• Proceedings of the Korean Environmental Sciences Society Conference
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• 2007.05a
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• pp.545-547
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• 2007

본 연구에서는 생체 적합성이 뛰어난 HA가 고분자와의 낮은 친화성을 개선하기 위하여 HA를 화학적으로 개질하여 고분자와의 친화성을 높이는 연구를 수행하였다. 결과에서 나타나 바와 같이 효과적으로 개환중합을 이용하여 HA를 효과적으로 개질하였고 고분자와의 복합재료에 대한 특성을 고찰 하였다.

• Composites Research
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• v.34 no.6
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• pp.357-372
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• 2021

The energy harvesting device is known to be promising as an alternative to solve the resource shortage caused by the depletion of petroleum resources. In order to overcome the limitations (environmental pollution and low mechanical properties) of piezoelectric elements capable of converting mechanical motion into electrical energy, many studies have been conducted on a polymer matrix-based composite piezoelectric energy harvesting device. In this paper, the output performance and related applications of the reported piezoelectric composites are reviewed based on the applied materials and processes. As for the piezoelectric fillers, zinc oxide, which is advantageous in terms of eco-friendliness, biocompatibility, and flexibility, as well as ceramic fillers based on lead zirconate titanate and barium titanate, were reviewed. The polymer matrix was classified into piezoelectric polymers composed of polyvinylidene fluoride and copolymers, and flexible polymers based on epoxy and polydimethylsiloxane, to discuss piezoelectric synergy of composite materials and improvement of piezoelectric output by high external force application, respectively. In addition, the effect of improving the conductivity or the mechanical properties of composite material by the application of a metal or carbon-based secondary filler on the output performance of the piezoelectric harvesting device was explained in terms of the structure of the composite material. Composite material-based piezoelectric harvesting devices, which can be applied to small electronic devices, smart sensors, and medicine with improved performance, can provide potential insights as a power source for wireless electronic devices expected to be encountered in future daily life.

• Elastomers and Composites
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• v.48 no.2
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• pp.133-140
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• 2013

Carbon fiber reinforced polymer (CFRP) composites consist of carbon fibers in a polymer matrix. Recently, CFRP composites having high thermal stability and low outgassing are finding their use in high performance materials for aerospace and electronics applications under high temperature and high vacuum conditions. Cyanate ester resin is one of the most suitable matrix resins for this purpose. In this study, proper combination of cyanate ester and catalyst, curing behavior, and cure cycle were determined by chemorheology. Optimum condition was found to be catalyst content of 100 ppm and curing temperature of $150^{\circ}C$. Thermal stability and outgassing of cured resin composition were analyzed and the results showed thermal decomposition temperature of $385^{\circ}C$ and total mass loss of 0.29%. The CFRP prepregs and subsequent composites were fabricated by predetermined resin composition and the cure condition. Tensile moduli of the composites were compared with theoretical models and the results were very consistent.

• Polymer Science and Technology
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• v.16 no.4
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• pp.447-457
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• 2005

• Polymer Science and Technology
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• v.6 no.4
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• pp.314-325
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• 1995

• Polymer Science and Technology
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• v.10 no.1
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• pp.47-54
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• 1999

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.424-432
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• 1996

The fiber reinforced thermoplastic composites(FRTP) were prepared with polypropylene fiber(PPF) as matrix and vinylon(VF), Aramid(KF) or nylon fiber(PAF) as reinforcing materials using the integrated fiber mixing apparatus. The composite sheets were prepared by compression molding and their impact and morphological properties were characterized. VF/PP system showed the maximum value in Izod impact strength, while KF/PP system showed the maximum value in high rate impact properties. Ductility Index(DI) order was VF/PP>KF/PP>PAF/PP. A maximum DI for VF/PP, 2.43, was obtained when the weight fraction of VF was 20%. The optimum amount of the reinforcing organic fiber was found to be 20~30%. As a result, it is concluded that VF/PP system has better interfacial adhesion properties than either KF/PP or PAF/PP.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.489-492
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• 2002

고분자/금속 복합재료는 현대 전자산업에 중요한 역할을 하고 있다. 그러나 이들간의 계면은 고분자의 수축 또는 계면 안정성의 저하로 인하여 박리가 일어나게 된다. 즉, 계면의 접합이 떨어지게 되면 전기 화학적인 반응이 계면에서 발생하여 드러난 금속부위는 산화되고 산소가 환원될 때 발생하는 OH기와 같은 라디칼들에 의해 금속과 고분자 사이의 결합이 파괴되어 금속표면으로부터의 고분자의 박리가 발생한다. (중략)

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.217-218
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• 2007

Aluminum 분말과 고분자를 혼합하여 고분자-금속 복합재료(polymer-metal composite)를 만들어 copper foil과 기판의 접착력을 평가하였다. Tape casting 방법을 이용하여 sheet 만들고 vacuum lamination으로 PCB(Printed Circuit Board)기판을 제조한 후 포토공정으로 peel strength pattern을 형성하였으며, 본 연구에서는 최적의 aluminum 조건을 찾기 위하여 압력, 온도, copper foil의 표면 상태와 silane 표면 코팅에 따른 aluminum-polymer복합재료의 peel strength의 변화를 확인하였다. 최적의 조건은 silane 표면 코팅 처리를 한 aluminum 분말로 $210^{\circ}C$에서 $9.7kg/cm^2$ 압력으로 matte면의 돌기 크기가 크며, 응집이 잘 되어있는 copper foil을 사용하여 13.89N의 우수한 peel strength를 구현 할 수 있었다.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.04a
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• pp.202-205
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• 2003

Investigated whether fiber orientation situation of fiber reinforcement macromolecule composition board and the fiber inclusion rate are perpendicular and horizontal direction tensile strength and some correlation. Fiber orientation situation of tensile strength of 0 direction of composition board increased changelessly by aeolotropy in isotropy. Tensile strength of 90 direction that is isotropy and tensile strength of 0 direction that is aeolotropy agreed almost. Get into aeolotropy, the reinforcement rate of fiber decreased. When load interacts for width direction of reinforcement.