• The tire
• /
• s.14
• /
• pp.26-30
• /
• 1968

본장에서는 전호에서 논술한 Carbon black을 제외한 각종 고무용보강제, 무기보진제 및 착색제를 해설키로 한다. 논제에서는 세가지 배합제로 분류하였으나 편의상 이들 세가지 배하제를 보진제란 한 어휘로 표현하였다.

• Elastomers and Composites
• /
• v.33 no.4
• /
• pp.231-237
• /
• 1998

In order to investigate the physical properties of rubber blend compound, this experiment was carried out on the cure rate, loss tangent, reinforcement and abrasion properties of S-SBR (solution styrene-butadiene rubber) blends containing silane coupled silica and E-SBR (emulsion styrene-butadiene rubber) blends containing carbon black as a model compound. E-SBR blend showed the highest total bound rubber(TBR), while S-SBR blends showed constant TBR level regardless of rubber type. Rapid cure rate was achieved when the styrene and vinyl content of rubber microstructure decreased and TBR content of rubber compounds increased. The modulus as the index of rubber reinforcement showed the linear relation with TBR content. The large amount of PICO loss was observed when the styrene and vinyl content of rubber microstructure increased, while the small amount of PICO loss was observed when the ratio of bu-tadiene increased in the S-SBR blends with silane copuled silica. The high loss tangent at $0^{\circ}C$, the low loss tangent at $60^{\circ}C$, and the large difference of loss tangent were shown in the S-SBR blends with high styrene content compared to E-SBR blend.

• Elastomers and Composites
• /
• v.45 no.3
• /
• pp.223-229
• /
• 2010

We investigated the effects of processing geometry of silica-filled isobutylene-isoprene rubber (IIR) compounds on its mechanical properties and silica dispersion, using a two roll mill and an internal mixer (banbury mixer). The compound processed with the two roll mill showed the longer induction time ($t_2$), higher maximum torque ($T_{max}$), and better silica dispersion than the compound processed with the internal mixer; however, showed slightly the lower cure index ($t_{90}$). The mechanical properties (hardness, 300% modulus, tensile strength, elongation) of the compound processed with two roll mill were higher than compound done with the internal mixer.

• Elastomers and Composites
• /
• v.31 no.5
• /
• pp.347-352
• /
• 1996

A natural rubber was blended with a butadiene rubber with different ratios. A natural rubber, along with three different blends, its ratio varying from 10 to 15 to 20 weight %, were prepared and tested. It was found that inclusion of the butadiene rubber increased cure time, compared to the natural rubber. It is speculated that increased free volume due to the inclusion of butadiene rubber contributed to this effect. Furthermore, inclusion of butadiene rubber led to increase hardness of a sphere, and as a result, the extent of rebound increased sharply.

• Elastomers and Composites
• /
• v.14 no.3
• /
• pp.161-168
• /
• 1979

이 논문(論文)의 목적(目的)은 열적안정성(熱的安定性) 및 내노화성면(耐老化性面)에 있어서 디엔제3성분단위체(第三成分單位體)(diene termonomer)의 각각(各各)의 종류(種類)가 EPDM의 중합체(重合體)의 성질(性質)에 미치는 효과(效果)를 구명(究明)하는데 있다. 제3성분단위체(第三成分單位體) 5종(種)으로 각각(各各) 다음과 같다. 즉, ethylidene norbonene(ENB), butadiene(BD), dicyclopentadiene(DCPD), methyltetrahydroindene (MTHI) 및 1,4-hexadiene(HD)이다. 이들을 써서 만든 각각(各各)의 EPDM은 동(同)몰의 불포화도(不飽和度)로 만들어졌다. 또한 가황계(加黃系)는 동일(同一)한 황/촉진제계(黃/促進劑系)를 사용(使用)하였다. ENB-EPDM이 순(純)고무배합체(配合體) 및 충전제함유배합체(充塡劑含有配合體)의 가황(加黃)에 있어서 모두 함께 가장 빠른 가황속도(加黃速度)를 보였다. HD-EPDM은 순(純)고무배합체(配合體)에서 가황속도(加黃速度)가 가장느렸으나 충전제함유배합물(充塡劑含有配合物)에서는 DCPD-EPDM보다는 발랐다. BD-EPDM을 제외(除外)한 이들 중합체(重合禮)는 거의 같은 초기가교밀도(初期架橋密度)를 갖는다. 가교밀도(架橋密度) 및 가교형(架橋型)을 분석(分析)하여 보면 BD-EPDM 쇄(鎖)에서 부타디엔 단위(單位)는 블럭을 이루고 있다. 또한 HD-EPDM은 순(純)고무가황체(加黃體) 및 충전제배합가황체(充塡劑配合加黃體)에 있어서 원가교결합(原架橋結合)의 50%가 monosulfide의 구조(構造)를 가지고있다. 이외(外)의 4종(四種)의 EPDM 폴리머는 보다 낮은 monosulfide구조를 가진다. $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 ENB 및 HD폴리머는 약(約) 65% monosulfide 가교(架橋) 및 거의 동일(同一)한 파괴에너지값$(E_b)$을 가진다. 그러나 1,4HD의 원가교(原架橋)의 monosulfide 구조함량(含量)이 보다 높다고 해서 그의 내노화성(耐老化性)이 다른 폴리머보다 더 좋다고는 생각되지 않는다. DCPD는 $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 똑같은 monosulfide가교(架橋)를 가지나 노화온도(老化溫度)가 $259^{\circ}C(500^{\circ}F)$로 높아짐에 따라 monosulfide 함량(含量)도 증가(增加)한다. $550^{\circ}F(287.7^{\circ}C)$의 노화온도(老化溫度)에서는 EPDM폴리머의 모든 가교(架橋)가 monosulfide구조가 되나 전가교밀도(全架橋密度) 및 $E_b$ (신장률(伸長率), 절단시(切斷時)의)는 대단(大端)히 낮은 것으로 나타나는데 이것은 산화(酸化)에 의한 노화(劣化)에 기인(基因)되는 것으로 보인다. 질소기류(窒素氣流)속에서의 TGA의 분석결과(分析結果)를 보면 EPDM 가황체(加黃體)는 $800\sim935^{\circ}F(427\sim502^{\circ}C)$의 온도범위(溫度範圍)에서 분해(分解)되며 공기중(空氣中)에서는 $750\sim935^{\circ}F$ 범위(範圍)에서 분해(分解)한다.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 1991.04a
• /
• pp.127-132
• /
• 1991

