• Title/Summary/Keyword: 계면분리

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Characteristics of Biosurfactant Producing Pseudomonas sp. Z1 (생물 계면활성제를 생산하는 Pseudomonas sp. Z1의 특성)

  • Chang, Dong-Ho;Ko, Eun-Jung;Park, Kyeong-Ryang
    • Journal of Life Science
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    • v.21 no.1
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    • pp.134-140
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    • 2011
  • One hundred forty five bacterial colonies which were able to degrade crude oil were isolated from soil samples that were contaminated with oil in the Daejon area. Among these colonies, one bacterial strain was selected for this study based on its low surface tension ability, and this selected bacterial strain was identified as Pseudomonas sp. Z1 through physiological-biochemical tests and analysis of its 16S rRNA sequence. Pseudomonas sp. Z1 showed a high resistance to antibiotics such as chloramphenicol and ampicillin, as well as heavy metals such as lithium, manganese, and barium. It was found that the optimal pH and temperature for biosurfactant production of Pseudomonas sp Z1 were pH 6.0-7.0 and $30^{\circ}C$, respectively. After ten hours of inoculation, the biosurfactant activity of the culture broth decreased rapidly, and had maximum surface tension (28 dyne/cm) after twenty-one hours incubation. The biosurfactant activity of the culture broth was also decreased up to 2% NaCl concentration.

Joining Foil-typed Pd-Cu Membranes to Collect CO2 Gas (이산화탄소 포집용 극박형 Pd-Cu 멤브레인 접합)

  • Rhewy, Gyung-Woo;Wee, So-Young;Kim, Gyeom;Lee, Chang-Ha;Baik, Il-Hyun;Park, Jin-Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1056-1063
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    • 2010
  • We present a new joining method for Pd-Cu membrane foils used as permeation tubes to collect $CO_2$. Since foils have poor mechanical strength, joining should be done at low temperatures to reduce residual stresses and without joining pressure. This contradicts the well known conditions for good contact between base materials that determines joint qualities. We selected Sn-Ag-Cu alloys that are highly reactive with Pd and Cu as a filler metal. As the filler melts at joining temperatures as low as $220{\sim}280^{\circ}C$, Pd and Cu are dissolved into the melt and react with the filler elements, which raises the melting temperature of the filler based on eutectic structures among the elements. Then, isothermal solidification progresses for the rest of the joining time. Intermetallic compounds (IMC) in the joints, one of the main factors for brittle joints, are inevitably formed. However, by optimizing both joining time and temperature, we balanced the wettability with IMC. Sealing test results confirmed that the joints are mechanically reliable during operation.

Improved Separation of Organic Explosives by Modified Micellar Electrokinetic Capillary Chromatography (Modified Micellar Electrokinetic Capillary Chromatography에 의한 폭약 성분의 분리능 향상)

  • Park, Sung-Woo;Yang, Young-Geun;Hong, Sungwook;Kim, Taek-Jae
    • Analytical Science and Technology
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    • v.10 no.5
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    • pp.325-331
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    • 1997
  • Among various CE separation methods, micellar electrokinetic capillary chromatography(MECC) method using sodium dodecylsulfate(SDS) provides rapid and accurate separation of organic explosive constituents with easy. The running buffer was composed with 2.5 mM borate and 25mM SDS(pH 8.5). Addition of 1M urea and 10% organic modifiers (acetonitrile, methanol and ethanol) improves the resolution of adjacent explosive constituents. When 15 explosive constituents were developed in MECC, most constituents were separated successively while RDX/TNB and DNN/DEP were not, and detection limits of separated compounds are in range of 1 to 4 ppm.

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Partial Purification and Characterization of the Alkaline Protease from Baccillus sp. (Bacillus sp.가 생산하는 호알카리성 Protease의 부분정제 및 특성)

  • 안장우;오태광;박용하;박관하
    • Microbiology and Biotechnology Letters
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    • v.18 no.4
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    • pp.344-351
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    • 1990
  • An alkalophilic microoganism producing a detergent-resistant alkaline protease was isolated from soil and identified as Baeiltus sp. The alkaline protease has been partially purified by ammonium sulfate fractionation, DEAE-Cellulose, CM-Cellulose and Sephdex G-100 column chromatography. The purified alkaline protease was highly active at pH 12-13 toward casein and stable at pH values from 6 to ll. The optimum temperature for the enzyme reaction was $55^{\circ}C$. The enzyme was completely inactivated by diisopropyl fluorophosphate (DFP) indicating that the enzyme was serine protease, but considerabiy stable in the presence of surface active agents.

