• The Journal of the Petrological Society of Korea
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• v.21 no.4
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• pp.405-413
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• 2012

This study demonstrates the consolidation effect of ethylsilicate consolidants considering material characteristics and weathering degree of Samneunggyeseongakyukjonbul(rock-carved Yukjonbul Buddha in Samneung Valley) in Namsan, Gyeongju. The buddha statue is composed of alkali feldspar granite and contains numerous sets of joint with exfoliation and granular disintegration, therefore the statue is necessary to be treated for surface strength. The laboratory and in-situ tests of consolidation effect showed more increase of ultrasonic velocity that KSE 300, a relatively highly concentrated consolidant, performed more increase of ultrasonic velocity and decrease of porosity than others after treatments in weathered granite. And the consolidated rock with OH 100 was more resistant to salt weathering. For the buddha statues, KSE 300 is more applicable to enhance surface strength because it showed higher consolidation effect for long term than OH 100 and the statues has not been weathered by salts.

• Journal of Conservation Science
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• v.29 no.3
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• pp.249-259
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• 2013

This study was experimented on accelerated weathering test using salt and freeze-thaw to prove effects of consolidants and consolidation for stone cultural heritage. The samples used four kinds of stones (Gyeongju Namsan Granite, Iksan Granite, Yeongyang Sandstone and Jeongseon Marble) which to distributed by three type of weathering grade (Fresh, Weathered Stone and Highly Weathered Stone) added for thermal treatment. The samples were treated with three consolidants (Wacker OH 100, Remmers KSE 300 and 1T1G), and tested by 500 cycles with freezing-thawing and 50 cycles of salt weathering test. As a results of freezing-thawing test, the crack and destruction occurred from some samples. And total immersed samples maintained effect of consolidation to 200 cycles. Also, The rock particle was fall off and gradually destructed by salts weathering test. The consolidated sample relatively had fewer changes by the weathering than not treated sample. The sprayed sample had not continuous effect on weathering.

• Journal of Conservation Science
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• v.21
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• pp.21-32
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• 2007

Low-viscosity alkoxysilanes that polymerize into the porous network of decayed stone by a sol-gel process are widely used as stone consolidants. During drying, the gel network contracts due to capillary pressure generated by solvent evaporation. We have prepared tetraethoxysilane mixed solution containing methyltrisilane, ethyl trisilane and (3-glycidyloxypropyl)trimethoxysilane having epoxy ring in order to reduce the shrinkage happened inside the stone porous structure during the gel formation. Mixed solutions were applied into sandstone and granites and characterized by FT-IR, SEM. The gelation time, water uptake, contact angles were measured and compared with those of the commercial stone conservation materials.

• Journal of Conservation Science
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• v.23
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• pp.1-10
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• 2008

Consolidants based on tetraethoxysilane (TEOS) such as alkoxysilanes have been widely used for the consolidation of decaying stone heritages. Low-viscosity alkoxysilanes penetrate inside the decaying stone and polymerize within the porous structure of the decaying stone, significantly increasing the cohesion of the material. However, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force, which is typical for TEOS-based consolidants. We prepared new consolidants TEOS-based consolidants containing flexible (3-glycidoxypropyl)trimethoxysilane (GPTMS) and silica nanoparticles (or polyhedral oligomeric silsesquioxanes (POSS)) in order to reduce capillary force development during gel drying. Since the consolidants should have a good interaction with the component of the stone in order to connect the isolate grains of decaying stone, the adhesion interaction of the developed consolidants on the surface of the granite was macroscopically investigated by the ISO 2409 cross cutting test. The adhesion interaction decreased with the addition of silica nanoparticle and POSS while it increased with the addition of GPTMS in TEOS solution.

• Journal of the Korean Wood Science and Technology
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• v.28 no.1
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• pp.28-35
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• 2000

This paper deals with a coating technique for hardening surface layer of softwood(Larix leptolepis) flooring board to improve its surface properties such as hardness and abrasion resistance, Two coating methods were applied for surface hardening of the wood in this study. First, several functional monomers were added in UV-curing epoxy acrylate varnish. Secondly, unsaturated polyester varnish was used as under coat and acryl varnish including anti-abrasive agent was used as top coat. The hardness of the treated wood was similar to that of high density hardwood such as keruing by the first coating method. The abrasion resistance of the coated wood was greatly improved by the second method. Adhesion properties and impact resistance of the coated wood surface were also good. It was suggested that the well-coated softwood could be used as interior flooring board for heavy walking as substitute for hardwood.

