• Title/Summary/Keyword: 결합재 경화제

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A Study on Improvement of Adhesion HTPB Propellant/Liner/Insulation (HTPB계 추진제/라이너/내열재의 접착력 향상에 관한 연구)

  • Park, Sungjun;Song, Jongkwon;Park, Euiyong;Rho, Taeho;Choi, Sunghan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.4
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    • pp.92-97
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    • 2019
  • A study was conducted to improve the adhesion of propellant, liner,and insulation. Insulation was shown to be more advantageous in improving the adhesion when a barrier coat was applied compared to a bare insulation layer. It was confirmed that the adhesion strength between the insulation and the propellant improves as the thickness of the liner coating increases. The liner was cured for 24 h. If the liner is cured for a long time, it will adversely affect adhesion. Adhesion is also improved when a bonding agent is applied. As the bonding agent content increases, the adhesion improves. There is a change in the adhesive strength depending on the type of bonding agent used. HX-868 shows slightly more improved adhesion than HX-752.

Status and Future Prospect of Precast Products Using Polymer Concrete (폴리머 콘크리트 공장제품의 개발 현황 및 전망)

  • 연규석;주명기
    • Magazine of the Korea Concrete Institute
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    • v.14 no.6
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    • pp.49-54
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    • 2002
  • 아직까지 우리나라에서 폴리머 시멘트 콘크리트가 콘크리트와 같이 광범위하게 사용되고 있는 것은 아니지만 건설재료로서의 사용이 증가하는 추세에 있다. 폴리머 콘크리트의 제조에는 결합재로서 물이나 시멘트가 전혀 사용되지 않고 수지(resin)만을 사용한다. 각종 수지가운데 많이 이용되고 있는 것은 에폭시 수지, 불포화 폴리에스테르 수지, 우레탄 수지, 퓨란 수지 등이 있다. 그러나 원료사정이 국가마다 다르기 때문에 폴리머 콘크리트의 결합재로 사용되는 액상수지 역시 차이가 있다. 우리나라의 경우는 에폭시수지, 불포화 폴리에스테르 수지 및 우레탄 수지가 주로 사용되고 있으며, 가까운 일본의 경우는 폴리머 콘크리트의 결합재로서 워커 빌리티, 저온경화성, 내후성 등이 우수한 메타크릴산 메틸도 사용되고 있다. 또한 폴리머 모르타르 및 콘크리트의 경화반응에 방해를 주지 않도록 충전재 및 골재 등은 건조시켜 함수율이 0.5 % 이하가 되도록 사용하고 있으나, 지금은 흡수제, 가교제 등의 혼화재료가 개발되어 함수율을 3% 까지 허용하고 있으며, 지금까지 불가능하게 생각되었던 폴리머 콘크리트에 대한 레디믹스트 콘크리트(레미콘) 개발도 흥미를 끌고 있다.(중략)

Setting Behavior of Polystyrene Mortars with Elapsed Curing Time (폴리스티렌 모르타르의 양생재령에 따른 경화거동)

  • Choi Nak-Woon;Kim Han-Sang
    • Journal of the Korea Concrete Institute
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    • v.16 no.1 s.79
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    • pp.54-60
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    • 2004
  • This study deals with the setting behavior of polystyrene mortars using waste expanded polystyrene(EPS) solution-based binders. The binders for polystyrene mortars are made by mixing crosslinking agent with EPS solutions prepared by dissolving EPS in styrene. Polystyrene mortars are prepared with various EPS concentrations of EPS solutions and crosslinking agent contents, subjected to a dry curing, and tested for working life, peak exotherm temperature and 10h-length change. From the test results, He working lives of polystyrene mortars are shortened with raising EPS concentration of EPS solution and crosslinking agent content. Low-shrinkage or non-shrinkage polystyrene mortars could be obtained by adjusting EPS concentration of EPS solution and crosslinking agent content.

