• Title/Summary/Keyword: 결정입자 변화

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Distribution of Nitrogen Components in Seawater Overlying the Gomso Tidal Flat (곰소만 조간대 해수 내 질소 성분의 시공간적인 분포)

  • 양재삼;김기현;김영태
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.3
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    • pp.251-261
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    • 2003
  • As a part of an on-going project investigating flux of materials in Gomso Tidal Flat, we have monitored temporal and spatial distribution of nitrogen components(TN, PON, DON, DIN) and have sought the relationships with the freshwater input(tidal range, salinity), the biological activities(chlorophyll-${\alpha}$, TP, DIP, silicate) and the resuspended bottom sediment in seawater(SPM) from 1999 to 2000. TN in seawater was 39.05 $\mu\textrm{m}$ol 1$\^$-1/ (31.03∼42.93 $\mu\textrm{m}$ol 1$\^$-1/) without any statistical difference(p<0.05) between the studied periods. Organic nitrogen (DON and PON) occupied 75%, 95%, 73%, and 75% in April, August, September and November, respectively. DON and PON have been found within the narrow concentration ranges of 11.30∼16.38 $\mu\textrm{m}$ol 1$\^$-1/ and 13.16∼20.04 $\mu\textrm{m}$ol 1$\^$-1/ in spite of severe environmental differences through the studied periods. Dissolved fractions of nitrogen(DON and DIN) occupied 53∼65% of TN. Only DIN varied with an evident temporal variability: low concentrations(1.325∼1.616 $\mu\textrm{m}$ol 1$\^$-1/) in August and high enrichment(8.377∼14.65 $\mu\textrm{m}$ol 1$\^$-1/) in September. High consumption rate of DIN by phytoplankton and a long-lasted drought probably induced such low concentration of DIN in August. Eventually heavy precipitation probably introduced plenty of new nitrogen sources into Gomso Bay in September. The portion of PON, DON and DIN in the total nitrogen was 40%, 38% and 22%, respectively. Their contents were in the order of DON>PON>DIN for the year round except PON>DON>DIN only in September. The highest DON portion in August probably due to the active microbial decomposition of organic material in summer. Only in April, some evident negative correlations have been found between chlorophyll-${\alpha}$ and DIN mostly nitrate(-0.64, p<0.01), phosphate(-0.46, p<0.01) and silicate(-0.55, p<0.01). The Si(OH)$_4$/DIN/DIP ratios in the water column suggests the limitation of DIN for the growth of phytoplankton during the dry summer in Gomso Bay, which was the case of August in this work. Even with some difference between the studied periods, the primary factors on the distribution of nitrogen components in seawater overlying the Gomso Tidal Flat have been the tidal range and the freshwater input, but the additional variations were due to the biological activities.

Deformation Characteristics of Zircaloy-4 Fuel Cladding due to Oxidation in Environment of High Temperature and Steam (고온, 수증기 속에서 산화된 질칼로이-4 핵연료 피복관의 변형 특성에 관한 연구)

  • Jung, Sung-Hoon;Suh, Kyung-Soo;Kim, In-Sup
    • Nuclear Engineering and Technology
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    • v.18 no.3
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    • pp.218-227
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    • 1986
  • Studies were conducted to determine the extent of oxidation and same of the mechanical property changes of Zircaloy-4 fuel cladding after it was exposed to hot steam environment. The purpose of these tests was to provide some informations on the embrittlement behavior of CANDU type fuel cladding, which could be experienced under the loss-of-coolant accident conditions. The Zircaloy fuel cladding tubes were exposed in a steam environment at the temperature of 90$0^{\circ}C$, 1,00$0^{\circ}C$. The growth of the ZrO$_2$ layer combined with an oxygen rich $\alpha$-phase layer into the Zircaloy tube material was found as a function of time t and temperature of steam exposure, E=1.1√Dt+0.002 where D is a temperature dependent diffusion coefficient. The tensile strength of the specimens exposed for a short period increased but decreased continuously with further exposure. The circumferential elongation was drastically changed with the exposure time while the hoop strength did't decrease greatly. The X-ray measurement of preferred orientation of the Zircaloy tube material indicated that grains in the as received tube were oriented such that the poles of the basal (0001) planes were predominantly radial, while the poles of the basal plane in the tube materials heattreated at 1,00$0^{\circ}C$ were oriented tangentially. It appears that this reoriented texture may contribute to lessening the decrease of the hoop strength of the heat treated Zircaloy tube material.

