• Title/Summary/Keyword: 가시광선 조사

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Photocatalytic activity of Fe treated AC/TiO2 composites between visible light and UV light irradiation (가시광선과 UV광선에 의한 Fe 처리된 AC/TiO2 복합체의 광분해활성)

  • Meng, Ze-Da;Zhang, Kan;Oh, Won-Chun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1760-1767
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    • 2010
  • FAT compounds photocatalysts were prepared with $TiOSO_4{\cdot}xH_2O$ (TOS) by a sol-gel method. The samples were characterized by scanning electron microscopy (SEM), BET specific surface area, X-ray diffraction analysis (XRD) and energy dispersive X-ray spectroscopy (EDX). The SEM results showed that ferric compounds and titanium dioxide were fixed onto the AC surfaces. The XRD results showed that Fe-AC/$TiO_2$ composites mostly contained anatase phase. EDX showed the presence of C, O, and Ti with Fe peaks in all samples. The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution, via compare photodegradation of MB solution under visible light and UV light separately. Fe-AC/$TiO_2$ composites had an excellent photocatalytic under strong visible light irradiation. A small amount of Fe ions in AC/$TiO_2$ particles could obviously enhance their photocatalytic activity.

Photodegradation of Cellulosics(Part II) - Chemical Properties of Irradiated Cotton - (Cellulose의 광분해에 관한 연구(II) - 광조사된 면섬유의 화학적 성질을 중심으로 -)

  • 전경숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.1
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    • pp.15-22
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    • 1994
  • The formation of carbonyl group was dominant to other functional groups. Concentrations of both carboxyl and peroxide groups were found to rapidly reach low steady state values that increased slightly with increa-sing temperature and relatice humidity. Since the deg-radation of cellulose samples was in the initial stage and the conversion of glycosidic bonds and hydroxyl groups were very small, it was found that changes in the physical and chemical properties could be fitted to a first-order reaction model.

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Effects of Photodynamics Therapy on the Acne Skin without Light Sensitive Material (광민감물질이 배제된 광선역학요법이 여드름 피부에 미치는 효과)

  • Park, Seon-Nam;Kim, Kyung-Yun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3131-3138
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    • 2015
  • At a dermatology during the skin care, photodynamic therapy(PDT) is carried after 5-aminolevulinic acid(ALA), light sensitive material, is applied. At a skin care shop, using drug is prohibited. Thus, the aim of this research was to see the effect of the acne skin by irradiating PDT to the skin without applying ALA. The research method was that 24 female undergraduates who had acne on their face at the level of mild or comedonal, and the participants were divided into four groups(group1: no treatment, group 2: 420 nm of blue visible light, group 3: 660 nm of red visible light and group 4: blue and red visible light). The participants of group 2, 3 and 4 were irradiated with visible light for 20 minutes per week for 6 weeks, and they were compared to group 1. As a result of the research, the number of erythema, sebum, papules and pustules of those who were irradiated with visible light decreased, and the pore size of those also decreased while the amount of moisture increased. If an skin care shop applies PDT to the existing acne skin care, that PDT will influence on the program of a skin care shop is expected.

Defect Inspection of Extreme Ultra-Violet Lithography Mask (극자외선 리소그래피용 마스크의 결함 검출)

  • Yi Moon-Suk
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.8 s.350
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    • pp.1-5
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    • 2006
  • At-wavelength inspection system of extreme Ultra-violet lithography was developed and the inspection results were compared with the optical mask inspection system by cross correlation experiments. In at-wavelength EUV mask inspection system, a raster scan of focused euv light is used to illuminate euv light to mask blank and specularly and non-specularly reflected euv light are detected by photo diode and microchannel plate. The cross correlation results between at-wavelength inspection tool and optical inspection tool shows strong correlation. Far-field scattering fringe pattern from programmed phase and opqque defect, which were detected by phosphor plate and CCD camera shows that distinct diffraction fringes were observed with fringe spacing dependent on the defect size.

