• Journal of the Korean Chemical Society
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• v.32 no.3
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• pp.171-178
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• 1988

The potential energy of adsorbate molecules in the main channel of $K^+$ ion exchanged zeolite L(K-L) was calculated. In K-L which adsorbs three molecules per unit cell, the interaction energies of $H_2O,\;NH_3,\;CH_3NH_2,\;(CH_3)_2NH,\;and\;(CH_3)_3N$ molecules with zeolite lattice are 61.11, 62.31, 65.68, 74.65, and 79.88kJ/mol, respectively. These values are less by 3.7∼12.6kJ/mol than $K^+$ ion affinities with adsorbing molecules. These results may be due to the facts that the electrostatic energies are reduced by the negative charge of the lattice oxygens. The distribution of adsorption sites of $NH_3$ and $CH_3NH_2$ in K-L was investigated by a technique of temperature programmed desorption. The experimental value of desorption energies of $NH_3$ and $CH_3NH_2$ on K-L are in good agreement with the theoritical values. It is concluded that the desorption of $NH_3$ and $CH_3NH_2$ on K-L is the first-order desorption with free readsorption.

• Journal of Korea Water Resources Association
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• v.43 no.8
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• pp.747-755
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• 2010

Distributed Models have relative weak points due to the amount of computer memory and calculation time required for calculating water flow using a numerical analysis based on kinematic wave theory when compared to the conceptual models used so far. Typically, the distributed models have been mainly applied to small basins. It was necessary to decrease the resolution of the grid to make it applicable for large scale watersheds, and because it would take up too much time to calculate using a higher resolution. That has been one of the more difficult factors in applying the model for actual work. In this paper, MPI (Message Passing Interface) technique was applied to solve the problem of calculation time as it is one of the demerits of the distributed model for performing physical and complicated numerical calculations for large scale watersheds. The comparison studies were performed a single domain and a divided small domain in Yongdam Dam watershed in case of typoon 'Ewiniar' at 2006. They were compared to analyze the application effects of parallelization technique. As a result, a maximum of 10 times the amount of calculation time was saved but keeping the level of quality for discharge by using parallelization code rather than a single processor.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.4
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• pp.594-600
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• 2021

Curved beam structures are generally used as components in structures such as railroad bridges and vehicles. The stability analysis of curved beams has been studied by a large number of researchers. Due to the complexities of structural components, it is difficult to obtain an analytical solution for any boundary conditions. In order to overcome these difficulties, the differential quadrature method (DQM) has been applied for a large number of cases. In this study, DQM was used to solve the complicated partial differential equations for buckling analysis of curved beams. The governing differential equation was deduced and solved for beams subjected to uniformly distributed radial loads. Critical loads were calculated with various opening angles, boundary conditions, and parameters. The results of the DQM were compared with exact solutions for available cases, and the DQM gave outstanding accuracy even when only a small number of grid points was used. Critical loads were also calculated for the in-plane inextensional buckling of the asymmetric curved beams, and two theories were compared. The study of a beam with extensibility of the arch axis shows that the effects on the critical loads are significant.

• Journal of Environmental Impact Assessment
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• v.28 no.3
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• pp.275-286
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• 2019

In order to prevent local extinction of organisms and to preserve biodiversity, it is important to ensure connectivity between habitats. Even if the habitat is exposed to various disturbance factors, it is possible to avoid or respond to disturbances if they are linked to other habitats. Habitat connectivity can be assessed from a variety of perspectives, but the importance of functional connectivity based on species movement has been emphasized in recent years due to the development of computational capabilities and related software. Among them, Circuitscape, which is a connectivity evaluation tool, has an advantage it can provide detailed reference data for the city planning because it maps ecological flows on individual grid based on circuit theory. Therefore, in this study, the functional connectivity of Suwon was evaluated by applying Circuitscape and then, the ecological corridor to be conserved and supplemented was suggested based on it. The results of this study are expected to effectively complement the methodology related ecological corridor/axis, which was previously provided only in the form of a diagram, and to be effective in management of development project and urban planning.