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A Study on the Turbidity Estimation Model Using Data Mining Techniques in the Water Supply System (데이터마이닝 기법을 이용한 상수도 시스템 내의 탁도 예측모형 개발에 관한 연구)

  • Park, No-Suk;Kim, Soonho;Lee, Young Joo;Yoon, Sukmin
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.2
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    • pp.87-95
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    • 2016
  • Turbidity is a key indicator to the user that the 'Discolored Water' phenomenon known to be caused by corrosion of the pipeline in the water supply system. 'Discolored Water' is defined as a state with a turbidity of the degree to which the user visually be able to recognize water. Therefore, this study used data mining techniques in order to estimate turbidity changes in water supply system. Decision tree analysis was applied in data mining techniques to develop estimation models for turbidity changes in the water supply system. The pH and residual chlorine dataset was used as variables of the turbidity estimation model. As a result, the case of applying both variables(pH and residual chlorine) were shown more reasonable estimation results than models only using each variable. However, the estimation model developed in this study were shown to have underestimated predictions for the peak observed values. To overcome this disadvantage, a high-pass filter method was introduced as a pretreatment of estimation model. Modified model using high-pass filter method showed more exactly predictions for the peak observed values as well as improved prediction performance than the conventional model.

Controls on Diagenetic Mineralogy of Sandstones and Mudrocks from the Lower Hayang Group (Cretaceous) in the Daegu Area, Korea (대구 부근 하부 하양층군(백악기) 사암과 이암의 속성 광물과 속성 작용의 규제 요인)

  • Shin, Young-Sik;Choo, Chang-Oh;Lee, Yoon-Jong;Lee, Yong-Tae;Koh, In-Seok
    • Journal of the Korean earth science society
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    • v.23 no.7
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    • pp.575-586
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    • 2002
  • Authigenic minerals found in sandstones and mudrocks of the Lower Hayang Group (Cretaceous) in the central part of the Kyungsang Basin are carbonate minerals (calcite, dolomite), clay minerals (illite, chlorite, C/S, I/S and kaolinite), albite, quartz and hematite. Characteristic diagenetic mineral assemblages are as follows: albite-chlorite (including C/S)-hematite in the Chilgog Formation, albite-illite-calcite in the Silla Conglomerate, illite-chlorite-hematite in the Haman Formation and albite-chlorite-dolomite in the Panyawol Formation, respectively. Among clay minerals reflecting the physical and chemical change of the diagenetic process, illite, the dominant clay mineral, occurs in every formation in the study area. Chlorite occurs mainly in green or gray sandstones and mudrocks, or in sandstones and mudrocks of the Chilogok Formation which contains a high content of volcanic materials. Based on the mineral assemblage, diagenetic minerals are strongly related with source rocks. Judging from the illite crystallinity, diagenesis of sandstones and mudrocks in the study area reached the late diagenetic stage or low grade metamorphisim. The diagenetic process was much influenced by intrusion of the Bulguksa granite, content of organic materials, grain size, and depositional environment rather than burial depth.

