• Resources Recycling
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• v.15 no.4 s.72
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• pp.27-35
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• 2006

In order to use alunite as an activator of blast furnace slag, we studied the hydration characteristics of the calcined alunite and the ground blast furnace slag. The alunite calcined at $650{\cire}C$ consists of KAl($KAl(SO_{4})_{2}$ and $Al_{2}O_{3}$. The calcined alunite reacts with $Ca(OH)_{2}$ and gypsum to form etrringite ($3CaO{\cdot}Al_{2}O_{3}{\cdot}3CaSO_{4}{\cdot}32H_{2}O$) as fellows:$2KAl(SO_{4})_{2}+2Al_{2}O_{3}+13Ca(OH)_{2}+5CaSO_{4}{\cdot}2H_{2}O+73H_{2}O{\rightarrow}3(3CaO{\cdot}Al_{2}O_{3}{\cdot}3CaSO_{4}{\cdot}32H_{2}O)+2KOH$. The $SO_{4}^{2-}$ ions from calcined alunite reacts with CaO in blast furnace slag to from gypsum, which reacts with CaO and $Al_{2}O_{3}$ to from ettringite in calcined alunite-blast furnace slag system. Therefore blast furnace slag can be activated by calcined alunite.

• Resources Recycling
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• v.18 no.3
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• pp.42-48
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• 2009

Since there are $OH^-,\;[SiO_4]^{4-}$ ion of high concentration at early hydration in the system added with activator (NaOH+$Na_2OSiO_2$) in the blast furnace slag, different from cement hydration, hydration progresses fast without induction period and forms reaction rim around the blast furnace slag grain. $0.6{\mu}m$ reaction rim was formed around the blast furnace slag grain from the 1 day of reaction period, and the thickness of reaction rim increases over the reaction time, growing to $1{\mu}m$ on the 28 days. Unreacted blast furnace slag grain deformed from angular shape to the spherical shape. Mole ratio of Ca/Si tends to decrease from inside of blast furnace slag grain to reaction rim. Difference of Ca/Si mole ratio between reaction rim and inside the blast furnace slag grain decreased and generated hydrate was a poor crystalline CSH(I) with Ca/Si mole ratio less than 1.5.

• Journal of the Korean Geotechnical Society
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• v.22 no.8
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• pp.99-106
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• 2006

In the present study, in order to clarify the effects of latent hydraulic property of granulated blast furnace slag (GBF slag) on the liquefaction, GBF slag was cured in the high temperature alkali water (adding the calcium hydroxide, pH=12, water temperature is about $30^{\circ}C$), and then the cyclic and the static tri-axial compression tests were carried out. Then the results were compared with those for Japanese standard sand of Toyoura sand and natural sand of Genkai sand. From the test results, it is clarified that the liquefaction strength of the GBF slag increases with the increase of the curing period by the hardening due to the latent hydraulic property. It is also shown that GBF slag with Dr=50% and 80% which was cured for 189 days in the fresh-water shows cohesion due to developing of latent hydraulic property. In addition, as for the liquefaction strength of GBFS during the hardening process, a linear relation between the cyclic stress ratio $R_{20}$ at the number of stress cycles Nc=20 and cohesion $C_{d}$ was observed. It is also clarified that the liquefaction strength for cured GBF slag in the high temperature alkali water is predicted by the cohesive strength or the unconfined compressive strength.

• Cement
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• s.108
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• pp.13-19
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• 1987

• Cement Symposium
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• no.15
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• pp.21-25
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• 1987

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.1
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• pp.107-113
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• 1992

This paper is the part of fundamental study considering whether the unprocessed water cooled blastfurnace slag, by-product of iron works, can be useful for some fine aggregate of mortar and concrete. The acquired results in this study show that the qualities of the water cooled blastfurnace slag produced in the state of raw material in the country in not good for using as a fine aggregate of mortar and concrete. To be used as a fine aggregate of concrete the qualities need to be improved in the process of manufacture.

• Journal of the Korean Geotechnical Society
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• v.22 no.8
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• pp.119-127
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• 2006

Granulated Blast Furnace Slag (GBFS) is produced in the manufacture process of pig-iron and shows a similar particle formation to that of natural sea sand and also shows light weight, high shear strength, well permeability, and especially has a latent hydraulic property by which GBFS is solidified with time. Therefore, when GBFS is used as a backfill material of quay or retaining walls, the increase of shear strength induced by the hardening is presumed to reduce the earth pressure and consequently the construction cost of harbor structures decreases. In this study, using the model sand box (50 cm$\times$50 cm$\times$100 cm), the model wall tests were carried out on GBFS and Toyoura standard sand, in which the resultant earth pressure, a wall friction and the earth pressure distribution at the movable wall surface were measured. In the tests, the relative density was set as Dr=25, 55 and 70% and the wall was rotated at the bottom to the active earth pressure side and followed by the passive side. The maximum horizontal displacement at the top of the wall was set as ${\pm}2mm$. By these model test results, it is clarified that the resultant earth pressure obtained by using GBFS is smaller than that of Toyoura sand, especially in the active-earth pressure.

• Resources Recycling
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• v.19 no.3
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• pp.33-44
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• 2010

In this study, the possibility of utilizing carbide lime waste, obtained from the generation of acetylene process, as a alkali activator of blast furnace slag cement was investigated. The physical and chemical analysis of the carbide lime waste was studied and three types lime waste in order to investigate behaviour as alkali activator were used. Lime wastes were added 0, 10, 20 and 30 wt.% in blast furnace slag and blast furnace slag containing lime waste were added 0, 10, 30 and 50 wt.% in OPC. As a result of analysis of hydration properties, in the case of calcium hydroxide rehydrated after heat treatment at $800^{\circ}C$, it was higher hydration rate than other specimens. For the results of compressive strength test, when lime waste passed 325 mesh sieve and rehydrated calcium hydroxide were used, it was higher compressive strength than OPC from hydration 7days. At OPC50 wt.%-BFS45 wt.%-AA5 wt.% system using lime waste of 325 mesh under, the highest compressive strength appeared.

• Resources Recycling
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• v.11 no.3
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• pp.46-59
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• 2002

• Cement Symposium
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• no.21
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• pp.38-41
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• 1993