• Journal of the Korean Wood Science and Technology
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• v.11 no.3
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• pp.23-30
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• 1983

This experiment was carried out for diminishing the material loss and the damage of human life due to the fire disaster by treating plywood with fire retardant chemical solution. At this study, we observed and measured chemical retention, burning point, maximum flame length, flame exausted time, carbonized area, and weight loss of plywood treated by each solution of ammonium sulphate [$(NH_4)_2SO_4$] and monoammonium phosphate [$NH_4H_2PO_4$]. Obtained results at the study may be summarized as follows: 1. In case of monoammonium phosphate-treated plywood, every tested item of fire retardancy was shown more excellent at the 25% chemical concentration and shown also at 9 hours treatment except maximum flame length compared with ammonium sulphate-treated plywood. 2. However in case of ammonium sulphate-treated plywood, 6 hours treatment of fire retardancy was better than 9 hours treating time. 3. Monoammonium phosphate was generally better than ammonium sulphate in every tested item.

• Fire Science and Engineering
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• v.27 no.3
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• pp.30-37
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• 2013

The ultimate purpose of the present study is to secure a effective method for foam liquid discharge when the mixing ratio deviates from the permissible range due to a decrease in the bypass flow rate resulting from a decrease in the cross sectional area of the foam liquid piping ranging from the branching header of one foam proportioner to the branching headers of multiple branching foam fire-extinguishing systems in the region for fire extinguishing and then to the standpipe at the lower part of the storage tank when a fire occurred in a combustible tank. To this end, the cause of mixing ratio variations following changes in the flow rates of existing foam fire extinguishing systems was analyzed, methods for compensation for constant mixing ratios were investigated, and it was proved that metering orifice replacements that could expand the cross sectional area of the stock solution inhaling piping was the most effective way for the improvement of form fire extinguishing systems' mixing ratios through foam proportioner venturi, foam chamber orifice, and metering orifice replacement experiments.

• Fire Science and Engineering
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• v.31 no.6
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• pp.74-82
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• 2017

Fires in buildings built using sandwich panels are difficult to extinguish, and the damage caused by the fire spreading through the inner core material is extensive. Sandwich panels consist of a nonflammable material on both sides of an insulation material. The types of insulation material include organic and inorganic insulation materials, but the former are used in more than 80% of the case. Organic insulation is economically advantageous compared to inorganic insulation, but it is vulnerable to fire. Therefore, the damage caused by sandwich panel fires is higher than that for general fires. In the case of the noxious gas analyzer test, the panel is tested with three round holes having a diameter of 25 mm, in order to determine the risk of the core material, but the cone calorimeter test is carried out using a sandwich panel. In this study, the cone calorimeter test was conducted to examine the fire risk of the composite material when heated on a nonflammable surface, exposed to the core material through a hole, and heated directly the core material. The type of organic insulation employed was flame retardant EPS (Expanded Polystyrene), and the test specimens were tested in three types of sandwich panel, a perforated sandwich panel and single core material. The purpose of this study is to propose a method of measuring the fire risk of the core materials of composite materials using the cone calorimeter test.

• Fire Science and Engineering
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• v.32 no.4
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• pp.75-85
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• 2018

The Grenpell tower fire in England in June of 2016 is a representative example of damage caused by a vertical fire spreading through external insulation. Organic insulation materials, which are widely used in external insulation, have the disadvantage that they have good insulation performance but are vulnerable to fire. Aluminum composite panels are used as exterior wall finishing materials, and plastics used in aluminum are regarded as the cause of vertical fire spread. Due to the steel frame used to secure the aluminum composite panel to the outer wall, a cavity is formed between the outer wall and outer wall finish. When a fire occurs on the outer wall, the flammable outer wall as well as the flame generated from the heat-insulating material spreads vertically through the cavity, resulting in damage to people and property. In Korea, material unit performance tests are carried out by the Ministry of Land, Infrastructure and Transport notice 2015 - 744. However, in the UK, the BS 8414 test is used to measure the vertical fire spreading time on the outer wall in real scale fire tests. In this study, the risk of external wall fire was evaluated in an actual fire by conducting a real scale wall fire test (BS 8414), which was carried out in Europe, using aluminum composite panels of semi-noncombustible materials suitable for current domestic standards. The purpose of this study was to confirm the limitations of material unit evaluation of finishing materials and to confirm the necessity of introducing a system to prevent the spread of outer wall fire through an actual scale fire test.

• Fire Science and Engineering
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• v.30 no.4
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• pp.65-72
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• 2016

This study examined the generation of combustion toxic gases of pinus rigida specimens processed with bis-(dimethylaminomethyl) phosphinic acid (DMDAP), bis-(diethylaminomethyl) phosphinic acid (DEDAP), and bis-(dibutylaminomethyl) phosphinic acid (DBDAP). Each pinus rigida plate was coated three times with 15 wt.% flame retardants in an aqueous solution. The specimens were then dried at room temperature. The production of combustion toxic gases was investigated using a cone calorimeter (ISO 5660-1). The first time to peak mass loss rate ($1^{st}-TMLR_{peak}$) processed with the chemical additives decreased to 5.9 from 41.2% compared with the unprocessed specimen. The second time to the peak mass loss rate ($2^{nd}-TMLR_{peak}$) for the processed specimens was decreased 1.8% for DMDAP and 5.3% for DBDAP and increased 1.8% for DEDAP. The peak carbon monoxide ($CO_{peak}$) production was 1.5 to 2.0 times higher than that of the unprocessed plate. The peak carbon dioxide ($CO_{2peak}$) production was reduced 0.01 times for DMDAP and increased 1.15 to 1.19 times for DEDAP and DBDAP compared with the unprocessed specimens. In particular, the oxygen concentration was much higher than 15%, which can be fatal to humans and the resulting hazard can be eliminated. Overall, the combustion toxicity of flammable gas were increased partially by the chemical additives compared with those of the unprocessed plate.

