• Journal of Conservation Science
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• v.25 no.1
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• pp.87-100
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• 2009

We carried out the effect verification of conservation treatment focusing on basement rock of alkali granite at the Yukjonbul (two-pairs of Buddha Triads) carved on rock cliff of Samneung valley in Namsan mountain of Gyeongju. The conservation treatments were used to ethylsilicate-type rock consolidant and epoxy-type resin. It is treatment method that the epoxy-type resin have been applied one time into the exfoliation area, after rock consolidation treatment have been worked for three times. As the result of measuring ultrasonic velocity, P-wave velocity of the exfoliation area was relatively increased after applied the conservation treatments. The ultrasonic velocity of all area was increased as 27.8%. This result has been proved with consolidation effects by consolidant and filler for stone cultural heritages. The treatment method should be worked about three time to consolidate sufficiently for rocks.

• Journal of the Mineralogical Society of Korea
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• v.30 no.2
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• pp.71-81
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• 2017

Rock properties and the effects of chemicals that were used for conservation were studied for effective conservation treatment of Seated Buddha rock carving, which is composed of grayish white tuff, at Golguram Hermitage, Gyeongju. The rocks contain 3-5% montmorillonite, a swelling mineral and reacting with water, the d spacing of swelling minerals was increased (1.54-2.69%). On the one hand, the physical properties of the rock samples, such as surface hardness, water absorption rate, and porosity improved after the application of ethyl silicate-based stone strengthener. On the other, the interlayer of swelling minerals decreased and greater the of swelling mineral content, the greater is the extent of swelling (4.23-12.12%). When the ethyl silicate-based stone strengthener was applied after pretreatment with a swelling inhibitor, the physical properties were similar to those of the stone strengthener alone. There was no interlayer spacing change of swelling minerals due to swelling inhibition treatment; however, when the stone strengthener was applied after the swelling inhibitor, interlayer changes were similar to those when only the stone strengthener was treated (4.10-11.85%). Though the peak intensity of swelling minerals in X-ray diffraction pattern decreased, the effect of the swelling inhibitor was almost negligible. Therefore, it is not appropriate to use ethyl silicate-based stone strengthener for Golgulam rock containing swelling minerals and supplementing them with a swelling inhibition system is not effective. Because weathering rapidly progresses when swelling minerals contact moisture, for now, measures to prevent water contact, such as expansion of the canopy, are needed in the lower and side parts of the carving.

• Journal of Conservation Science
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• v.18 s.18
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• pp.89-96
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• 2006

Surface layers of stone cultural properties including the soluble salt need consolidation because they are mostly very weak. There is a lot of research on the penetration depth of consolidant in stone and the effect of consolidant on mechanical stability of deteriorated structure. But some conservation experiences show that consolidation with silicic acid ester is not successful on salt contaminated stone cultural properties. In this study, in order to assess the influence of soluble salts$(CaSO_4\;2H_2O,\;NaNO_3)$ on the efficiency of consolidation on the deteriorated stone cultural properties(Nationalgalerie, Berlin, Germany) sandstone samples have been soaked with the salts solution. The impregnation of consolidant based on ethyl filicate have been afterwards carried out on these samples. As a result, it confirms that the soluble salts act as a preventer or consolidation. They fill up the pores in the stone and prevent that sufficient amount of consolidant enter deeply into the stone. According to this result, if use silicic ethyl ester as a consolidant for the research object which is built by Nebra sandstone, desalination is necessary before the treatment with consolidant. But it is also reported by other researches that some soluble salts improve the consolidation effect. Therefore it should be necessary to pre-study about salt and its harmfulness before the consolidation treatment. In order to consolidate without the aggravative damage in salt contaminated stone cultural heritage, we must first of all study the relations among salt, stone and consolidant.

• Journal of the Mineralogical Society of Korea
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• v.27 no.3
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• pp.149-158
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• 2014

Consolidants were extended use for conservation of weathered stone heritage. Epoxy, acryl, isocyanate, and alkoxysilane consolidants are most commonly used products. Consolidant of 1T1G_5 wt 0.08 % that consists of T (TEOS: Tetraethyl Orthosilicate) and G (GPTMS: 3-Glycidoxy propyl trimethoxy silane) were used this study. A shore hardness values show increasing after treated with consolidant in granite. Surface brightness after treated with consolidant are changing slightly dark but turns the original color over time. Ultra-sonic velocity is increased after treated with consolidant but slightly reduced over time to remain constant. It has the advantage of being effective after treated with consolidant in granite and efficiency of consolidation increase with slow velocity before treated with consolidant.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.1
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• pp.51-64
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• 2022

For effective preservation of the rocks, which bearing plant fossils at Gumkwangdong Formation, Pohang, the properties of rock and treatment of chemicals were examined in an artificial weathering test. The rocks are diatomaceous siliceous mudstone, which contain a small amount of smectite and has developed laminated layers. The rocks react with water, the d₀₀₁ spacing of smectite was increased. On the one hand, the physical properties of the rock samples, such as surface hardness, improved after the application of ethyl silicate-based stone strengthener. On the other hand, the spacing of interlayer of swelling clay minerals decreased and spacing of laminae layer increased. When the ethyl silicate-based stone strengthener was applied after pretreatment with a swelling inhibitor, interlayer and spacing of laminae changes were similar to those when only the stone strengthener was treated. The effect of the swelling inhibitor was almost negligible. When the rocks that have been conserved with chemicals react with water, spacing of laminae has widened much, whereas when the rocks was in contact with moisture only, there was little change. In addition, if it is placed in the outdoor after conservation treatment, although it occurs slightly slower than the untreated rock, the separation of the lamination layer and the pulverization of the rock occur within a very short time. Consolidation is required to improve the physical properties of fossil rock, but when exposed to rain and undergoing freeze-thaw process, the effect is lost very quickly. Therefore, regardless of the chemical treatment, it is a priority to prevent direct rainfall contact with the rock.

