• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2000.04a
• /
• pp.135-138
• /
• 2000

본 논문에서는 열팽창계수(CTE)가 거의 없는 카본게폭시, PZT 세라믹 박판, 그리고 열팽창계수가 큰 글래스/에폭시 층으로 이루어진 곡면형 복합재료 작동기(LIPCA)의 설계, 제작 및 성능실험에 대한 연구성과를 제시하고 있다. LIPCA의 른 요점은 기존 THUNDER의 성능을 유지하면서 이를 경량화 하기 위하여 THUNDER의 금속 층을 상대적으로 가벼운 섬유 강화 복합재료로 대체하는 것이다. 이러한 경량화 작업으로 LIPCA는 기존 THUNDER 보다 약 30~40% 정도의 무게를 감소시킬 수 있으며, 복합재료의 특성에 따라 설계의 유연성을 가질 수 있는 장점이 있다. 또한, 에폭시 수지를 사용함으로써 접착제 없이 평판 몰드에서 오토클레이브에서 177$^{\circ}C$로 경화되어, 탈형된 후 충분한 곡률을 형성하였다. 작동 성능 실험에서, LIPCA는 기존 THUNDER보다 작동변위가 향상됨을 보였다.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2002.10a
• /
• pp.183-188
• /
• 2002

Co-cured composite materials has its own characteristics, so its thermal expansion is different each other. The selection of tool material for co-cured composite part in high temperature more over $350^{circ}F$ and 50 Psi pressure have to consider part thermal expansion, size, shape, and economic aspect in production line. So it is important choose tooling material in manufacturing composite parts. We called the tool for airplane composite parts as BAJ (Bonding Assembly Jig). Composite parts are cured on the BAJ in autoclave. BAJ have to stable at high temperature over $350^{circ}F$ and 50 Psi pressure, Considering composite parts' dimensional tolerance compare to heat up in autoclave. This paper come from the results of the experiment at the composite parts production line and review other aircraft company's method for tooling This is for the engineer engaged in composite parts manufacturing.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 1999.11a
• /
• pp.44-48
• /
• 1999

섬유 강화 고분자 복합재료에서 강화재인 섬유와 매트릭스의 계면은 복합재료의 물성에 지대한 영향을 미친다. 섬유와 매트릭스의 물성 차이 즉, 탄성율, 열팽창 계수, 경화시의 수축, 결정화도 등의 차이뿐만 아니라 하중이 가해질 때 응력 집중 (stress concentration) 현상이 계면에서 일어난다[1]. 유리섬유를 강화재로 사용한 복합재료에서 유리섬유는 표면이 hydroxyl기로 덮여 있기 때문에 친수성이 매우 크고 또한 마찰이나 정전기에 의해 손상을 받기 쉬운 단점이 있다. 따라서 매트릭스 수지와의 계면 접착력을 향상시키고 제조 공정 중에 섬유를 마찰이나 정전기로부터 보호하기 위한 처리가 필요하며 이들 "sizing" 이라고 한다[2,3].고 한다[2,3].

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.953-956
• /
• 2006

Sulfate resistance of mortar specimens with or without alkali-free accelerator exposed to sulfate solutions for 360 days was investigated. Test results confirms a negative effect of alkali-free accelerator on the sulfate deterioration, irrespective of attacking sources. Based on the ASTM C1012 expansion test, the experimental findings demonstrated that higher $C_3A$ content in cement led to the higher expansion, especially in the mortar specimens with alkali-free accelerator.

• Korean Journal of Materials Research
• /
• v.6 no.11
• /
• pp.1146-1152
• /
• 1996

실제 사용시 신뢰성을 보장하기 위하여, 고온에서 장시간 동안의 시효로 인한 ACA COG(Anisotropic Conductive Chip On Glass) 접합 특성의 변화가 연구되었다. 모든 접합 시편들은 16$0^{\circ}C$에서 156시간 동안 유지되었고 시효하는 동안의 접촉저항의 변화는 감소하였다. 특히, 156시간이후, 4000개 /$\textrm{mm}^2$의 입자밀도를 가진 ACA에서는 접촉저항의 벼노하가 나타나지 않았다. 입자크기의 경우 작은 입자를 가진 ACA는 16$0^{\circ}C$에서 시효후에도 접촉저항의 변화를 보이지 않았다. 또한 4000개/$\textrm{mm}^2$ 및 5$\mu\textrm{m}$ 입자를 가진 ACA를 사용한 시편은 접합상태가 안정하였기 때문에 16$0^{\circ}C$에서도 경화수지의 팽창 및 리플로우(reflow)에 의한 영향을 받지 않았다. 따라서 이 ACA에서는 16$0^{\circ}C$에서 156시간 동안 시효한 후에도 오픈(open)이 나타나지 않았다.