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A Study on Emulsion Stability of O/W and W/S Emulsion according to HLB of Emulsifier (유화제의 HLB에 따른 O/W 및 W/S 에멀젼의 유화 안정성에 관한 연구)

  • Yeon, Jae Young;Shin, Bo Ram;Kim, Ta Gon;Seo, Jeong Min;Lee, Cheong Hee;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.3
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    • pp.227-236
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    • 2014
  • In this study, O/W and W/S emulsions were prepared by combining oils having different required hydrophilic lipophilic balance (HLB) values under the diverse conditions of HLB values composed of a hydrophilic surfactant and a lipophilic surfactant and their stability was investigated. Results showed that the higher the viscosity of O/W emulsions was as the lower the HLB value of emulsifier and emulsion particle showed a tendency to be a smaller and compact and stabler in centrifugal filtration. W/S emulsions also showed a similar tendency to be a smaller and compact as HLB values of emulsifier was higher and stabler in centrifugal filtration. However, the viscosity of W/S emulsion tended to get lower in HLB conditions of all emulsifiers as the time passed. This indicated that the emulsions had an unstable feature in long-term stability. In conclusion, the results showed opposite to the known theory that O/W emulsion is proper to be applied by nonionic surfactant with a high HLB value and W/S emulsion to be applied by nonionic surfactant with a low HLB value and provide useful information for the cosmetics research and related areas.

Development of Aqueous/Semi-Aqueous Cleaning Agent and its Field Application to Cleaning Process of Electronic Parts (수계/준수계 세정제의 개발 및 전자부품 세정공정 현장적용 연구)

  • Kim, Han-Seong;Cha, An-Jeong;Bae, Jae-Heum;Lee, Ha-Yeoul;Lee, Myung-Jin;Park, Byeong-Deog
    • Clean Technology
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    • v.10 no.2
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    • pp.61-72
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    • 2004
  • In this study, aqueous/semi-aqueous cleaning agents which consist of organic solvent, surfactant, cosurfactant, and water were developed by changing formulation parameters such as organic solvent type and contents, surfactant type and contents, and cosurfactant/surfactant(A/S) ratio, etc.. And physical properties and flux removal of the formulated cleaning agents have been evaluated. Also, the performance of oil-water separation from the rinse water contaminated during the cleaning process was evaluated for its recycling. The formulated cleaning agents in this work expected to have good penetration because of their low viscosity and low surface tension values of 30.2~32.5 dyne/cm. The flux removal with the terpene type cleaning agent was higher than that with hydrocarbon type cleaning agent and two commercial products (CPA(commercial product A), CPB(commercial product B)). And the performance of oil-water separation by gravity settling from the rinse water contaminated with formulated cleaning agent and soils was shown to be very good. The cleaning agents developed in this work were applied to surface mounting technology(SMT) cleaning process for manufacturing electronic parts at L electronic company. As a result, the newly developed cleaning agents showed two times better cleaning speed for removal of solder cream than the conventional ond containing ethanol and IPA(isopropyl alcohol). In addition, malodor and VOC problems generated by the previous organic cleaning agents have been solved in the manufacturing field through introduction of the non-volatile and environmental-friendly cleaning agents to the field.

