한 첨가제와 보강재들이 고분자 물질들에 넣어져 강도와 마모 특성들을 향상 시키고 있다. 예를 들어, 다양한 복합재료들로서 현재 입수 가능한 것에 베어링 재료들이 있으며 이에 포함되는 것이 자체 윤활 보강 플라스틱 들이며 이들에는 고체 윤활제, 즉, 테플톤, $MoS_2$, 혹은 흑연가루들이 첨가된다. 실험적 그리고 이론적인 연구들이 여러 조건들에서의 섬유 보강 복합 재료들의 마모 거동에 대하여 보고되었다(예를 들어, 미끄럼 마모, 연마 마모, 입자 충격 마모, 비빔 마모). Tsukizoe와 Ohmae의 보고에 의하면 탄성계수 탄소섬유 복합재료는 가장 적은 마모가 횡단 방향(Transverse)에서 있고, 고 강도 탄소 섬유 복합재료는 길이 방향(Longitudinal)에서 있다. 가장 많은 마모는, 고 탄성계수 복합재료는 길이 방향에서, 고 강도 섬유 복합재료는 횡단 방향에서 잇다. 그들이 또한 발표한 것은 양쪽의 고 탄성계수와 고 강도 섬유 복합재료들의 수직방향(Norma)에서 눌러 불음(Seizure)가 일어났다고 한다.

• Membrane Journal
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• v.20 no.1
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• pp.13-20
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• 2010

Using poly(ethylene oxide) (PEO) as a polymer host, poly(ethylene glycol) (PEG) as a plasticizer, potassium iodide and iodine as sources of $I^-/{I_3}^-$ PEO-PEG-KI/$I_2$ polymer gel electrolytes were prepared. Based on the polymer gel electrolytes, solid-state dye-sensitized solar cell(DSSC)s were fabricated. The content of PEG in the electrolyte was changed from 0 to 85%. The electrolyte showed self-supporting form through whole range of the PEG content. As the PEG content increased, the ionic conductivity and ${I_3}^-$ diffusivity increased and the light-to electrical energy conversion efficiency increased under irradiation of 100 $mWcm^{-2}$ simulated sunlight.

• Polymer(Korea)
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• v.38 no.3
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• pp.391-396
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• 2014

Polymer microneedles can be fabricated by a micromolding method, an easy and cost-effective method. However, it is not easy to achieve uniform coating with an aqueous coating solution due to hydrophobic surface of polymer microneedles. 3-Dimensional coating polymer microneedles could deliver more than twice as much dose as in-plane metal microneedles by increasing coating area and the number of microneedles per unit area. A uniform coating was not obtained by addition of coating additives in the coating solution. The satisfied coating was achieved by treatment of surface of polymer microneedle with metal deposition and UV/ozone, and UV/ozone treatment was an ultimate surface treatment method based on biological safety. Calcein coating polymer microneedles were prepared by using UV/ozone treatment and followed dip-coating, and they delivered calcein in porcine skin successfully after 15 min of insertion.

• Polymer(Korea)
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• v.27 no.6
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• pp.576-582
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• 2003

When the halogenated flame retardant, decabromodiphenyl oxide, was added to the polypropylene/nylon blend, and was compounded with montmorillonite and compatibilizer, maleic anhydride polypropylene, the improvement of flame retardancy and mechanical properties was investigated. The degree of dispersion between polymer resin and inorganic nanoparticles was investigated, and the flame retardancy and mechanical properties was measured quantitatively. XRD results showed that the montrnorillonite was com-pletely exfoliated after polypropylen/nylon nanocomposites was mixed above twice. By compounding with montmorillonite, polypropylene/nylon blend system was overcome the deterioration of flame retardancy. The tensile strength and impact strength were slightly increased, and by compounding with montmorillonite, the additional increase in mechanical properties was obtained. Therefore, the flame retardancy of polypropylene / nylon blend was decreased by adding nylon, but by compounding with inorganic nanoparticle, improvement of the flame retardancy and mechanical properties was obtained.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06b
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• pp.223-237
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• 1996

플라스틱재료의 강도, 인성, 경직성, 탄성 등과 같은 기계적 특성을 개선시켜 주기 위해 kaoline, talc, sand, quartz 등과 같은 규산염을 첨가하여 복합재료를 만들고자 하는 연구가 상당히 활발하다. 이와 같이 다양한 규산염이 복합재료의 강화재 또는 첨가제로 사용되는 반면에, 규산염가운데 공업적으로 이용도가 가장 높은 montmorillonite는 아직도 복합재료의 강화재로 폭 넓게 이용되고 있지 못한 실정이다. 이론적으로 볼 때, 높은 분자량을 지니는 무기고분자 (예; inorganic montmorillonite)와 유기고분자 (organic polymer)를 gkadbk는 실질적인 무기-유기 결합물질의 생성이 가능할 수 있으며, 이에 대한 연구 또한 시도되고 있다. 이렇게 해서 얻게 되는 무기-유기 복합체, 즉 montmorillonite로 강화된 플라스틱 복합재료 bumper를 사용함으로써 접촉 또는 충돌시 충격완화의 효과를 가져 올 수 있어 안정성이 좋아지고, 내파괴성이 높기 때문에 비강화 플라스틱재료보다 더 오래 사용할 수 있으므로 경제성이 좋을 뿐만 아니라, 폐품의 감소로 인해 환경보호에도 일익을 담당할 수 있다. 따라서, 본 연구에서는 이러한 montmorillonite강화 플라스틱 복합체를 얻기 위해 우선 무기-유기 고분자물질의 형성이 가능한가를 조사분석하였다. 이를 위해 먼저 amontmorillonite의 층사이에서 화학반응이 수행될 수 있는 충분한 공간을 얻고자 Na-Montmorillonite 층사이의 Na+-이온을 긴 알킬사슬을 취하는 유기 양이온으로 치환시켜 주었다; 이렇게 해서 얻은 유기양이온-몬트모릴로나이트 층간화합물 (Organic cation-Montmorillonite Intercalations-complex)내에 유기 단분자 (organic monomer)를 추가적으로 삽입시킨 후, montmorilonite의 층내에서 증합반응시켜 고분자화해 줌으로써 무기고분자와 유기고분자가 서로 결합된 무기-유기고분자 결합물질을 형성하고자 하였다. X-선 및 IR-분석결과 층내에서의 유기단분자의 고분자화 반응이 성공적으로 이루어 졌음이 입증되었다.