• Journal of Conservation Science
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• v.26 no.4
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• pp.361-370
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• 2010

The open pore of stone cultural heritage is not expected to have an effect only by consolidation, and it has a drawback that only the internal wall adheres and gets consolidated due to the incrase of liquidity caused by the low viscosity and difference of materials in the case of filling with high molecules synthetic resins. Therefore, this research selected the effective filler for Three-storied Stone Pagoda at the West of Gameunsaji Site through the verification of filling effects of materials using the information about various fillers based on minerals. As the result of filler experiment, got filled with the combination of KSE 500 STE + KSE Filler A${\cdot}$KSE Filler B that is the same as the Member or has very similar properties. The total surface area of the west stone is $252.6m^2$ and the area where the internal opening has been developed is $17.77m^2$(7.03%) requiring a task that fills the internal($24,885m{\ell}$).

• Bulletin of Korea Environmental Preservation Association
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• v.30 s.373
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• pp.33-36
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• 2008

금년부터 국제기준(GHS)에 따른 새로운 화학물질 분류∙표시제가 시행이 되며, 실내공기질 관리대상이 확대되고 포름알데히드 기준이 강화된다. 또한 종전에는 폐기물적법처리시스템을 지정폐기물만을 전산입력토록 하였으나, 2008년 8월부터는 사업장일반폐기물까지 전산입력 대상이 확대된다. 폐수 배출허용기준 강화, 폐기물 수출∙입 신고제도 시행 등 2008년부터 달라지거나 새롭게 시행되는 제도를 분야별로 정리하였다.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.425-428
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• 2002

면직물의 황토염색에 대한 세탁견뢰도 증진을 위하여 대두콩즙을 전처리하거나 염액에 쌀풀이나 아교 또는 소금을 첨가한다. 이러한 물질들은 황토와 섬유사이의 결찹을 강화시키는 역할을 한다[1,2]. 그러나 염착성의 개선을 위하여 반복염색이 행하여지며 기존 고착제의 처리방법은 복잡하고 재현성이 없는 단점을 지니고 있다. 본 연구에서는 콩즙, 탈지유, 키토산 등을 고착제로 사용하여 염착량, 색상 변화 및 세탁과 마찰견뢰도를 분석하여 황토염색의 고착제로서의 가능성을 조사하였다. (중략)

• Journal of Conservation Science
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• v.27 no.2
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• pp.201-209
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• 2011

While consolidants based on tetraethoxysilane (TEOS) have been widely used for the consolidation of decaying stone heritages, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force. We have prepared new TEOS-based consolidants containing flexible (3-glycidoxypropyl) trimethoxysilane (GPTMS) in order to reduce capillary force development during gel drying. In this study, we have prepared TEOS/GPTMS-based consolidants containing ETEOS in order to improve the surface hydrophobisity. The physical properties of the TEOS/GPTMS/ETEOS solution with different hydrolysis were compared with those of the commercial products Wacker OH$^{(R)}$. The contact angle of the surface increased with the addition of the ETEOS, which is higher than that of Wacker OH$^{(R)}$. The sol-gel mechanism was manipulated by the degree of hydrolysis as well as the amount of ETEOS. The properties and the applicability of the developed consolidants for the decayed Korean granites are also investigated.

• Proceedings of the KSAR Conference
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• 2004.06a
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• pp.265-265
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• 2004

한우번식우 사육농가와 사육규모가 확대와 소 값 상승으로 인하며 인공수정 및 수정란 이식에 대한 수태율 향상에 많은 관심이 집중되고 있다. 이러한 수태율 향상을 위하여 한우 암소에 배란동기화 처리 후 인공수정 시 황체기능 강화제인 등을 투여하여 황체기능을 강화시키고, 투여시기에 따라 개체에 대한 신체충실지수(BCS)와 혈중요소태질소화합물(BUN)을 분석하였으며, 또한 투여시기에 따른 혈중 Progesteroner의 변화를 조사하였다. 황체기능강화제의 투여 방법은 HCG 투여구는 배란동기화 처리 후 6일째와 7일째에 각각 1500 IU와 3000 IU를 투여하였고, 투여 후 14일째에 혈액을 채취하여 혈중 P4 분석하였다. (중략)