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Innovative Technology for Removal of Dispersants used in Oil Spill Remediation Using the Magnetic Separation (자성 분리를 이용한 해상 유류오염제어에 사용되는 유화제를 제거하는 새로운 기술에 대한 연구)

  • Chun, Chan-Lan;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.679-688
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    • 2000
  • Dispersants, which are used to break water-in-oil emulsions and to remediate oil-spills, are another water pollutants. In this study, magnetic separation technology was applied to remove dispersants from the sea. Magnetite and maghemite were used as magnetic sorbents and SDDBS, an anionic surfactant and Triton X-100, a nonionic surfactant, were employed as dispersants. Batch experiments were undertaken to study the sorption capacity and sorption equilibrium, and water-bath experiments were conducted to simulate the real situation and to describe the recovery of magnetic particles by the permanent magnet or electromagnet. Maghemite has rather constant removal efficiency for dispersants, regardless of surfactant species. On the other hand, removal efficiency by magnetite is higher for anionic surfactant than maghemite and is higher in distilled water than in seawater which contains more ions. The sorption of dispersants to magnetite is explained by electrostatic attraction and that of maghemite is described not only by electrostatic attraction, but also by structural characteristics that provide high sorption ability and surface condition. Water bath experimental results showed that recovery efficiency of magnetic particle after sorption for dispersants is nearly 100%. It is suggested that this magnetic separation technology is an effective way of dispersant removal because of short operating time, high sorption capacity, and high recovery efficiency of sorbents.

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Thends in Membrane Contactors (분리막 접촉기의 기술 동향)

  • Lee Kew-Ho;Kim Min-Joung;Sea Bongkuk;Park You-In;Lee Ki-Sub
    • Membrane Journal
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    • v.15 no.3
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    • pp.187-197
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    • 2005
  • A membrane contactor is a device that achieves liquid/liquid or gas/liquid mass transfer without dispersion of one phase within another. This is accomplished by passing the fluids on opposite sides of a microporous membrane. This approach offers a number of important advantages over conventional dispersed phase contactors, including absence of emulsions, no flooding at high flow rates, no unloading at low flow rates, and high interfacial area. This article provides a general review of membrane contactors, including operating principles and applications.

Removal of Unburned Carbon from Fly Ash using Countercurrent Column Flotation Cell (역류형 컬럼 부선기를 이용한 석탄회정제에 관한 연구)

  • 이전언;이제군
    • Resources Recycling
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    • v.8 no.5
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    • pp.51-58
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    • 1999
  • The sbdy iwestlgaled ihc propa-ties of Lhe dust\ulcorner rrom fe~~oallomya ~~ufacturTeh. e chemical composition, cornpasitlon material, p d c l e sire md shapes of the bulk dust, sired dust and magnetically separated durl were mvesligaled. As the re\ulcornerulL, we suppose that the dust from &gh Carbon Fenama~~gunesMc anuiact~vingP rocess is not sufiicient as solulce material of Mn because of ale low Mn canlenl (13.5%) and complicaled composition mate~ial. The dust from Bug F!lter or AOD Proccss is mi~inlym ade up of 0.2-2 pm Mn30, (Hausmam~iu)p iutlde in spherical shape and thc Mn content is 63.190.The dust from Cooler of AOD Process is inninly made up of coarse Ca(O1-Or)zM. n,FeyO,, SiO, and fine Mn30d.

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Development of an Integrated Electrode-bipolar Plate Assembly with Reduced Contact Resistance for Vanadium Redox Flow Battery (바나듐 레독스 흐름전지용 접촉저항 감소 일체형 전극-분리판 조립체 개발)

  • Amanpreet Kaur;Jun Woo Lim
    • Composites Research
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    • v.37 no.3
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    • pp.190-196
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    • 2024
  • The bipolar plate is a crucial element of the vanadium redox flow battery (VRFB) as it serves as both the electrical conduit and the structural support for the cell within the VRFB stack. Although, the graphite material is primarily used for the bipolar plate due to its excellent electrical conductivity, a significant limitation of performance of the VRFB is present due to high interfacial contact resistance (ICR) arises between the electrode and bipolar plate in the cell stack. This study aims to develop an integrated electrode-bipolar plate assembly that will address the limitations of the ICR. The integrated assembly was constructed using a single carbon felt with thermoplastic and thermoset polymers utilizing hot press method. Experimental results verify that the bipolar plate assembly exhibits reduced area specific resistance (ASR) due to the continuous electrical path. Additionally, from the charge/discharge cell test results, the integrated assembly shows improved cell performance. Therefore, the developed integrated electrode-bipolar plate assembly can serve as a substitute for the conventional bipolar plate and electrode assembly.