• Fire Science and Engineering
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• v.21 no.3
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• pp.15-23
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• 2007

In the events of a fire in the residential building, highly flammable polyurethane foam sofa produce toxic smokes. In this type of fire, the residents of the building can be gotten into the difficulties of evacuating from the fire places or may be to death due to a lot of hot toxic gases. In this study, CFD simulations were carried out to study the effects of the openings of stairwell on the fire characteristics of fire room and stairwell. Also, analysis of fire hazard based on the tenability limits of fire and FED(fractional effective dose) was performed to evaluate the life safety of the residents of the building. In the fire room, maximum temperature was about $290^{\circ}C$, maximum CO concentration was about 4,740 ppm, and the time to incapacitation of residents in fire room was about t=144 s. In the stairwell, temperature and CO concentration in the condition of openings to be open were even lower than those in it to be closed. Time to the tenability limit with respect to smoke visibility in the stairwell with openings, which was open, was shorter than that of it without openings to be open. It has been shown from this study that opening the stairwell openings is able to decrease the fire hazards to the life safety in the multi-story residential building fire.

• Fire Science and Engineering
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• v.30 no.1
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• pp.24-30
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• 2016

Autoignition characteristic is an important factor of all combustible substances, and a critical determinant in assessing the effectiveness of fire hazard prevention. This study investigated the autoignition characteristic of mixtures of Ethylene Glycol and water using an ASTM D2155 type ignition temperature measuring apparatus. It was possible to get the minimum temperature as $434^{\circ}C$ from 100% Ethylene Glycol within range of $75{\sim}160{\mu}l$. A volume of $100{\sim}125{\mu}l$ of a mixed sample of Ethylene Glycol and water (80 : 20) was ignited at the same temperature ($434^{\circ}C$). Also it was possible to get the auto ignition temperature as $437^{\circ}C$ from a mixed sample of Ethylene Glycol and water (60 : 40) within range of $120{\sim}160{\mu}l$. The instantaneous ignition temperatures determined for $125{\mu}l$ of each of the three samples were $579^{\circ}C$, $595^{\circ}C$ and $611^{\circ}C$, respectively. Both auto ignition temperatures and instantaneous ignition temperatures were increased through the addition of water to the samples.

• Applied Chemistry for Engineering
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• v.19 no.5
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• pp.466-470
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• 2008

The objective of this study is to convert methane into hydrogen using a nanoporous catalyst in the $CO_2$ containing syngas generated from the gasified waste. For the purpose, $Ni/Al_2O_3$ catalyst was prepared with the one-pot method. According to analyses of the catalyst, three dimensionally linked sponge shaped particles were created and the prepared nanoporous catalysts had larger surface area and smaller particle size and more uniform pores compared to the sphere shaped commercial catalyst. The catalyst for reforming reaction gave the highest $CH_4$ conversion of 91%, and $CO_2$ conversion of 92% when impregnated with 16 wt% of Ni at the reaction temperature of $750^{\circ}C$. At that time, the prepared catalyst remarkably improved the $CH_4$ and $CO_2$ conversion up to 20% compared to the commercial one.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.3
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• pp.286-293
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• 2020

In this study, we tried to verify the correlation of the amount of combustible industrial by-products, household waste used as fuels on cement sintering process and the amount of NOx, and CO, harmful components in the exhaust gas. The analysis uses coal as natural fuel, soft plastics (plastics with properties that tend to be scattered by wind, such as vinyls), hard plastics (plastics with properties that are not scattered by wind, such as PETs, wate rubbers), and reclaimed oils as alternative fuels. Utilizing the response surface analysis (RSM) technique using the process data of 2019, such as the fuel input and combustion temperature of a domestic A cement manufacturer's sintering facilities as independent variables, and the NOx, and CO emissions to the stack as dependent variables. Correlation was analyzed. As a result, it was confirmed that the impact on the emission material differs for each waste. In particular, it was analyzed that the hard plastics increase the CO emission but have an excellent effect of reducing NOx.

• Korean Journal of Materials Research
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• v.5 no.6
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• pp.644-649
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• 1995

The sinterability and the microstructure of Al doped UO$_2$-6wt%Gd$_2$O$_3$pellets, which were doped using Al(OH)$_3$, ADS(aluminium distearate), Al(OH)$_3$+ ADS mixture and sintered at 1$700^{\circ}C$ for 4h in H$_2$, atmospheres, were examined. The sintered densities of Al doped UO$_2$-6wt%Gd$_2$O$_3$pellets were more than 94% T.D.. The open porosity in ADS doped pellets was dramatically decreased. And the amounts of pores less than l${\mu}{\textrm}{m}$ and larger than 10${\mu}{\textrm}{m}$ were decreased regardless of the kinds of doped Al compounds. And the average pore size of Al doped UO$_2$-6wt%Gd$_2$O$_3$pellets was ranged between 2 and 3${\mu}{\textrm}{m}$. While grain structure of non-doped UO$_2$-6wt%Gd$_2$O$_3$pellets was revealed to be duplex type (rocks in sands), that of Al doped pellets to be uniformly equiaxid type. Especially, the grain size in ADS doped pellets was averaged to 4.6${\mu}{\textrm}{m}$.