• Title/Summary/Keyword: 고분자 복합소재

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Organically Modified Vermiculite-Poly(Ethylene Terephthalate) Nanocomposites (유기물로 개질한 나노점토-폴리(에틸렌 테레프탈레이트) 복합재료의 기계적 특성)

  • Hai Anh Thi Le;Yong Tae Park
    • Composites Research
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    • v.36 no.4
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    • pp.275-280
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    • 2023
  • Because polymer-based composites are lightweight and have excellent properties, their demand is growing rapidly as a way to fulfill properties that are difficult to achieve with a single material. As a result, there has been a lot of research on polymer nanocomposites, which are made by dispersing particles with a size of 1-100 nm in a polymer matrix. In addition, many nanocomposites using thermoplastic resins as matrix materials are being studied. In this study, poly(ethylene terephthalate) (PET)-based nanocomposites containing organic nanoclays modified with cetyltrimethylammonium bromide (CTAB) as interlayer materials were prepared. Among various nanoclays, vermiculite (VMT) has been studied to increase the mechanical and thermal properties of polymeric materials due to its low cost, abundant reserves and unique properties. However, the strong interlayer bonding of VMT has limited its utilization due to its poor exfoliation and dispersion performance within polymer matrices. In this study, the mechanical properties of the VMT content were confirmed by tensile tests, the dispersion of VMT particles in the PET matrix was evaluated by TEM cross-sectional images, and the nitrogen gas barrier properties were evaluated.

Study of Miscibility of Natural Silk by Molecular Dynamics Calculation of Solubility Parameter (용해도 파라미터의 분자동역학 계산을 통한 천연 실크 소재의 혼화성 연구)

  • Im, Keunan;Choi, Kang-min;Leem, Jung Woo;Kim, Young L.;Park, Chi Hoon;Jang, Hae Nam
    • Membrane Journal
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    • v.31 no.2
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    • pp.153-159
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    • 2021
  • In recent years, polymer membranes, which are actively used in various industrial fields, have the advantage of being able to impart unique properties through the control of chemical structures and physical properties in the film-fabrication process, as well as through fabricating blend membranes mixed with various materials. In this study, the solubility parameter, which can be used as an index of miscibility with other materials, was calculated using molecular dynamics using a silkworm (Bombyx mori) silk polymer which has a wide potential to be used as an eco-friendly natural material. When the solubility parameter of polyvinylalcohol (PVA), which is also environmentally friendly and biocompatible, was calculated by molecular dynamics and compared with each other, it was confirmed that the two polymer materials had similar solubility parameter values. In conclusion, it was theoretically proved that the two polymers could blend well with each other, which was confirmed through experiments.

Evaluation of Yield Surfaces of Epoxy Polymers Considering the Influence of Crosslinking Ratio: A Molecular Dynamics Study (분자동역학 해석 기반 가교율에 따른 에폭시 폴리머의 항복 표면 형상 평가)

  • Jinyoung Kim;Hyungbum Park
    • Composites Research
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    • v.36 no.5
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    • pp.369-376
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    • 2023
  • This study focuses on investigating the influence of epoxy polymer crosslinking density, a crucial aspect in composite material matrices, on the yield surface using molecular dynamics simulations. Our approach involved generating epoxy models with diverse crosslinking densities and subjecting them to both uniaxial and multiaxial deformation simulations, accounting for the elasto-plastic deformation behaviors. Through this, we obtained key mechanical parameters including elastic modulus, yield point, and strain hardening coefficient, all correlated with crosslinking conversion ratios. A particularly noteworthy finding is the rapid expansion of the yield surface in the biaxial compression region with increasing crosslinking ratios, compared to the uniaxial tensile region. This unique behavior led to observable yield surface variations, indicating a significant pressure-dependent relationship of the yield surface considering plastic strain and crosslinking conversion ratio. These results contribute to a deeper understanding of the complex interplay between crosslinking density and plastic mechanical response, especially in the aspect of multiaxial deformation behaviors.

Fabrication and Mechanical Properties of Carbon Fiber Reinforced Polymer Composites with Functionalized Graphene Nanoplatelets (기능기화 된 그래핀 나노플레이틀릿이 첨가 된 탄소섬유 강화 고분자 복합소재의 제조 및 기계적 특성 연구)

  • Cha, Jaemin;Kim, Jun Hui;Ryu, Ho Jin;Hong, Soon H.
    • Composites Research
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    • v.30 no.5
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    • pp.316-322
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    • 2017
  • Carbon fiber is a material with excellent mechanical, electrical and thermal properties, which is widely used as a composite material made of a polymer matrix. However, this composite material has a weak point of interlaminar delamination due to weak interfacial bond with polymer matrix compared with high strength and elasticity of carbon fiber. In order to solve this problem, it is essential to use reinforcements. Due to excellent mechanical properties, graphene have been expected to have large improvement in physical properties as a reinforcing material. However, the aggregation of graphene and the weak interfacial bonding have resulted in failure to properly implement reinforcement effect. In order to solve this problems, dispersibility will be improved. In this study, functionalization of graphene nanoplatelet was proceeded with melamine and mixed with epoxy polymer matrix. The carbon fiber reinforced polymer composites were fabricated using the prepared graphene nanoplatelet/epoxy and flexural properties and interlaminar shear strength were measured. As a result, it was confirmed that the dispersibility of graphene nanoplatelet was improved and the mechanical properties of the composite material were increased.

Gas Transport Behavior of Modified Carbon Nanotubes/Hydrogel Composite Membranes (개질된 탄소나노튜브/하이드로겔 복합막의 기체 투과 특성)

  • Yoon, Hee Wook;Lee, Hee Dae;Park, Ho Bum
    • Membrane Journal
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    • v.23 no.5
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    • pp.375-383
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    • 2013
  • Nanomaterials having large surface area, uniform dimensions or pores can be utilized in various membrane applications Amongst them, many studies have been focused on nanocarbon materials: graphene, graphene oxide and carbon nanotubes. Carbon nanotubes, one-dimensional structure, have excellent characteristics in thermal, chemical and mechanical strength properties. However, carbon nanotubes was mainly used to reinforce mechanical properties of polymer materials in previous applications. In contrast to previous studies, we focused on modified carbon nanotubes/polyethylene glycol diacrylate (PEGDA) composite membrane preparation for improvement of permeability and selectivity on gas separation.

복합 Filler 충진 전기전도성 폴리머 소재

  • 강영구;송종혁
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.11a
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    • pp.29-33
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    • 2002
  • 산업의 고도화에 따라 반도체를 비롯한 전자산업의 발전과 더불어 전자파의 인체 유해성에 대한 EMI 규제가 더욱 강화되고 있으며 반도체 소자나 정밀기기의 ESD 기술이 요구되고 있다. 따라서 전기전도성 고분자는 유해전자파의 차폐나 정전기 방지를 위한 특수용도의 소재로 각광받고 있으며 그 수요가 급증하고 있다.(중략)

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