STARSPOT MODEL OF RS CVn TYPE BINARY SZ PSC (RS CVn형 쌍성 SZ Psc의 흑점 모델)

  • 강영운
    • Journal of Astronomy and Space Sciences
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    • v.17 no.2
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    • pp.189-198
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    • 2000
  • The emission lines of the ultraviolet region and the light curves of the optical region have been analyzed to investigate the distorted light curves of SZ Psc. The Mg II emission lines of the IUE spectra confirmed that the chromospheric activity of SZ Psc occurs on the K1 IV star. The distorted light curves in the optical region have been analyzed by the spot model where the spots are on the K1 IV star as the result of the chromospheric activity. The complete photometric solution could be deduced for SZ Psc by the good fitness with the spot model.

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High School Student Perception of the Relationships between Solar and Visible Radiation and between Terrestrial and Infrared Radiation (태양 복사와 가시광선 복사 및 지구 복사와 적외선 복사의 관계에 대한 고등학생들의 인식)

  • Lee, Jong-Jin;Seo, Eun-Kyoung;Ahn, Yumin
    • Journal of the Korean earth science society
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    • v.43 no.2
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    • pp.312-323
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    • 2022
  • This study began with the hypothesis of whether "solar radiation" and "terrestrial radiation" can be replaced by "visible radiation" and "infrared radiation", respectively. To this end, we investigated the perceptions of high school students who completed the Earth Science I course through a questionnaire to reveal how they perceived each concept. We also analyzed the descriptions and illustrations of textbooks that may have affected their perceptions. All of the students who participated in the questionnaire recognized solar radiation as radiation emitted only in the visible light region. About 35% of the students recognized convection, conduction, and latent heat as energy transfer by radiation in the Earth's heat budget. By analyzing six types of Earth Science I textbooks in the 2015 revised curriculum, we observed that two types introduced the terms "shortwave radiation" and "longwave radiation" but had no explanation for them, while the other two described solar radiation as "radiation mainly in the visible light region" or "radiation in short wavelengths". Regarding solar and terrestrial radiation in the last two types, there was no explanation for the wavelength regions, or ambiguous terms such as "short wavelength" and "long wavelength" were used. In addition, the two textbooks contained some errors in the illustration of the energy budget. Considering that textbooks described solar and terrestrial radiation without defining the exact terms for shortwave and longwave radiation, learners are likely to recognize solar and terrestrial radiation as visible and infrared radiation, respectively. This finding implies that vague statements or errors in textbooks can cause or reproduce students' misconceptions. The discussion in this study is expected to be used as a helpful reference material for teaching and learning processes regarding the Earth's radiation equilibrium and heat budget, and thereby contribute to proposing reasonable description plans for future textbook writing.

Photocatalysis of Sub-ppm-level Isopropyl Alcohol by Plug-flow Reactor Coated with Nonmetal Elements Irradiated with Visible Light

  • Jo, Wan-Kuen
    • Clean Technology
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    • v.18 no.4
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    • pp.419-425
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    • 2012
  • This work explored the characteristics and the photocatalytic activities of S element-doped $TiO_2$ (S-$TiO_2$) and N element-doped $TiO_2$ (N-$TiO_2$) for the decomposition of gas-phase isopropyl alcohol (IPA) at sub-ppm concentrations, using a plug-flow reactor irradiated by 8-W daylight lamp or visible light-emitting-diodes (LEDs). In addition, the generation yield of acetone during photocatalytic processes for IPA at sub-ppm levels was examined. The surface characteristics of prepared S- and N-$TiO_2$ photocatalysts were analyzed to indicate that they could be effectively activated by visible-light irradiation. Regarding both types of photocatalysts, the cleaning efficiency of IPA increased as the air flow rate (AFR) was decreased. The average cleaning efficiency determined via the S-$TiO_2$ system for the AFR of 2.0 L $min^{-1}$ was 39%, whereas it was close to 100% for the AFR of 0.1 L $min^{-1}$. Regarding the N-$TiO_2$ system, the average cleaning efficiency for the AFR of 2.0 L $min^{-1}$ was above 90%, whereas it was still close to 100% for the AFR of 0.1 L $min^{-1}$. In contrast to the cleaning efficiencies of IPA, both types of photocatalysts revealed a decreasing trend in the generation yields of acetone with decreasing the AFR. Consequently, the N-$TiO_2$ system was preferred for cleaning of sub-ppm IPA to S-$TiO_2$ system and should be operated under low AFR conditions to minimize the acetone generation. In addition, 8-W daylight lamp exhibited higher cleaning efficiency of IPA than for visible LEDs.

