• Title/Summary/Keyword: 거동안정화

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Raman Spectroscopy and Molecular Modeling Study on the CH4 and SF6 Mixture Gas Hydrate Growth Behavior (라만 분광학과 분자모델링을 이용한 메탄 및 육불화황 혼합 가스 하이드레이트 성장 거동 연구)

  • Lim, Jun-Heok;Lee, Ju Dong;Park, Sung Soo;Eom, Ki Heon;Won, Yong Sun
    • Clean Technology
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    • v.19 no.4
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    • pp.476-480
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    • 2013
  • The growth behavior of $CH_4$ and $SF_6$ mixture gas hydrate has been investigated by a combined approach of Raman spectroscopy and molecular modeling. Raman spectroscopy results presented that when $CH_4$ is used only, $CH_4$ guest molecule is inserted first into the large cavity of the host structure built by $H_2O$ molecules and then into the small cavity to stabilize the whole gas hydrate structure. In the other hand, when $SF_6$ is mixed together, $SF_6$ is favored over (or competing with) $CH_4$ in being inserted into the large cavity and the small cavity still prefers $CH_4$ insertion. The calculations of binding energies clearly supported this. While $SF_6$ has a binding energy of -26.9 kcal/mol a little lower than -24.2 kcal/mol of $CH_4$ in the large cavity, $SF_6$ and $CH_4$ has 1.2 kcal/mol and -22.0 kcal/mol, respectively, in the small cavity. It indicates that the sizable $SF_6$ is not preferred in the small cavity but has a relative energetic advantage over $CH_4$ in the large cavity.

Monitoring of Reinjected Leachate in a Landfill using Electrical Resistivity Survey (전기비저항 탐사를 이용한 매립지의 재주입 침출수 모니터링)

  • Chul Hee Lee;Su In Jeon;Young-Kyu Kim;Won-Ki Kim
    • Geophysics and Geophysical Exploration
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    • v.27 no.3
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    • pp.159-170
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    • 2024
  • The bioreactor method, in which leachate is reinjected into a landfill for rapid decomposition and stabilization of buried waste, is being applied and tested at many landfills because of its numerous advantages. To apply the bioreactor method to a landfill successfully, it is very important to understand the behavioral characteristics of the injected leachate. In this study, electrical resistivity monitoring was performed to estimate the behavior of a landfill leachate in Korea where the bioreactor method was applied. For the electrical resistivity monitoring, a baseline survey was conducted in August 2013 before the leachate was injected, and time-lapse monitoring surveys were conducted four times after injection. The electrical resistivity monitoring results revealed reductions in electrical resistivity in the landfill attributable to the injected leachate, and the change in its characteristics over time was confirmed. In addition, by newly defining the electrical resistivity change ratio and applying it in this study, the spatial distribution and behavior of the leachate over time were effectively identified. More research on optimization of data acquisition and integrated monitoring methods using various techniques should be conducted in the near future.

Field Investigation and Stability Analysis of a Volcanic Rock Slope at the Song-Gok site, Wan-Do (완도 송곡지구 화산암류 비탈면의 현장조사 및 안정성 검토 사례 연구)

  • Kim, Hong-Gyun;Ok, Young-Seok;Kim, Seung-Hyun;Koo, Ho-Bon
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.149-160
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    • 2013
  • Volcanic activity commonly creates a highly complicated volcanic complex due to the admixture of lava flow and sedimentation of volcanic ash. The Song-Gok site is composed of volcanic rocks that collapsed at the lower part of the slope, in combination with several discontinuities in and around a fault. The results of projection analysis indicated the possibility of plane, wedge, and toppling failure in the failure section. The results of discontinuity modeling using the Distinct Element Method (DEM) revealed a total displacement of 207 mm and a joint shear displacement of 114 mm. The yield surface zone was verified at the fault plane of the failure section. In geotechnical terms, volcanic rock slopes are characteristically vulnerable to failure because of differential weathering among the various rock types, the effect of groundwater based on the permeability of the rocks, and the presence of systematic joints generated by the cooling and contraction of lava. When considering the stability of a volcanic rock slope, it is necessary to consider data such as the geological features of the rock, as obtained through detailed geological survey, and variations in discontinuities and rock blocks.