• Composites Research
• /
• v.12 no.4
• /
• pp.71-78
• /
• 1999

To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.

• Journal of the Korea Institute of Building Construction
• /
• v.14 no.4
• /
• pp.308-313
• /
• 2014

Recently, for longevity of resident building, the main trend is that the change of the inside space organization of resident building from wall construction to rhamen construction, which resulted in increase in use of lightweight composite panel. Thus, in this study, authors analyzed the engineering property of oxide of magnesium depending on the magnesium chloride addition ratio. The results of this research is expected to contribute on providing a fundamental material for the surface materials of lightweight composite panel. As the result of the experiment, as fluidity increased, air content decreased and initial set and final set as the magnesium chloride addition ratio increase. In the aspect of flexural strength and compressive strength, the test specimen showed the highest strength at 40% of the magnesium chloride addition ratio. At 20% of the magnesium chloride addition ratio, the test specimen showed the lowest water absorption rate. As the magnesium chloride addition ratio increases, the expansibility tends to increase as well in the aspect of shrinkage strain. After observing microstructure, we can see hydration products in the form of needle. It appeared high flexural strength because the hydration products have mineral fibrous tissue shape, which also contribute to the cause of the expansibility.

• Journal of the Korea Institute of Building Construction
• /
• v.15 no.4
• /
• pp.359-365
• /
• 2015

Floor mortar experiences dry shrinkage by temperature and humidity difference of internal matrix with material type. Also, since floor mortar is influenced by environmental conditions during placing and curing period, cracks are likely to be occurred. In this study, it was evaluated the hardening and dry shrinkage properties of non-sintered binder based floor mortar utilizing alpha-hemihydrate gypsum which has expansibility in order to prevent crack of the floor mortar. It was applied to the construction site, and examined the effects of external environmental conditions on shrinkage deformation and cracking. Different types of slag accelerated initial and final setting in comparison with cement mortar and its compressive strength was satisfied standard compressive strength for floor mortar. Also shrinkage deformation behavior after the initial expansion exhibited a similar tendency with the cement mortar. From the field application result, no crack was found from slag mortar, and it is determined that the slag mortar has better dimensional stability than cement mortar caused by external environment conditions.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.24 no.1
• /
• pp.80-87
• /
• 2020

The purpose of this study is to investigate the physical properties and self-healing effects of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS). The EMMs with GGBFS were prepared with various polymer-binder ratios and GGBFS contents, and tested for strengths, adhesion in tension, water permeation and self-healing effects. The conclusions obtained from the test results are summarized as follows. The compressive strength of the EMMs with GGBFS is reduced with increasing polymer-binder ratios because of reduction of the degree of hardening in the EMMs, and is somewhat inferior to that of unmodified mortars. In the flexural and tensile strengths, the flexural strength of the EMMs is almost constant with increasing polymer-binder ratios. However, the tensile strength of the EMMs is gradually increased with increasing polymer-binder ratios. Regardless of the GGBFS contents, the adhesion in tension of the EMMs increases sharply with increasing polymer-binder ratios. The water permeation of the EMMs is remarkably reduced with increasing polymer-binder ratios and GGBFS contents. The self-healing effect of the hardener-free EMMs with GGBFS is improved with increasing water immersion period at a GGBFS content of 20%.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.3
• /
• pp.110-117
• /
• 2011

This study investigated possibilities for a new reducing shrinkage method of soybean oil(SO) and waste oil(WO) to compare with shrinkage reducing agent(RS) and expansion additive(EA). There was no big difference to flow, air contents, and compressive strength of plain to use SO and WO. For the reducing shrinkage performance, SO and WO was more effective than RS and EA, because their fatty acid reacted with calcium hydroxide of concrete to turn soap. For the pore distribution by porosimter, $0.01{\sim}0.1{\mu}m$ pores of SO and WO were 0 ml/g, and $10{\sim}100{\mu}m$ also remarkably lower than any others. In these results, it inferred that they filled up capillary pore and mitigated autogenous shrinkage by their saponification of their fatty acid and calcium hydroxide.