Preparation of UV Curable Anti-Glare Coating Films Using Micrometer-Sized Silica Particles (마이크로미터 크기의 실리카 입자를 이용한 UV 경화형 눈부심 방지 코팅 필름 제조)

  • Kim, Tae Hyoung;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.165-173
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    • 2021
  • Anti-glare (AG) coating films are applied to various display fields such as liquid crystal displays, LED lighting, and touch panels. In this study, micrometer-sized silica particles were added as fillers in the UV-curable coating solutions to provide anti-glare effect. During this process, the effects of the particle size, content, stirring time, and mixing ratio of silica particles of different sizes were investigated on the haze values and visible light transmittance of the coating films. As a result, as the size of the silica particles increased and the content of the silica particles increased, the haze values increased, but the visible light transmittance decreased. On the other hand, the stirring time did not significantly affect the haze value and transmittance of coating films. In addition, as the mixing ratio of large-sized silica particles increased, the haze value increased, but on the contrary, the visible light transmittance decreased.

Photocatalytic Degradation of Rhodamine B Using Cd0.5Zn0.5S/ZnO Photocatalysts under Visible Light Irradiation (가시광선하에서 Cd0.5Zn0.5S/ZnO 광촉매를 이용한 로다민 B의 광분해 반응)

  • Lee, Hyun Jung;Jin, Youngeup;Park, Seong Soo;Hong, Seong Soo;Lee, Gun Dae
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.356-361
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    • 2015
  • $Cd_{0.5}Zn_{0.5}S/ZnO$ composite photocatalysts were synthesized using the precipitation method and characterized by XRD, UV-vis DRS, PL and FE-SEM. Photocatalytic activities of the materials were evaluated by measuring the degradation of rhodamine B under visible light irradiation. Contrary to ZnO, $Cd_{0.5}Zn_{0.5}S/ZnO$ materials absorb visible light as well as UV and their absorption intensities in visible region increased with increasing the $Cd_{0.5}Zn_{0.5}S$ amount. The increment in the $Cd_{0.5}Zn_{0.5}S$ content in $Cd_{0.5}Zn_{0.5}S/ZnO$ also leads to reducing the particle size and consequently increasing the specific surface area. $Cd_{0.5}Zn_{0.5}S/ZnO$ materials with the larger $Cd_{0.5}Zn_{0.5}S$ content showed the higher activity in the photocatalytic degradation of rhodamine B under visible light irradiation. Therefore, the heterojunction effect between $Cd_{0.5}Zn_{0.5}S$ and ZnO as well as the adsorption capacity seems to give important contributions to the photocatalytic activity of the $Cd_{0.5}Zn_{0.5}S/ZnO$.

Photocatalytic Dye Decomposition Effect of Binary Copper (I) Selenide-graphene Nanocomposites Synthesized with Facile Microwave-assisted Technique (용이한 마이크로웨이브 조사법을 사용하여 합성한 이원계 Cu (I) 셀렌 그래핀 나노복합체의 광촉매 염료분해 효과)

  • Ali, Asghar;Oh, Won-Chun
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.483-489
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    • 2016
  • Here, we examined the photo-degradation efficiency of $Cu_2Se$-graphene nanocomposites synthesized by a facile and fast microwave-assisted technique. The prepared composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, XPS and UV-Vis spectrophotometry. The photocatalytic performance was studied through the decomposition of Rhodamine (Rh B) as a standard dye under visible light radiation. A 95% of Rh B degradation after visible light irradiation for 180 min indicates that the $Cu_2Se$-graphene composite exhibited significant photodegradation efficiency. Therefore, it can be concluded that the synthesized $Cu_2Se$-graphene can be used as a suitable catalyst for decomposing dye pollutants.