충격에 민감한 용기나 기계들은 운반이나 보관중에 받을 수 있는 진동충격 을 완화시키기 위해 충격 마운트를 이용하게 되며, 충격마운트는 용기나 기 계들이 허용하는 최대가속도와 이들이 취급되는 환경에 의해 적절히 선정되 어야 한다. 그러므로 내충격 설계는 최대 허용 가속도나 취급환경에 대한 사 양과 이 사양에 의한 충격 마운트의 선정, 그리고 선정된 내충격 시스템의 충격시험에 의한 오일 탬퍼의 결합용이 사용되기도 하지만 구조가 복잡하고 가격이 비싸서 대용량이 경우에만 국한되어 사용되고 있으며, 가장 경제적인 것은 방진고무를 사용한 것이다. 내충격 시스템은 일반적으로 큰 변형량을 요구하고 있으며, 방진고무의 경우 큰 변형에서는 hardening 스프링의 비선 형성을 가지고, 형상계수와 고무배합율에 따라 정적 스프링상수와 동적 스프 링상수가 큰 차이를 보이는 등, 설계상의 여러 제한이 있다. 그러나 방진고 무는 형상변화가 자유로우며 제작이 용이하기 때문에 이러한 장점을 이용하 면 저렴하고 다양한 용도의 충격마운트 제작에 효과적으로 사용될 수 있다. 본 논문에서는 원통형 콘테이너의 내충격 설계를 위해 충격사양에 의한 충 격마운트의 설계, 설계된 내충격 시스템의 충격시험에 의한 검증을 순차적으 로 실시하여, 방진고무를 이용한 충격마운트 설계기술을 제시함으로써, 이후 방진고무제품의 설계를 위한 자료 및 과정의 제정에 도움을 주고자 한다.

• Elastomers and Composites
• /
• v.36 no.4
• /
• pp.262-267
• /
• 2001

Insulating rubber gloves with antibacterial and withstand voltage properties were prepared by blending the natural rubber latex(NRL), waterborne polyurethane(PU) and 4N-chitosan. Tensile strength of rubber glove increased with increasing amount of PU, and elongation decreased. The property of withstand voltage of rubber gloves improved with increasing leaching time, and the rubber gloves showed insulating capability of 10000V at leaching time of 3 hours. Little bacteria existed after 4N-chitosan was added to rubber gloves.

• Elastomers and Composites
• /
• v.49 no.4
• /
• pp.293-304
• /
• 2014

Rubber air spring (RAS) is a special suspension device for the industries of automobile, railroad car and other transportation. A RAS serves as a spring component with the elastic effect of compression and expansion of air in a composite rubber bag. The main component of RAS is the rubber sleeve. Rubber sleeve is the composite which is made up of combination of chloroprene rubber (CR) and nylon 6 cord, and the adhesive strength between CR and nylon 6 cord is very important. In this study, considering the effects of additives in rubber sleeve, various physical properties were tested to find the optimal combination of composition and conditions. Further, in order to select the optimum orientation of the reinforcing fibers, numerical analysis was performed using the finite elements method. After assembling all components of RAS, it was mounted on an actual vehicle, and then it was tested air leakage, fatigue life and fundamental properties.

• Applied Chemistry for Engineering
• /
• v.22 no.4
• /
• pp.395-399
• /
• 2011

Material of the gasket for lithium ion battery requires the chemical resistance, the electrical insulting property, the compression set, the anti-contamination level and the low temperature resistance. We compounded ethylene propylene diene monomer (EPDM), which showed widely different solubility parameter index, with adjusting the amount of metal oxide as an activator. We did long-term test and compression set against an electrolyte with consideration for operating conditions in lithium-ion battery. In these tests, we checked the physical, chemical characteristics and the effect to lithium ion battery with different kinds of activators. In case of rubber with ZnO as an activator, through 1000 h depositing test in propylene carbonate which is one of representative solvents, we could get the satisfying characteristics and result. However, $Zn^{2+}$ had eluted in the ion elution test. So, ZnO should be limited in EPDM compound for the gasket material in lithium-ion battery.

• Elastomers and Composites
• /
• v.34 no.4
• /
• pp.341-349
• /
• 1999

In this study, heat and crack resistance of natural rubber (NR) compounds was evaluated. To prevent the effects of the crosslinking system, a conventional vulcanization system was selected, where the accelerator/sulfur ratio was fixed to 0.25. Vulcanizates containing phenylenediamine showed high tensile strength and tear strength compared to other vulcanizates because phenylenediamine can cause additional crosslinking and high dispersion In the vulcanizates. In the pure shear test, vulcanizates containing phenylenediamine showed an excellent tearing energy which was due to the irregular crack path, and showed excellent heat and crack resistance which was also due to the good dispersity of antioxidant and additional crosslinks in the rubbber vulcanizates.