• Resources Recycling
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• v.5 no.3
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• pp.3-8
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• 1996

The settling charaderist~aU I flocculation of Dae-mynng kaolin were studicd by measurrng the electropharetic mnhilbty and the light transmittance of suspensions with various concentrations of floccul;mnts, hydragcn inn and ~ I ~ c t r ~ l y t e s . Isoelectric points of kaolin occurred at pH 3.2. The fine particle cnagulation of kaolin \\'as achieved must cffcctivcly a1 the isoelcctric points. The optinurn flocculation of Accofloc was occurred when thc concentration w;o 4 ppm. and thc coagulation became greater in thc order of an~onic,n al>~aniacn d catiomc. The flocculation of Accofloc(C-4S2) \\,as more effective lhan that of Superfloc(C-577) No cffeectiveness was found whcn NaCl was added, hut flocculations oi nonionic and anionic were more effective when NaCl and flacculants werc added.

• Resources Recycling
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• v.4 no.1
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• pp.20-24
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• 1995

When the slurry of water and coal which is produced from hydraulic coal mining was dehydrated by COM(Coal Oil Mixtue), the effects of flocculant were measured by light transmittance of supernatant liquid, The experimental results obtamed m this study are summarized as follows; The efficient flocculant is anionic flocculant(AllO), and in this case, the required concentration is about l00g/t. When diesel oil is used with flocculant, COM is formed in lower impeller speed than when only diesel oil is used. The amout of diesel oil required to form COM is 10% of that of coal.

• Proceedings of the KAIS Fall Conference
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• 2008.05a
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• pp.369-371
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• 2008

본 논문은 철강공장의 냉각수 처리 시스템에서 고로 집진수를 대상으로 한 응집교반실험을 실시한 결과, 주기적인 관 갱생작업(산세척)과 분산제의 주입이 필요하며, 음이온 고분자응집제에 양이온 고분자응집제를 첨가하여 사용할 경우에 탁도 제거측면에서 우수하였다. 급속교반 후 완속교반을 적용할 경우 급속교반 후 침전보다 탁도 제어 효과가 더 우수한 것으로 관찰되었으므로, 침전지의 처리효율을 증가시키기 위해서는 급속교반과 완속교반이 동시에 필요하였다.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.2
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• pp.101-109
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• 2004

In this study, the solid-liquid separation characteristics of swine wastewater were investigated for the coagulation and dissolved air flotation (DAF). Coagulation characteristics were studied using jar-tester with the different coagulants and dosage amounts. DAF characteristics were also investigated in terms of the different flotation conditions with the raw swine wastewater, pH adjustment only, and adding coagulants. When the raw swine wastewater was coagulated with the only inorganic coagulants, the proper inorganic coagulants were founded as $FeCl_3$ > PAC > Alum orderly, and the optimal coagulant dosages were founded as $1,000mg/{\ell}$, $1,500mg/{\ell}$, $1,500mg/{\ell}$, respectively. As the raw swine wastewater was treated with the polymer coagulants, the only cationic polymer coagulant showed an effective coagulation and the optimal dosage of cationic coagulant was founded as $200mg/{\ell}$. When the different dosages of cationic polymer was added to each $500mg/{\ell}$ of the inorganic coagulants, the proper inorganic coagulants were founded as $FeCl_3$ > Alum > PAC orderly, and optimal cationic polymer dosages was founded as $25mg/{\ell}$, $25mg/{\ell}$, and $100mg/{\ell}$, respectively. Resulting from the raw swine wastewater experiments using DAF without coagulation, the proper operation conditions of DAF were set to 400% of recycling ratio, 4 atm in air dissolving tank, and under pH 3. But the raw swine wastewater was difficult to successfully operate DAF without pre-coagulation. While the DAF separation after pre-coagulation using inorganic coagulants was not accomplished due to the low intensity of the floc, DAF after pre-coagulation using both the inorganic and cationic polymer coagulants was accomplished very well. Optimal dosage of cationic polymer coagulant in case of $500mg/{\ell}$ Alum dosage was founded as $500mg/{\ell}$.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.11
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• pp.729-734
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• 2012

During chlorination processes dissolved organic nitrogen (DON) can form toxic nitrogenous disinfection byproducts and organic chloramines which have little or no bactericidal activity. DON needs to be removed before chlorination processes to reduce the formation of those products. This study investigated the removal of DON from surface water and reclaimed water by coagulation with aluminum sulfate (alum) and a cationic polymer (polyDADMAC). Removal characteristics of dissolved organic carbon (DOC) and ultraviolet absorbance at 254 nm ($UVA_{254}$) were compared with that of DON. Coagulation with alum removed DON, DOC, and $UVA_{254}$ with similar trends, but the removal of $UVA_{254}$ was highest. A dual coagulation strategy of alum and cationic polymer improved the removal of DON. Coagulation with cationic polymer alone was not effective due to its narrow range of charge neutralization. DON in reclaimed water was easier to remove than that in surface water, and higher molecular weight fraction (>10,000 Da) of DON was preferentially removed.