The Slope Stabilization of Solid Waste Landfill Liner System (폐기물매립장의 사면차수체계 안정화 연구)

  • Shin, Eunchul;Kim, Jongin;Park, Jeongjun
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.3
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    • pp.21-28
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    • 2009
  • As the natural aggregates such as sand and clay are getting exhausted, the quantity of utilizing geosynthetics is being increased in the solid waste landfill. Especially, the waste landfills have been constructed at the gorge in the mountainous area and reclaimed land from the sea in the Korean Peninsula. Those areas are not favorable for construction of waste landfill in geotechnical engineering aspect. In this study, the frictional characteristics of geosynthetics that used in the waste landfill were estimated. Then, the studies of the behavior of geosynthetics and stability of LDCRS (Leachate Detection, Collection, and Removal System) of side slope were conducted in the waste landfill by means of the pilot test, and numerical analysis. Geocomposite which is combined type or separated type is influenced on the strain itself, and also implicated in the stress and strain of geomembrane at the lower layer. The strain on the combined type of geocomposite is about 50% smaller than that of the separated type at the side slope. The lateral displacement and settlement of top at the slope with the separated type are three times greater than that of the combined type. In the numerical analysis, discontinuous plans in between ground and geosynthetic, geosynthetic and geosynthetic, goesynthetic and waste have been modeled with the interface element. The results gave a good agreement with the field large-scale model test. The relative displacements of geosynthetics were also investigated and hence the interface modeling of liner system is appropriate for analysis of geosynthetics liner system in the waste landfill.

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Dynamic Position Control Method for the Buffer Unit of a Deepsea Mining System (해석심해자원개발용 버퍼의 동적위치제어기법)

  • Kim, Ki-Hun;Choi, Hang-S.;Hong, Sup
    • Journal of the Society of Naval Architects of Korea
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    • v.39 no.3
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    • pp.57-63
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    • 2002
  • This paper describes a control algorithm for the buffer of a deep-sea mining system, in which the buffer is connected to a long slender pipe and then to a surface ship on one end, and to a collector on sea floor through a flexible hose on the other end. A mathematical modeling is established for designing the controller for buffer thrusters, in which the dynamic response of the long pipe is taken into account based on the mode superposition method. The fluid loading acting on the pipe is estimated by using Morison's formula. For simplicity, the surface ship is assumed to be kept stationary, the reaction from the flexible hose is ignored and only the lateral motions are considered. In order to guide the buffer to react only to the low-frequency motion of the surface vessel, the FIR digital filter is introduced to a PID-based controller It can be shown numerically that the high frequency component of the ship's motion can be effectively filtered out by using the FIR low pass filter.

Improving Stability and Characteristic of Circuit and Structure with the Ceramic Process Variable of Dualband Antenna Switch Module (Dual band Antenna Switch Module의 LTCC 공정변수에 따른 안정성 및 특성 개선에 관한 연구)

  • Lee Joong-Keun;Yoo Joshua;Yoo Myung-Jae;Lee Woo-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.105-109
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    • 2005
  • A compact antenna switch module for GSM/DCS dual band applications based on multilayer low temperature co-fired ceramic (LTCC) substrate is presented. Its size is $4.5{\times}3.2{\times}0.8 mm^3$ and insertion loss is lower than 1.0 dB at Rx mode and 1.2 dB at Tx mode. To verify the stability of the developed module to the process window, each block that is diplexer, LPF's and bias circuit is measured by probing method in the variation with the thickness of ceramic layer and the correlation between each block is quantified by calculating the VSWR In the mean while, two types of bias circuits -lumped and distributed - are compared. The measurement of each block and the calculation of VSWR give good information on the behavior of full module. The reaction of diplexer to the thickness is similar to those of LPF's and bias circuit, which means good relative matching and low value of VSWR, so total insertion loss is maintained in quite wide range of the thickness of ceramic layer at both band. And lumped type bias circuit has smaller insertion itself and better correspondence with other circuit than distributed stripline structure. Evaluated ceramic module adopting lumped type bias circuit has low insertion loss and wider stability region of thickness over than 6um and this can be suitable for the mass production. Stability characterization by probing method can be applied widely to the development of ceramic modules with embedded passives in them.