• Journal of Korean Tunnelling and Underground Space Association
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• v.11 no.1
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• pp.11-22
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• 2009

Tunnel excavation with several sections and appropriate auxiliary measures such as face bolt and pre-grouting are widely used in case of weak and less rigid ground for the stability of a tunnel face during excavation. This papers first described the evaluation methods proposed in technical literature to maintain the tunnel face stable, and then studied by FEM analysis whether face reinforcement is need in what degree of ground deformation and strength features for the stability of a tunnel face when excavating by full excavation with sub-bench. Lastly, a three dimensional FEM analysis was performed to study how the tunnel face itself and the ground around the tunnel behave depending on different bolt layouts, length of bolts, number of bolts. There were relative differences in comparison of results on the stability of a tunnel face by a theoretical evaluation methods and FEM analysis, but the same in reinforced effect of face. It was found that the stability of a tunnel face can be obtained with face bolt installed longer than 1.0D (tunnel width), bolt density of about 1 bolt per every $1.5\;m^2$ (layout of grid type), and reinforcement area of $120^{\circ}$ arch area of upper section.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.31 no.6
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• pp.468-477
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• 2019

The numerical model of Boussinesq approximation, which is mainly used for evaluating the port calmness due to the irregular waves, has a limit of applicability of lattice size in ports such as marinas with narrow port openings of around 30m. The SWASH model controls the partial reflection according to the depth, porosity coefficient and structure size when applying the reflected wave incident on the structure and terrain. In this study, the partial reflection evaluation at the front of the structure according to the bottom shape and the shape of the structure are examined. In order to evaluate the reproducibility of the model due to the diffraction waves entering the term, the area of incidence at right angles and inclination of the structure is constructed and compared with the diffraction theory suggested by Goda et al. (1978). The experimental results of the sectional structure reflectances calculated as the depth mean show reflectances similar to the approximate values of the reflectances presented by Stelling and Ahrens (1981). It is considered that the reflected wave is well reproduced according to the control of the reflected wave at the boundary and the shape and topography of the structure. Compared with previous studies to examine the diffraction of the wave incident from the breakwater opening, the wave incidence angle and the shape of the diffraction wave are very similar to the theoretical values, but both oblique and rectangular incidence In the case where the direction concentration is small, the diffraction degree is underestimated in some sections with the crest ratio of 0.5 to 0.6.

• Journal of the Korean Magnetics Society
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• v.14 no.1
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• pp.46-50
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• 2004

Compounds of $Y_{3-x}Ce_{x}Fe{5}O_{12}$(x=0.0, 0.1, 0.2, and 0.3) were prepared using the sol-gel method. The XRD measurements show that these samples have only a single phase of the garnet structure regardless of the amount of Ce substitution. The lattice constants of x = 0.0 and x = 0.3 were found to be a$_0$ = 12.3758 ${\pm}$0.0005 ${\AA}$ and 12.4062 ${\pm}$0.0005 ${\AA}$, respectively. The lattice constant increases linearly with increasing Ce concentration. The saturation magnetization was not changed flirty, with increasing Ce concentration, but coercivity decreased form 18.3 Oe to 5.8 Oe as x increased form x = 0.0 to x = 0.1. Mossbauer spectra of $Y_{3-x}Ce_{x}Fe{5}O_{12}$ were measured at various absorber temperatures from 13 K to Neel temperature. The Mossbauer spectra were fitted by least-squares technique with two subpatterns of Fe sites in the structure and corresponding to the 16a and 24d site. The temperature dependence of the magnetic hyperfine field in $^{57}$/Fe nuclei at the tetrahedral 240 and octahedral 16a sites were analyzed based on the Neel theory of ferrirnagnetism. The result of the Debye temperatures indicated that the inter-atomic binding force for the 24d site was larger than that for the 16a site.