• Journal of Life Science
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• v.27 no.8
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• pp.930-936
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• 2017

The flocculating properties of bioflocculant Biopol32 produced by Pseudomonas sp. GP32 were investigated for application in industrial wastewater treatment. The major flocculating substance of bioflocculant Biopol32 was identified as polysaccharide. Many anionic flocculants need a counter ion to induce higher flocculating activity. The flocculating activity of bioflocculant Biopol32 was markedly increased by the addition of cationic ions ($Ca^{2+}$, $Al^{3+}$). The flocculating activity of bioflocculant Biopol32 was the most effective when 7.0 mM $CaCl_2{\cdot}2H_2O$ as coflocculant was added. The flocculating activity on the effect of pH and the temperature of the bioflocculant Biopol32 was compared with anionic commercial flocculant (polyacrylamide) and bioflocculant (zooglan from Zoogloea ramigera). In kaolin suspension, the highest flocculating activity was obtained at the bioflocculant Biopol32 concentration of 1.5 mg/l. A high flocculating activity was observed in the pH range of 5.0 to 8.0. The flocculating activity of bioflocculant Biopol32 was sustained up to $60^{\circ}C$, but decreased rapidly at over $70^{\circ}C$. In the batch culture, the charge density of bioflocculant Biopol32 was compared with flocculating activity. The larger the anionic charge density and apparent viscosity of bioflocculant Biopol32, the higher the flocculating activity. Therefore, we confirmed that the flocculating activity and apparent viscosity of bioflocculant Biopol32 was closely related to the charge density of bioflocculant Biopol32.

• Korean Journal of Environmental Agriculture
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• v.18 no.4
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• pp.316-320
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• 1999

The purpose of this research was to estimate dewatering characteristics of generating water treatment plant by dewatering velocity, suitable polymer and mixing condition. Zeta potential of sludge in storage tank was negative and in case of adding cation, anion and nonion polymer for sludge conditioning, specific resistance coefficients of conditioned sludge were similar at zeta potential -5㎷. But above zeta potential -15㎷, canon polymer was more effective than others for reduction of specific resistance coefficients. Using of cation acrylate polymer showed better dewatering coefficients than cation methacrylate polymer.

• Polymer(Korea)
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• v.27 no.6
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• pp.596-602
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• 2003

A Polymeric emulsifier was synthesized by solution polymerization with 2-ethylhexyl acrylate, n-butyl acrylate, and acrylic acid. A series of polymeric emulsifier have been used in the emulsion copolymerization of 2-ethylhexyl actryacrylate and n-butyl acrylate. The size of the synthesized latex particles was around 145 nm and its distribution was very narrow. Emulsion with polymeric emusifier showed no coagulum after 7 cycles of freeze-thaw test, while the emulsion with traditional emulsifier exhibited coagulum after 2 cycles. The adhesion tests showed that the initial tackiness and peel strength decreased as the molecular weight and acrylic acid content of polymeric emulsifier increased, whereas the holding power increased.

• Environmental engineer
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• s.20
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• pp.22-23
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• 1988

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.542-547
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• 1998

Polyamine type polymer flocculants were synthesized and their characterization, viscosity and flocculation studies were conducted. In order to increase the molecular weight of polyamine flocculant which was prepared by polycondensation reaction from dimethylamine and epichlorohydrin, a small amount of 1,6-hexanediamine was employed. The incorporation of 1,6-hexanediamine up to 5.5 mole % replacing corresponding part of dimethylamine gave a branched type polyamine sample with increased intrinsic viscosity ([${\eta}$]=0.46 in 1 wt % aqueous NaCl solution). The amount of 1,6-hexanediamine above 5.5 mole %, however, resulted in gelation during polymerization. Utilizing raw water from Maegok potable water treatment plant, it was found that the addition of polyamine flocculant at a concentration of 1 mg/L level could reduce the amount of polyaluminum chloride (PAC) inorganic flocculant by half (15 mg/L). It was also observed that the incoporation of polyamine flocculant at 1 mg/L level was effective in the higher pH raw water, while PAC inorganic flocculating agent alone was not effective.