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Polymerization Behavior of Self-healing Agents for Damage Repair in Composite Materials (복합재 손상보수용 자가치료제의 중합 거동)

  • Oh, Jinoh;Yoon, Sungho;Jang, Seyong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.5
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    • pp.35-42
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    • 2014
  • Thermal analysis properties and adhesive properties of self-healing agents were evaluated through differential scanning calorimetry, reaction heat measurement, and adhesive shear test. D1E0, D3E1, D1E1, D1E3, and D0E1, depending on the mixing ratio of DCPD and ENB, were considered as self-healing agents. The amount of Grubbs' catalyst, depending on the type of self-healing agents, was varied from 0.1 wt% to 1.5 wt%. In the case of DCPD, the polymerization reaction occurred faster and the stabilized adhesive strength increased as the amount of catalyst increased; however, a large amount of catalyst was required. ENB had excellent reactivity with a small amount of the catalyst; however, high reaction heat was observed at the early stage of polymerization. Thermal analysis properties and adhesive properties of self-healing agents can be controlled by varying a mixing ratio of DCPD and ENB. Among the self-healing agents used for this study, the D3E1 would be one of the most preferable candidates with regard to maximum adhesive strength, reaching time to maximum adhesive strength, stabilized adhesive strength, and reaction heat.

Investigation of Friction Characteristics between Concrete Slab and Subbase Layers (콘크리트 슬래브와 보조기층 사이의 마찰특성 조사)

  • lim, Jin Sun;Park, Moon Gil;Nam, Young Kug;Jeong, Jin Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.6D
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    • pp.719-726
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    • 2009
  • In this study, a series of push-off tests for lean concrete, aggregate, asphalt subbases mainly used in Korea were performed to investigate the friction characteristics between the slab and subbase layers. Use of separation membrane and wet condition of subbase were other parameters in the tests. Horizontal displacements of the slabs and friction coefficients were measured at 1st loading, stable condition (2nd and 3rd loadings), and wet condition (4th loading) by applying 40mm/hour horizontal loadings. Larger maximum friction coefficients were measured in order of the lean concrete, asphalt, aggregate, and subbases using the separation membrane at 1st loading, and in order of the asphalt, aggregate, lean concrete, and subbases using the separation membrane at stable and wet conditions. The friction coefficients of the aggregate and asphalt subbases which did not used the separation membrane decreased by the wet condition while the subbases using the separation membrane were not affected. Additional push-off tests for effects of slab thickness and temperature sensitivity of asphalt will be performed. And, effects of the friction characteristics between the slab and subbase layers on behavior and performance of concrete pavements will be investigated by structural analyses using the test results.

Variation Characteristics of the Groundwater Level of Natural Vegetation and Sandy Beaches (식생/모래기반 자연해빈에서의 지하수위 변동특성)

  • Park, JungHyun;Yoon, Han-sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.1
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    • pp.62-73
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    • 2016
  • The variation of groundwater by wave, tide and precipitation conditions is closely related to the vegetation environment at the natural vegetation and sandy based beach, and it has a significant impact on the vegetation development and ground stabilization. In this study, the water temperature, electrical conductivity, and pressure were monitored at five observational stations normal to the Jinu-do(Island) shoreline of Nakdong river estuary from March 2012 to September 2014 (approximately 799 days) with the aim of measuring the variation in groundwater-table characteristics. The purpose of the study was to identify factors (tide, wave etc.) affecting groundwater-table variation using time series and correlation analysis, and to record spatial variations in the groundwater level and electrical conductivity as a result of storm events. The observational station in the intertidal zone was strongly affected by wave period and tide level. During the storm period, the groundwater-table and electrical conductivity were stabilized at the edge of sand dunes, vegetation, and areas of transition between freshwater and seawater.

Experimental Study on Behavior of Confined Concrete with Electric Arc Furnace Oxidizing Slag Aggregates (전기로 산화 슬래그 골재를 사용한 콘크리트의 횡 구속 거동에 관한 실험적 연구)

  • Kim, Sang-Woo;Lee, Jung-Mi;Lee, Yong-Jun;Jung, You-Jin;Kim, Kil-Hee
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.195-201
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    • 2011
  • This paper estimates the structural performance of spirally confined concrete having electric arc furnace (EAF) oxidizing slag aggregates. The EAF oxidizing slag is a by-product generated from iron and steel industry. The EAF oxidizing slag have been largely put to low-value-added uses due to its expansive properties of the free-CaO and free-MgO. Recently, this problem has been solved by the advances in steelmaking technology and thereby stabilizing EAF oxidizing slag aggregate. To verify the application of the EAF oxidizing slag aggregate to the structural concrete usage, a total of 27 cylindrical specimens with a diameter of 150 mm and a height of 300 mm were cast and tested. The test parameters were aggregate type and spiral reinforcement yield strength. Experimental results showed that the structural performance of specimens with EAF oxidizing slag aggregates was equivalent to that of confined concrete with natural aggregates.