• Journal of the Mineralogical Society of Korea
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• v.25 no.2
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• pp.105-115
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• 2012

The consolidants have been widely used for the consolidation of decaying heritage stone surfaces. In this study, X-ray diffraction analysis, polarized and stereo-microscope and scanning electron microscope were used to study the surface characterization of granite, sandstone and marble, and to assess the efficiency and the effects of the developed condolidants in the field. The developed consolidants used in this experiment are 100%1T1G and 3%40nm/97%1T1G. The effects of consolidants are 3%40nm/97%1T1G${\gg}$100%1T1G in granite, 3%40nm/97%1T1G>100%1T1G in sandstone, and 3%40nm/97% 1T1G=100%1T1G in marble. The characteristics of rock surface when treated with consolidants show different result according to consolidantes type. This result of treating with consolidant can be used for the conservation of an decaying heritage stone.

• Analytical Science and Technology
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• v.22 no.3
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• pp.263-271
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• 2009

The purpose of metal artifacts conservation is recovering the original state of objects and preventing it from further corrosion. Four different consolidants are selected that are widely used for bronze objects conservation. This study found out the characteristics of thin film by various experiments and analysis for the bronze plates coated using each solutions. After a series of analysis, resin B and V showed good coating properties. However, the evaluation point suited to this purpose are adhesive strength, stability against yellowing and corrosion resistance. Therefore, resin B of four different consolidants could expect to get the most suitable consolidation effect for consolidation purpose.

• Economic and Environmental Geology
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• v.53 no.1
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• pp.87-98
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• 2020

The bird track fossil site in Haman Formation is divided into seven sedimental layers by the sedimentary structures, lithofacies and sequences. The bird tracks top on the highest layer, which includes ripple marks and suncracks. The layer has lithofacies with reddish grey siltstone and dark grey mudstone, alternately. As an analysis for the same rocks of the fossil site, physical properties show on mean values for 0.62% of absorption rate, 1.64% of porosity and 2.63 of specific gravity. Rock-forming minerals composed mainly of plagioclase, quartz, calcite, chlorite and mica. Meanwhile, we executed an experiments based on the petrography and weatherings to find a proper consolidants. In the experiments, the OH 100 reagent proved stable aspect and the lowest transition rate in terms of weight and chromaticity. Also, it showed the highest increase in ultrasonic velocity, improving the physical properties of the rocks. In the case of applying the OH 100 with antihygro, an swelling inhibitors on the sedimentary rocks, the chromaticity indicated an stable transition aspect. When it comes to the physical properties, the antihygro also decreases the porosity effectively. Thus, the most proper method for the fossil site of Haman Formation is to apply antihygro and OH 100 reagents since the rocks includes clay minerals that show swelling characteristics. However, this result is deduced from an indoor application experiments, leaving the necessity of verification how these reagents would affect the bird tracks site under the field condition.

• Journal of the Mineralogical Society of Korea
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• v.30 no.4
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• pp.187-194
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• 2017

In this study, marble that consist mainly of calcite were used for applicability evaluation after treated with consolidant such as alkoxysilane series of 0.8T0.2E1G_3wt0.08% and 1T1G_7wt0.08%. The position and intensity of X-ray diffraction peaks are no change and increasing trend after treated with two consolidants. The results of scanning electron microscopic analysis, morphology of rope type and homogeneous surface of platy or leaflike form observed on the marble after treated with 0.8T0.2E1G_3wt0.08% and 1T1G_7wt0.08%, respectively. Brightness of surface after treated with consolidant are changing slightly dark. Shore hardness and ultrasonic velocity values show increasing after treated on the marble surface with two consolidants.

• Journal of Conservation Science
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• v.25 no.3
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• pp.245-256
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• 2009

Stereo-Microscope observation, ultrasonic velocity, shore hardness and standard color measurement performed for studies of physical characterization of Namsan granite after treated with consolidants. The consolidants used in experiment are 35wt% Silicate Nonparticle/100%1T1G (Nonparticle), 3%POSS-SO1455/97%1T1G(3%POSS1455), POSS-SO1458/97%1T1G (3%POSS1458), 3%7nm/97%1T1G(3%7nm), 3%16nm/97%1T1G(3%16nm), 3% 40nm/97%1T1G(3%40nm) develop with Sejong university, and Wacker Silres BS OH-100, Unil Sandsteinfestiger OH-100. The color of rock surface is darker than original one but similar to original samples with time, and ultrasonic velocity and shore hardness increased with after consolidant treatment.