• The Monthly Technology and Standards
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• s.19
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• pp.41-45
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• 2003

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.28 no.5
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• pp.347-358
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• 1999

암모니아는 독성, 가연성 및 동 재질의 부식성 등의 단점은 있지만 CFC계 냉매가 개발되기 전에는 우수한 열역학 및 열전달 특성 때문에 냉매로서 가장 많이 사용되어져 왔다. 미국에서는 약120년, 일본에서는 약 80년 전부터 암모니아가 냉동 사이클에 사용되었고, 따라서 축적된 관련 기술 수준도 놀고 경험도 많은 편이다. 지금도 미국에서는 상업용 냉동기의 80% 정도가 암모니아를 냉매로 사용하고 있다. 우리나라도 냉동창고 냉동용으로는 암모니아 시스템이 널리 사용되고 있다.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.6
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• pp.522-529
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• 2004

In this study, external condensation heat transfer coefficients (HTCs) of flammable refrigerants of propylene, propane, isobutane, butane, DME, and HFC32 were measured on a horizontal plain tube, 26 fpi low fin tube, and Turbo-C tube. All data were taken at the temperature of 39$^{\circ}C$ with a wall subcooling of 3∼8$^{\circ}C$. Test results showed a typical trend that condensation HTCs of flammable refrigerants decrease with increasing wall subcooling. HFC32 had the highest HTCs among the tested refrigerants showing 44% higher HTCs than those of HCFC22 while DME showed 28% higher HTCs than those of HCFC22. HTCs of propylene and butane were similar to those of HCFC22 while those of propane and isobutane were similar to those of HFC134a. Based upon the tested data, Nusselt's equation is modified to predict the plain tube data within a deviation of 3%. For 26 fpi low fin tube, Beatty and Katz equation predicted the data within a deviation of 7.3% for all flammable refrigerants tested. The heat transfer enhancement factors for the 26 fpi low fin and Turbo-C tubes were 4.6∼5.7 and 4.7∼6.9 respectively for the refrigerants tested indicating that the performance of Turbo-C tube is the best among the tubes tested.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.10
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• pp.726-734
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• 2007

In this study, lower flammability limits (LFLs) of three hydrocarbon refrigerants (R600a, R290, R1270) and two hydrofluorocarbon refrigerants (R152a, R32) and DME (RE170) are measured by the method proposed by ASTM E681-04 Standard. Flammability tests are carried out at three temperatures of $23^{\circ}C,\;60^{\circ}C\;and\;100^{\circ}C$ and relative humidity 50%. Test results show that the present data for isobutane and propane obtained at $23^{\circ}C$ are similar to those found in the literature, confirming indirectly the reliability of the present test method and facility. For propylene, R152a, and R32, LFLs found in the literature differ considerably. Especially, the deviation of LFL of propylene is more than 30% among the literature data. The present data for propylene, R152a, and R32 agree with either of the data sets available. As the temperature increases from $23^{\circ}C\;to\;100^{\circ}C$, LFLs of all refrigerants tested decrease. LFLs of most refrigerants tested in this study at $60^{\circ}C$ decrease by $0.1{\sim}0.3%$ as compared to those at $23^{\circ}C$. Also LFLs of most refrigerants tested in this study at $100^{\circ}C$ decrease by $0.1{\sim}0.3%$ as compared to those at $60^{\circ}C$.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2013.11a
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• pp.93-94
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• 2013

에어컨 실외기는 냉매와 함께 가연성 윤활유가 고압으로 충전되어 있어 연소하중이 높다. 대부분의 건축물에 설치되는 에어컨 실외기는 미관을 고려하여 건물 외벽에 종렬로 설치하기 때문에 에어컨 실외기 또는 주변에서 화재가 발생하면 이들 실외기를 따라 고층으로의 연소 확대의 위험성이 있다.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.5 no.3
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• pp.217-225
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• 1993

Nonflammable mixtures of flammable and nonflammable refrigerants are possible as substitute refrigerants for use in domestic heat pumps and refrigerators. Refrigerant leakage from such a system is of paramount concern since it is possible that the resulting mixture composition remaining in system will reside in the flammable range. This paper presents a simulation of a leakage process of refrigerant mixtures. Idealized cases of isothermal leakage process are considered in this study representing a slow leak. Simulation is performed for selected composition of binary and ternary refrigerant mixture; R-32/134a and R-32/125/134a. Mixture compositions with respect to percentage leak of original charge are presented. In isothermal leakage process, both vapor and liquid compositions of more volatile refrigerant decrease during vapor and liquid leak, but the total composition of this component decreases during vapor leak and increases during liquid leak. Vapor and liquid compositions are determined depending on the vapor-liquid equilibrium relation of the refrigerant mixture. The refrigerant mixture left in the system can go to a nonflammable direction relying on which component in the mixture is flammable.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.3
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• pp.247-253
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• 2006

In this work, pool boiling heat transfer coefficients (HTCs) of hydrocarbon refrigerants are measured from a horizontal smooth tube of 19.0 mm outside diameter. Tested pure refrigerants are Propylene, Propane, Isobutane, Butane and Dimethylether (DME). The pool temperature was maintained at saturation temperature of $7^{\circ}C$ and heat flux was varied from $10kW/m^2$ to $80kW/m^2$ with an interval of $10kW/m^2$. Wall temperatures were measured directly by thermocouple hole of 0.5 mm out-diameter, 152 mm long and inserting ungrounded sheathed thermocouples from the side of the tube. Tested results show that HTCs of Propane, Propylene are 2.5%, 10.4% higher than those of R22 while those of Butane and Isobutane are 55.2%, 44.3% lower than those of R22 respectively. For pure refrigerants, new correlation can be applied to all of CFCs, HCFCS, HFCs, as well as hydrocarbons was developed. The mean deviation was 4.6%.

• Journal of the Korean Institute of Gas
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• v.20 no.1
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• pp.62-67
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• 2016

Natural gas, one of the cleanest fossil fuel, is liquefied to reduce its volume for the long distance transportation. Small size floating liquefied natural gas plant has small area that safe issue is highly considered. However, Dual Mixed Refrigerants (DMR) process has fire potential by using flammable refrigerants and N2 Expander process has low compressed energy efficiency which has high inherent process safety. Therefore, safe process with high compressed energy efficiency is constantly needed. This study suggested an alternative refrigerants to existing DMR process by using Hydrofluorocarbon which has high safety due to its non-flammable properties. As a result, it showed 34.8% lower compressed energy efficiency than DMR process that contains fire potential whereas 42.6% improved compressed energy efficiency than Single N2 Expander process. In conclusion, this research proposed safe process for small size floating liquefied natural gas plant while having high efficiency.