• Resources Recycling
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• v.3 no.1
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• pp.17-24
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• 1994

Recovery of precious metal values from petrochemical spent catalyst is important from the viewpoint of environmental protection and resource recycling. Two types of spent catalysts were used in this study. One used in the manufacture of ethylene contains 0.3% Pd in the alumina substrate. The other used in oil refining contains 0.3% Pt and 0.3% Re. Both spent catalysts are roasted to remove volatile matters as carbon and sulfur. Then, metallic Pd powder from Pd spent catalyst is obtained in the course of grinding, hydrochloric acid or aqua regia leaching and cementation with iron. For the recovery of Pt and Re from Pt-Re spent catalyst, Pt and Re are leached with either HCI or aqua regia, first. Metallic Pt powder is recovered from the leach solution by cementation with Fe powder. Re in sulfide form is precipitated by the addition of sodium sulfide to the solution obtained after Pt recovery. It is found that 6N HCI can be successfully used as leaching agent for both types of spent catalyst. 6N HCI is considered to be better than aqua regia in consideration of reagent and equipment cost.

• Journal of the Korean Institute of Gas
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• v.3 no.3 s.8
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• pp.23-28
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• 1999

Variation of explosion characteristics by the blocks in closed vessel was investigated to analyse the effect of the block volume(volume blockage) and the surface area of the blocks(ratio of block surface area to vessel volume). Volume and surface area of blocks in explosion vessel were changed by the combination of blocks. The volume of explosion vessels was 270 liter, and the LPG-air or NG-air mixtures were ignited by the electric spark. Explosion pressure was measured with the strain type pressure transducer. From the experimental results, explosion pressure was decreased by the increase of the volume blockage and the block surface area. And the decrease of explosion pressure was more affected by the volume blockage than the surface area.

• Journal of the Korean Institute of Gas
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• v.20 no.1
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• pp.62-67
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• 2016

Natural gas, one of the cleanest fossil fuel, is liquefied to reduce its volume for the long distance transportation. Small size floating liquefied natural gas plant has small area that safe issue is highly considered. However, Dual Mixed Refrigerants (DMR) process has fire potential by using flammable refrigerants and N2 Expander process has low compressed energy efficiency which has high inherent process safety. Therefore, safe process with high compressed energy efficiency is constantly needed. This study suggested an alternative refrigerants to existing DMR process by using Hydrofluorocarbon which has high safety due to its non-flammable properties. As a result, it showed 34.8% lower compressed energy efficiency than DMR process that contains fire potential whereas 42.6% improved compressed energy efficiency than Single N2 Expander process. In conclusion, this research proposed safe process for small size floating liquefied natural gas plant while having high efficiency.

• Fire Science and Engineering
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• v.18 no.1
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• pp.1-6
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• 2004

In the reutilization process using limonene, the organic solvent to reduce volume of EPS, the AIT was measured with the variation of concentration and volume of mixture, in order to present the fund-mental data on the fire hazard assessment of limonene - EPS mixture at storage and handling. And ignition zone was compared with non-ignition zone. The equation related to AIT, activation energy and ignition delay time, used by the most scientific basis for predicting AIT values, was suggested using linear regression analysis as ln t = 0.704/T-5.819. And the equation related to concentration of mixture and AIT was also suggested to predict ignition hazard of combustible mixture using nonlinear regression analysis as $T_m/=248.32+69.27X+172.60X^2$. It enabled to predict ignition temperature according to variation of ignition delay time and concentration of mixture by the suggested equations.

• Fire Science and Engineering
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• v.32 no.3
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• pp.8-13
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• 2018

It was conceived from the realization that there was a lack of studies on the fire risk compared to utility and importance of plastic which is widely used. In this study, the fire hazard of five types of plastic products was measured by Cone Calorimeter (ISO 5660-1). As a result, the time to ignition (TTI) of polyvinyl Chloride (PVC) plate delayed TTI (196 s), and polystyrene (PS) plate had the shortest TTI of 19 s. The total heat release (THR) of PS plate was measured at 213.07 % higher than the lowest measured PVC plate. Also, the PS plate will have 1.45 to 4.21 times higher $CO_2$ than other plastics, resulting in the highest incomplete combustion and the greatest possible damage of life. Thus, assessing the risk of fire revealed that PS plate is the most dangerous and PVC is the safest.

