• Title/Summary/Keyword: 개질시스템

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Operational Characteristics of the Multi-㎾ Class PEMFC Stack (수 ㎾급 고분자전해질 연료전지 스택의 운전특성)

  • 심중표;오인환;하흥용;최형준;안상열;홍성안;임태원
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.11a
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    • pp.95-100
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    • 1999
  • 고분자전해질 연료전지 (polymer electrolyte membrane fuel cell, PEMFC)는 다른 형태의 연료전지에 비하여 전류밀도가 크고 구조가 간단하며 전해질의 누출이나 손실의 염려가 없어 수송용 무공해 차량의 동력원으로서 적합한 시스템이다. 또한 빠른 시동과 응답특성, 우수한 내구성을 가지고 있고 연료로 수소 이외에 메탄올이나 천연가스를 개질하여 사용할 수 있다는 장점이 있다.(중략)

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Steam Reforming of Tar Produced from Biomass Gasification Using Ni/Ru-X/Al2O3 (X=K or Mn) Catalyst (Ni/Ru-X/Al2O3 (X=K or Mn) 촉매를 이용한 바이오매스 가스화 타르의 수증기개질)

  • Oh, Gunung;Park, Seo Yoon;Lee, Jae-Goo;Kim, Yong Ku;Ra, Ho Won;Seo, Myung Won;Yoon, Sang Jun
    • Clean Technology
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    • v.22 no.1
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    • pp.53-61
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    • 2016
  • Steam reforming of tar produced from biomass gasification was conducted using several Ni-based catalysts. In labscale, the catalytic steam reforming of toluene which is a major component of biomass tar was studied. A fixed bed reactor was used at various temperatures of 400-800 ℃. Ru (0.6 wt%) and Mn or K (1 wt%) were applied as a promoter in Ni based catalysts. Generally, Ni/Ru-K/Al2O3 catalyst shows higher performance on steam reforming of toluene than Ni/Ru-Mn/Al2O3 catalyst. Used catalysts were analyzed by XRD and TGA to detect sintering and carbon deposition. Base on the lab-scale studies, the monolith and pellet type catalysts were tested in 1 ton/day scale biomass gasification system. Ni/Ru-K/Al2O3 monolith catalyst shows high tar reforming performance at high temperature. In addition, Ni/Ru-Mn/Al2O3 monolith catalyst was showed deactivation with operation time. Reforming performance of Ni/Ru-K/Al2O3 pellet catalyst which showed 66.7% tar conversion at 587 ℃ was compared to regenerated one. Overall, Ni/Ru-K/Al2O3 pellet catalyst shows higher stability and performance than other used catalysts.

Comparative Performance Analysis of Hybrid PEM Fuel Cell Hybrid Systems (하이브리드 PEM 연료전지 시스템의 성능 비교해석)

  • You, Byung-June;Kim, Tong-Seop;Lee, Young-Duk;Ahn, Kook-Young
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3230-3235
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    • 2007
  • Design performances of various configurations of the PEMFC/GT hybrid systems have been evaluated. Based on PEMFC adopting steam reforming, various system configurations (one ambient pressure configuration and three different pressurized configurations) were designed and their performances were compared. Their Performances are also compared with the reference PEMFC system. Influences of turbine inlet temperature, pressure ratio on the hybrid systems performance were investigated and design ranges exhibits better efficiency than the PEMFC system were presented. One of the pressurized system may have much higher efficiency than the PEMFC system, while other systems hardly provide efficiency upgrade.

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Prediction of the Dynamic Adsorption Behaviors of the Uranium and Cobalt Ions in a Fixed Bed by Surface Modified Activated Carbon (표면개질 활성탄을 이용한 고정층에서 우라늄 및 코발트 이온의 동적 흡착거동 모사)

  • Geun-IL Park;Jung-Won Lee;Kee-Chan Song;In-Tae Kim;Kwang-Wook Kim;Myung-Seung Yang
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.81-92
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    • 2003
  • In order to predict the dynamic behaviors of uranium and cobalt in a fixed bed at various influent pH values of liquid waste, the adsorption system is regarded as a multi-component adsorption between each ionic species in the solution. Langmuir isotherm parameters of each species were extracted by incorporating equilibrium data with the solution chemistry of the uranium and cobalt using IAST. Prediction results were in good agreement with the experimental data, except for a high concentration and pH. Although there was some limitations in predicting the cobalt adsorption, this method may be useful in analyzing a complex adsorption system where various kinds of ionic species exist in a solution.

