Browse > Article
http://dx.doi.org/10.6108/KSPE.2014.18.5.035

Polymerization Behavior of Self-healing Agents for Damage Repair in Composite Materials  

Oh, Jinoh (Department of Mechanical Engineering, Kumoh National Institute of Technology)
Yoon, Sungho (Department of Mechanical Engineering, Kumoh National Institute of Technology)
Jang, Seyong (The 7th R&D Institute?2, Agency for Defense Development)
Publication Information
Journal of the Korean Society of Propulsion Engineers / v.18, no.5, 2014 , pp. 35-42 More about this Journal
Abstract
Thermal analysis properties and adhesive properties of self-healing agents were evaluated through differential scanning calorimetry, reaction heat measurement, and adhesive shear test. D1E0, D3E1, D1E1, D1E3, and D0E1, depending on the mixing ratio of DCPD and ENB, were considered as self-healing agents. The amount of Grubbs' catalyst, depending on the type of self-healing agents, was varied from 0.1 wt% to 1.5 wt%. In the case of DCPD, the polymerization reaction occurred faster and the stabilized adhesive strength increased as the amount of catalyst increased; however, a large amount of catalyst was required. ENB had excellent reactivity with a small amount of the catalyst; however, high reaction heat was observed at the early stage of polymerization. Thermal analysis properties and adhesive properties of self-healing agents can be controlled by varying a mixing ratio of DCPD and ENB. Among the self-healing agents used for this study, the D3E1 would be one of the most preferable candidates with regard to maximum adhesive strength, reaching time to maximum adhesive strength, stabilized adhesive strength, and reaction heat.
Keywords
Self-healing Agent; Thermal Analysis Properties; Adhesive Properties; Catalyst;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 ASTM D1002, "Standard Test Method for Apparent Shear Strength of Single-Lap-Joint Adhesively Bonded Metal Specimens by Tension Loading (Metal-to-Metal)," Annual Book of ASTM Standards, Vol. 08.01, 2002.
2 ASTM D2651-01, "Standard Guide for Preparation of Metal Surfaces for Adhesive Bonding," Annual Book of ASTM Standards, Vol. 08.01, 2002.
3 Caruso, M.M., Blaiszik B.J., Jin, H., Schelkop, S.R., Stradley, D.S., Sottos, N.R., White, S.R. and Moore, J.S., "Robust, Double-Walled Microcapsules for Self-Healing Polymeric Materials," ACS Applied Materials Interfaces, Vol. 2, No. 4, pp. 1195-1199, 2010.   DOI   ScienceOn
4 Odom, S.A., Jackson, A.C., Prokup, A.M., Chayanupatkul, S., Sottos, N.R., White, S.R. and Moore, J.S., "Visual Indication of Mechanical Damage Using Core-Shell Microcapsules," ACS Applied Materials Interfaces, Vol. 3, pp. 4547-4551, 2011.   DOI   ScienceOn
5 Noh, H.H. and Lee, J.K., "Microencapsulation of Self-healing Agents Containing a Fluorescent Dye," Express Polymer Letters Vol. 7, No. 1, pp. 88-94, 2013.   DOI
6 Brown, E.N., White, S.R. and Sottos, N.R., "Microcapsule Induced Toughening in a Self-healing Polymer Composite," Journal of Materials Science, Vol. 39, No. 5, pp. 1703-1710, 2004.   DOI   ScienceOn
7 Rule, J.D. and Moore, J.S., "ROMP Reactivity of Endo- and Exodicyclopen dadiene," Macromolecules, Vol. 35, No. 21, pp. 7878-7882, 2002.   DOI   ScienceOn
8 Liu, X., Lee, J.K., Yoon, S.H. and Kessler, M.R., "Characterization of Diene Monomers as Healing Agents for Autonomic Damage Repair," Journal of Applied Polymer Science, Vol. 101, pp. 1266-1272, 2006.   DOI   ScienceOn
9 Cho, S.H., Anderson, M., White, S.R., Sottos, N.R. and Braun, P.V., "Polydimethylsiloxane-based Self-healing Materials," Advanced Materials, Vol. 18, pp. 997-1000, 2006.   DOI   ScienceOn
10 Kessler, M.R., Sottos, N.R. and White, S.R., "Self-healing Structural Composite Materials," Composites : Part A, Vol. 34, No. 8, pp. 743-753, 2003.   DOI   ScienceOn
11 Yoon, S.H., Park, H.W. and Heo, K.S., "Evaluation of Bond Performance of Self-Healing Agents Using Single Lap Shear Test," Journal of Korean Society for Composite Materials, Vol. 17, No. 4, pp. 40-46, 2004.   과학기술학회마을
12 Jin, H., Mangun, C.L., Griffin A.S., Moore, J.S., Sottos, N.R. and White, S.R., "Thermally Stable Autonomic Healing in Epoxy using a Dual-microcapsule System," Journal of Advanced Materials, Vol. 26, Issue 2, pp. 282-287, 2014.   DOI   ScienceOn
13 White, S.R., Sottos, N.R., Geubelle, P.H., Moore, J.S., Kessler, M.R., Sriram, S.R., Brown, E.N. and Viswanathan, S., "Autonomic Healing of Polymer Composite Materials," Nature, Vol. 409, No. 6825, pp. 794-797, 2001.   DOI   ScienceOn
14 Kessler, M.R. and White, S.R., "Self- Activated Healing of Delamination Damage in Woven Composites," Composites: Part A, Vol. 32, No. 5, pp. 683-699, 2001.
15 Brandon, E.J., Vozoff. M., Kolawa, E.A., Studor, G.F., Lyons, F., Keller, M.W., Beiermann, B., White, S.R., Sottos, N.R., Curry, M.A., Banks, D.L., Brocato, R., Zhou, N., Jung, S., Jackson, T.N. and Champaigne, K., "Structural Health Management Technologies for Inflatable/ deployable Structures: Integrating Sensing and Self-healing," Acta Astronautica, Vol. 68, Issue 7-8, pp. 883-903, 2011.   DOI   ScienceOn
16 Caruso, M.M., Blaiszik, B.J., White, S.R., Sottos, N.R. and Moore, J.S., "Full Recovery of Fracture Toughness Using a Nontoxic Solvent-Based Self-Healing System," Advanced Functional Materials, Vol. 18, Issue 13, pp. 1898-1904, 2008.   DOI   ScienceOn
17 Mookhoek, S.D., Blaiszik, B.J., Fischer, H.R., Sottos, N.R. and White, S.R., "Peripherally Decorated Binary Microcapsules Containing Two Liquids," Journal of Materials Chemistry, Vol. 18, Issue 44, pp. 5390-5394, 2008.   DOI   ScienceOn
18 Sondari, D., Septevani, A.A., Randy, A. and Triwulandari, E., "Polyurethane Microcapsule with Glycerol as the Polyol Component for Encapsulated Self Healing Agent," Journal of Engineering and Technology, Vol. 2, No. 6 pp. 466-471, 2010.
19 Yuan, L., Liang, G.J., Xie, J.Q., Guo, J. and Li, L., "Thermal Stability of Microencapsulated Epoxy Resins with Poly(urea-formaldehyde)," Polymer Degradation and Stability, Vol. 91, Issue 10, pp. 2300-2306, 2006.   DOI   ScienceOn