Evaluation of Physical Properties according to Mixing Ratio and the Survey of the Current Situation for Epoxy Resin used in Conservation (문화재 보존처리에 사용되는 에폭시수지의 사용현황과 배합비율에 따른 물성 변화 연구)

  • Lee, Eun Ji;Jang, Sung Yoon
    • Journal of Conservation Science
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    • v.32 no.2
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    • pp.223-234
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    • 2016
  • Two-component epoxy resin is widely used in the cultural heritage restoration field. However according to mixing ratio of resin and hardener, curing property, mechanical strength and chemical structure differ which have possibility to effect the stability of cultural heritage. Result of questionnaire survey shows hands-on workers in the conservation field tend to mix the epoxy resin with his or her eye measurement when the using amount is small or mix additional hardener to shorten the pot life of epoxy resin. This research aims to analyze the curing property, mechanical strength and chemical structure of rapid curing type epoxy resin and medium curing type one depending on relative ratio of 0.25~4 of hardener to resin. When the amount of hardener was 0.5~2 times more than the resin, exothermic heat and curing speed were both increased. In case of included hardener to resin was lower than official ratio, mechanical strength (tensile shear strength, tensile strength and compressive strength) became higher along with active cross-linking bonding of the epoxy resin. Medium curing type epoxy relatively had lower exothermic heat and slower reaction during curing process. It was observed to be put to definite point of mechanical strength under lower content of hardener than official ratio. While, hardener ratio more than twice the resin slowed down the curing greatly and lowered the adhesion strength also. In conclusion, under the lower mixing rate of hardener than official ratio would show relatively fast reaction with similar mechanical strength. Over the official ratio on the other hand, material property drops rapidly. Accordingly, mixing ratio of epoxy resin is expected to be influential to the stability of cultural heritage.

Properties of Fresh Polymer Concretes Using Mixed Waste Plastics (복합 재질 폐플라스틱을 재활용한 폴리머콘크리트의 경화 전 성질)

  • Joo, Myung-Ki;Lee, Youn-Su;Kim, Moon-Chan;Kim, Youn-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.117-124
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    • 2006
  • The effects of binder content and recycling mixed waste plastics(PA) content on the workability, work life and hardening shrinkage of fresh polymer concrete using mixed waste plastics are examined. As a result, the workability of the polymer concretes using mixed waste plastics tend to improve with increasing binder content, PA content and filler content. The work life of the polymer concretes using mixed waste plastics is shortened with an increase in the initiator content and curing temperature. The length change of the polymer concretes using mixed waste plastics tend to increased with Increasing binder content and PA content. The result of the present research is expected to make a contribution to the recycling of final mixed waste plastics and the continuing efforts for the development of use of the recycled products are thought to expand the horizon for the recycling of the final mixed waste plastics.

Hot Water Resistance of Polymer Mortar Composites Depending on Unsaturated Polyester Resin Types (불포화폴리에스테르 수지의 형태에 따른 폴리머 모르타르 복합재료의 내열수성)

  • Hwang, Eui-Hwan;Song, Min-Kyu;Kim, Yong-Yeon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.201-208
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    • 2018
  • The ortho- and iso- type unsaturated polyester resins were synthesized and used as a polymer binder of the polymer mortar composite. Styrene monomer and acrylonitrile were used as a diluent for the unsaturated polyester resin. Methyl ethyl ketone peroxide (MEKPO) and cobalt octoate (CoOc) were used as a curing agent and an accelerator, respectively. Four kinds of unsaturated polyester resins were prepared according to types of the resin and diluent, and used as a polymer binder in the preparation of the specimen. A total of 16 polymer mortar specimens were prepared according to the added amount of the polymer binder and subjected to a hot water resistance test, followed by compressive and flexural strength tests, and pore and SEM analyses. As a result, it was found that the strength of the specimen using the iso-type unsaturated polyester resin as the polymer binder was better than that of using the ortho-type unsaturated polyester resin. The total pore volume and diameter measured after the hot water resistance test were reduced compared to the values before the test. In the micrographs observed before the hot water resistance test, the polymer binder, filler and fine aggregate were firmly combined to the co-matrix, but the polymer binder was mostly decomposed in the micrographs observed after the test.