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Determination of Peening Area for Finite Element Residual Stress Analysis of Ultrasonic Nanocrystal Surface Modification under Multiple Impact Conditions (초음파나노표면개질 다중충격 조건에서의 잔류응력 예측을 위한 유한요소 피닝해석 영역 결정)

  • Tae-Hyeon Seok;Seung-Hyun Park;Nam-Su Huh
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.17 no.2
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    • pp.145-156
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    • 2021
  • Ultrasonic Nanocrystal Surface Modification (UNSM) is a peening technology that generates elastic-plastic deformation on the material surface to which a static load of a air compressor and a dynamic load of ultrasonic vibration energy are applied by striking the material surface with a strike pin. In the UNSM-treated material, the structure of the surface layer is modified into a nano-crystal structure and compressive residual stress occurs. When UNSM is applied to welds in a reactor coolant system where PWSCC can occur, it has the effect of relieving tensile residual stress in the weld and thus suppressing crack initiation and propagation. In order to quantitatively evaluate the compressive residual stress generated by UNSM, many finite element studies have been conducted. In existing studies, single-path UNSM or UNSM in a limited area has been simulated due to excessive computing time and analysis convergence problems. However, it is difficult to accurately calculate the compressive residual stress generated by the actual UNSM under these limited conditions. Therefore, in this study, a minimum finite element peening analysis area that can reliably calculate the compressive residual stress is proposed. To confirm the validity of the proposed analysis area, the compressive residual stress obtained from the experiment are compared with finite element analysis results.

A Study on Optimal Operation of Methanol Steam Reforming System for Hydrogen Fuel Cell Propulsion Ships (수소 연료전지 추진 선박 적용을 위한 메탄올 수증기 개질 시스템 최적 운전점 연구)

  • HEEJOO CHO;SOOBIN HYEON;SEUNGKYO JUNG;HYUNJIN JI;JUNGHO CHOI
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.733-742
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    • 2022
  • Hydrogen fuel cell propulsion ships are emerging to respond to the recently strengthened carbon emission regulations in the international shipping sector. Methanol can be stored in a liquid state at normal pressure and temperature, and has the advantage of lower reforming temperature compared to other fuels. In this study, the optimal operating point of the methanol steam reforming system was derived by changing the Steam Carbon Ratio (SCR) from 0.10 to 3.00. Results showed that In terms of methanol conversion rate and hydrogen yield, the larger the SCR is the better, but in terms of system efficiency, it is most advantageous to operate at SCR 0.70 in Pressure Swing Adsorption (PSA) mode and SCR 0.80 in Pd membrane mode. Through this study, it was found that the optimal SCR in the reformer and the entire system including the reformer may be different, which indicates that the optimum operating point may be different depending on the change of the system configuration.

Applications of Self-assembled Monolayer Technologies in MEMS Fabrication (MEMS 공정에서의 자기 조립 단분자층 기술 응용)

  • Woo-Jin Lee;Seung-Min Lee;Seung-Kyun Kang
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.2
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    • pp.13-20
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    • 2023
  • The process of microelectromechanical system (MEMS) fabrication involves surface treatment to impart functionality to the device. Such surface treatment method is the self-assembled monolayer (SAM) technique, which modifies and functionalizes the surface of MEMS components with organic molecule monolayer, possessing a precisely controllable strength that depends on immersion time and solution concentration. These monolayers spontaneously adsorb on polymeric substrates or metal/ceramic components offering high precision at the nanoscale and modifying surface properties. SAM technology has been utilized in various fields, such as tribological property control, mass-production lithography, and ultrasensitive organic/biomolecular sensor applications. This paper provides an overview of the development and application of SAM technology in various fields.

Performance Analysis of Solid Oxide Fuel Cell/Gas Turbine Hybrid Systems for Different Cell Inlet Preheating Methods (셀 입구 예열방법에 따른 고체산화물 연료전지/가스터빈 하이브리드 시스템의 성능해석)

  • Yang, Won-Jun;Kim, Tong-Seop;Kim, Jae-Hwan
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1664-1669
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    • 2004
  • Design analysis of the solid oxide fuel cell and gas turbine combined power system is performed considering different methods for preheating cell inlet air. The purpose of air preheating is to keep the temperature difference between cell inlet and outlet within a practical design range. Three different methods are considered such as a burner in front of the cell, a preheater in front of the cell and recirculation of the cathode exit gas. Analyses are carried out for two maximum cell temperature differences. The greater temperature difference ensures higher efficiency. The cathode exit gas recirculation exhibits better performance than other methods.

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