• Journal of the Korean Institute of Gas
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• v.2 no.3
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• pp.25-36
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• 1998

Explosion and fires can occur in all segments of chemical and petroleum industries because of complexity of process, usage and storage of flammable and reactive chemicals, and operating conditions of high pressure and temperatures. Especially chemical plants have high possibility of the occurrence of BLEVE(Boiling Liquid Expanding Vapor Explosion)and Fireball. In this study, a computer program was developed for the effect assessment of BLEVE and Fireball. BLEVE was analysed by three explosion models of physical explosion model, isothermal expansion model and adiabatic expansion model and Fireball using solid model. The parametric sensitivity analysis has been done for the models of BLEVE and Fireball. The damage by BLEVE and Fireball of Benzene and Toluene and m-Xylene were estimated.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.23 no.8
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• pp.996-1003
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• 2019

The undergrounding of diverse ground facilities has led to a decrease in issues, such as foul smell of water supply systems and wastewater, a fall of telephone poles, electromagnetic waves and breaking of wires caused by a railway work. On the other hand, there are new issues, including a fall accident, explosion affected by flammable gas, a choking accident by harmful gas and a lack of oxygen concentration, a fire coming from high-tension wire heating and flooding in the manhole. Besides, these issues damage the civil society and are an anxiety to public safety. Therefore, this paper is focused on a smart manhole device for stable communication environments inside and outside the manhole and wireless communication with various devices for managing facilities in the manhole, and aims to make a contribution to public safety by suggesting a direction of future underground facility management.

• Journal of the Korean Institute of Gas
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• v.23 no.3
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• pp.40-45
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• 2019

Flash point is the important flammability indicator characterizing the risk of fire and explosion of flammable liquid mixture. In this study, flash points of water+formic acid and water+acrylic acid were measured by Seta flash apparatus. The flash points estimated by the methods based on empirical equation and Raoult's law were compared with experimental flash points. Absolute average errors of the results estimated by Raoult's law are $10.7^{\circ}C$ and $4.8^{\circ}C$ for water+formic acid and water+acrylic acid, respectively. Absolute average errors of the results estimated by empirical equation are $1.0^{\circ}C$ and $0.5^{\circ}C$ for water+formic acid and water+acrylic acid, respectively. In conclusion, the estimated values by empirical equation simulated the measured values better than those calculated by Raoult's law.

• Fire Science and Engineering
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• v.32 no.6
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• pp.55-62
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• 2018

To improve the prediction result with enhanced reliability of domestic Performance-Based Design (PBD), actual scale fire tests were carried out on products made of plastics from sales facility combustibles. The commercial buildings were separated into single and multiple combustibles for the experimentation of fire spread caused by the sales shelves where the various combustible materials are displayed. A according to the maximum heat release rate, exposed area and weight of the combustible material, the results revealed a linear relationship of as 93% and 89%. In addition, analysis of the gas concentrations for various combustibles showed that $CO_2$ has a linear relationship, whereas the CO concentration indicated exponential function. These results can be applied to reliable fire source information in PBD of plastic fire source in commercial buildings. This may be applied as fire source information representative of a plastic fire in commercial buildings through additional experiment using the area of the shelf in actual commercial buildings.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.2
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• pp.139-165
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• 2019

The current status and prospect of decommissioning technology development at KAERI are reviewed here. Specifically, this review focuses on four key technologies: decontamination, remote dismantling, decommissioning waste treatments, and site remediation. The decontamination technologies described are component decontamination and system decontamination. A cutting method and a remote handling method together with a decommissioning simulation are described as remote dismantling technologies. Although there are various types of radioactive waste generated by decommissioning activities, this review focuses on the major types of waste, such as metal waste, concrete waste, and soil waste together with certain special types, such as high-level and high-salt liquid waste, organic mixed waste, and uranium complex waste, which are known to be difficult to treat. Finally, in a site remediation technology review, a measurement and safety evaluation related to site reuse and a site remediation technique are described.