Study on the Preparation of the Phosphoric Flame retardent for the EMC (EMC용 반응형 인계 난연 수지 개발)

  • Ahn, Tae-Kwang;Kim, Han-Byung;Ryu, Kum-Sook
    • Proceedings of the KAIS Fall Conference
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    • 2009.05a
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    • pp.372-375
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    • 2009
  • 반도체 봉지재란 실리콘 칩, 골드와이어, 리드프레임 등의 반도체 소지를 열, 수분, 충격으로부터 보호하기 위해 밀봉하는 재료로서 EMC(Epoxy Moding Compound)가 가장 많이 쓰인다. EMC는 기계적, 전기적 성능향상을 위한 무기재료로 실리카(Silica), 열에 의해 경화되어 3차원 경화구조를 형성하는 에폭시수지, 빠른 경화특성을 부여하기 위한 경화제로서의 페놀수지, 유기재료와 무기재료 사이의 결합력을 높이기 위해 커플링제, 카본블랙, 이형성 확보를 위한 왁스(Wax), 착색제(Colorant), 난연제(Flame Retardant)등의 첨가제로 구성되는 복합소재로써 본 연구에서는 에폭시의 유형에 따른 용융 실리카를 주충진재로 하여 각각의 봉지재의 첨가제를 기준으로 할 때 다양한 형태의 친환경 비할로겐계 반응형 난연제를 합성하는 기술을 개발하고 비 할로겐계 및 Sb 계 첨가형 난연제의 혼용 배합을 통해 친환경 EMC용 난연제의 제조기술을 개발하였다. 이들 EMC의 요구특성은 요구특성은 외부환경으로부터 칩 보호, 칩을 전기적으로 절연특성 유지, 칩의 작동시 발생되는 열의 효과적인 방출 특성 유지, 실장(Board Mounting)의 간편성 특성을 확보해야 하는 특성을 지니고 있어 이들 요구특성에 적합한 특성조사가 함께 이루어졌다.

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Suggesting Optimum Mix Proportion of Hardener for Soil-pavement Concrete Incorporating Natural Organic Lime and Magnesia-lime (천연유기석회 및 고토석회를 조합한 흙 포장 콘크리트용 경화재의 최적배합안 도출)

  • Han, Min-Cheol;Han, Jun-Hui
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.2
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    • pp.113-121
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    • 2020
  • Lots of soil-pavement concrete placed showed a number of problems such as decreasing strength, and durability. In this research, to provide a solution of the problem reported the wasting materials of natural organic lime and magnesia lime were used as a hardener to achieve sufficient performance of soil-pavement concrete. Namely, as a stimulus of blast furnace slag, the natural organic lime and magnesia lime were tested within the mix proportion of 0 to 10 % for each lime to make a new hardener. As a result, in the case of mortar with 1 to 3 % of cement to fine aggregate, 30 % replaced blast furnace slag showed the more favorable results with 5 to 5 % of mix proportion for natural organic lime and magnesia lime.

Manufacture of Artificial stone using Wasts Stone and Powder Sludge (폐석 및 석분 슬러지를 활용한 인조석판재의 제조)

  • 손정수;김병규;김치권
    • Resources Recycling
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    • v.4 no.1
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    • pp.4-11
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    • 1995
  • The amounts of waste stone and stone powder sludge that occurred in the quarry and processing plant of s stone plates, have been increased with the development of stone industry. The manufactunng process of 따tificial s stone was studied to reduce the outlet of these wastes and utilIze them as raw materials for architecture, interior decoration and art work. In order to compare the properties of artiflcial stone with those of natural building-stone, the physi$\alpha$II properties of artificial stone such as specific gravity, absorption ratio, elastic wave velocity, compressive s strength, tensile strength, shore hardness, elasticity and Poission's ratio were measured. From the mesaured d data of physical properties, it was found that physical propertIes of artificial stone were controlled by homogeneous m mixing ratio of constituents, molding pressure, and amount of binder. Also, from the thermo-gravimetric analysis, it was found that artIfIcial stone manufactured had a good thermal stability up to $300^{\circ}C$. It was concluded that t the optimum conditions for manufacturing process of artificial stone were $200kg/\textrm{cm}^2$ of molding pressure, 12-15 w weight % of binder amounts.

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Preliminary Study for the Development of Alkali Activated Natural Hwangtoh Binder (알칼리활성 천연황토 결합제 개발을 위한 기초연구)

  • Kim, Baek-Joong;Kim, Jun-Hwan;Yi, Chong-Ku;Kang, Kyung-In
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.389-390
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    • 2010
  • this study is preliminary experimental research for develop methods to utilize the natural Hwangtoh as replacement materials for the cement in concrete, via alkali activation at $60^{\circ}C$ using NaOH solution and liquefied $Na_2SiO_3$ in a manufacture process of Hwangtoh concrete binder.

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