Fabrication of Honeycomb Adsorbents by Using the Ceramic Paper and Adsorption Characteristics of VOC (세라믹섬유지를 사용한 허니컴 흡착소자 제조 및 VOC 흡착특성)

  • Yoo, Yoon-Jong;Cho, Churl-Hee;Kim, Hong-Soo;Ahn, Young-Soo;Han, Moon-Hee;Jang, Gun-Eik
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1035-1041
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    • 2002
  • The adhesion characteristics of adsorbent during impregnation of Y-type and ZSM-5type zeolites into ceramic paper were analyzed, as the amount of silica sol in slurry for impregnation was varied. 31 wt% of zeolite particle, which is useful for VOC adsorption, was evenly dispersed and adhered on ceramic paper and original crystal structure of the zeolite remained unchanged even after binder application and heat treatment. Surface area of the impregnated ceramic paper was decreased compared with that of zeolite powder. And it was found to be attributed to the reduction of volume of mesopore while the volume of micropore under $20{\AA}$ was unchanged. Zeolite-impregnated honeycomb cylinder, whose diameter and length were 10 cm and 40 cm, respectively, was subjected to adsorption/desorption test with respect to toluene, MEK, cyclohexanone. All of the VOC's were removed by adsorption with efficiency higher than 97% and from the static adsorption test, $42 Nm^3/h$ of 300 ppmv-VOC-laden air was calculated be treated continuously, when the honeycomb was used in an adsorptive rotor system.

Characterization of Transparent TiO2 Power and Thin Films through Sol-Gel Process (졸-겔법을 이용한 투과성 TiO2 분말 및 박막의 특성 연구)

  • Jung, Mie-Won;Lee, Zee-Young;Son, Hyun-Jin
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.252-258
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    • 2002
  • Transparent $TiO_2$ thin films prepared by sol-gel process using the modification of titanium(IV) alkoxide showed improved thermal stability and high refraction index. Compared to the pure $TiO_2$ film, the modified $TiO_2$ films show the increased index of refraction under proper condition at pH 2.5. Transparency of these $TiO_2$ thin films were more than 80% in the visible region. It has been demonstrated that the reaction occurs in the amorphous phase: an exchange of phase results in anatase before and after 400$^{\circ}C$, in rutile over 700$^{\circ}$C form the XRD results. The particle sizes, shapes and structures of these nanoclusters in the $TiO_2$ films have been identified through a SEM and XRD. The physical properties and structures of their powders have also been studied through a SEM, XRD, TGA and DSC. The thickness and index of refraction have been determined by the analysis of ellipsometric spectra.

Design and Construction of Multi-wire Proportional Counter and Preamplifier for Measurement of Charged Particle (하전입자의 측정을 위한 다중선 비례계수기와 전치증폭기의 설계 제작)

  • Kim, Jong-Soo;Yoon, Suk-Chull
    • Journal of Radiation Protection and Research
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    • v.21 no.2
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    • pp.139-143
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    • 1996
  • A multi-wire proportional counter with large sensitive area was designed and constructed considering diameter of anode wire. its material and space. A preamplifier connecting detector to main amplifier or counter was also designed and constructed for measurement output pulse from multi-wire proportional counter. The preamplifier was composed of charge-sensitive differential circuit. clipping circuit and amplification circuit. To test the performance of this equipment, terminal output pulse from the preamplifier was measured and compared with noise For these tests $^{239}Pu(360 Bq)\;and\; ^{90}Sr/^{90}Y(250 Bq)$ were used as radiation sources. The noise ingredient contributing to the maximum amplitude(180mV from $^{239}Pu$ and 200 mV from $^{90}Sr/^{90}Y$) was found to be very small(8 mV) Piled up pulse occurring at the output pulse of charge-sensitive differential circuit was measured as an independent pulse since this affected the amplification in the clipping circuit and amplification circuit. This information can be used to improve the loss of measurement due to piled up pulse.

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A Numerical Model for Analysis of Groundwater Flow with Heat Flow in Steady-State (열(熱)흐름을 동반(同伴)한 정상지하수(定常地下水)의 흐름해석(解析) 수치모형(數値模型))

  • Wang, Soo Kyun;Cho, Won Cheol;Lee, Won Hwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.11 no.4
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    • pp.103-112
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    • 1991
  • In this study, a numerical model was established and applied to simulate the steady-state groundwater and heat flow in an isotropic, heterogeneous, three dimensional aquifer system with uniform thermal properties and no change of state. This model was developed as an aid in screening large groundwater-flow systems as prospects for underground waste storage. Driving forces on the system are external hydrologic conditions of recharge from precipitation and fixed hydraulic head boundaries. Heat flux includes geothermal heat-flow, conduction to the land surface, advection from recharge, and advection to or from fixed-head boundaries. The model uses an iterative procedure that alternately solves the groundwater-flow and heat-flow equations, updating advective flux after solution of the groundwater-flow equation, and updating hydraulic conductivity after solution of the heat-flow equation. Dierect solution is used for each equation. Travel time is determined by particle tracking through the modeled space. Velocities within blocks are linear interpolations of velocities at block faces. Applying this model to the groundwater-flow system located in Jigyung-ri. Songla-myun, Youngil-gun. Kyungsangbuk-do, the groundwater-flow system including distribution of head, temperature and travel time and flow line, is analyzed.

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Physicochemical Properties of Sugary-Endosperm Mutants in Rice (벼 고당미 변이계통 배유의 이화학적 특성)

  • ;Mun-Hue Heu
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.39 no.1
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    • pp.1-6
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    • 1994
  • Some physicochemical properties of sugary rices were comparatively analyzed with the original cultivars, using Hwachung su-1, su-2, and Nampung su lines bred in Seoul Nat'l Univ., and EM 5 bred in Kyushu Univ. Sugary rice grains were smaller in width and thickness, and the relative dry weight of 1000 grains of sugary rices ranged from 49% to 72%, compared to normal ones. No distinct starch granules were found in endosperm of sugary rices exposured by SEM, with structural variations between Hwachung su-1 and su-2 lines. Sugary rices showed the significant increases in sucrose, glucose and fructose content, especially much higher in sucrose content showing 5.84-8.79%, in comparison with the normal ones, 1.11∼2.65%. However, sucrose and total sugar content varied within sugary lines carrying the same sugary gene, and were significantly lower in Hwachung su-2. Sugary rices, except Hwachung su-1, showed the same or lower ADV and harder gel characteristics, compared to normal ones. Protein and lipid content were much higher in sugary rices, due to the increased relative proportion of aleurone layer in brown rice caused by thicker aleurone layer than in normal rices and the reduction of endosperm part. However, there were no remarkable changes in amino acid and fatty acid compositions.

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Petrology and Geochemistry of the Cretaceous Palgongsan Granite, Southern Korea (백악기(白堊紀) 팔공산(八公山) 화강암(花崗岩)의 암석학적(岩石學的) 및 지구화학적(地球化學的) 연구(硏究))

  • Hong, Young Kook
    • Economic and Environmental Geology
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    • v.16 no.2
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    • pp.83-109
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    • 1983
  • The Cretaceous Palgongsan granite is a typical, calc-alkaline, subsolvus monzogranite and shows characteristics of "I-type" granite by mineralogy and chemical composition. Many of the major and trace element characteristics of the Palgongsan granite are consistent with a relationship by fractional crystallisation to form a chemically zoned pattern. The granite show light REE enrichment with (Ce/Yb)N ratios of 5.78-9.50. All the REE patterns show Eu negative anomalies which become larger from the margin ($Eu/Eu^*=0.75$) to the core ($Eu/Eu^*=0.24$) of the pluton, mainly due to feldspar fractionation. Mineral geochemistry (alkali-feldspar, plagioclase & biotite) studies also show the zonal structure of the Palgongsan granite. The two-feldspar geothermometer shows that the temperature difference between the margin and the core part of the pluton is about $200^{\circ}C$ at various assumed pressures.

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