• Title/Summary/Keyword: 가스-액체

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고체 수소를 이용한 군용 연료전지 차량

  • 이부윤
    • Journal of the KSME
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    • v.44 no.1
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    • pp.27-27
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    • 2004
  • 미국 국방부 소속 육군차량사업부(National A Automotive Center)는 대체에너지를 이용한 군용 차량 개발을 위해 Michigan 주 Rochester Hills에 위치한 E Energy Conversion Devices(ECD) 사와 일부 기술 개발 에 대한 기술 제휴를 한다고 발표했다. 국방부는 태양전 지와 수소를 연료로 사용하는 대체에너지 차량을 개발하 기 위해 ECD에 1단계 연구에 필요한 연구비를 지원했다. 이번 연구에는 연료전지를사용한차량개발을위해 5 500,$\omega$0달러가 투자되는데, Texaco Ovollic Hydrogen S Systems(TOHC)의 고체 휴대용 수소 연료와 채충천 (refueling) 시스탬이 주요 개발 목표로 설정됐다. ECD의 역할은 최근 개발된 Toyota Prius에 시범 적으로 장착된 저압 고체형 수소 저장 시스템의 기술을 군용 차량에 알맞게 전환시키는 것이다. TOHC와 ECD가 개발한 고체형 수소 보관 시스댐은 고압을 요구하는 연료전지 차량의 수소 저 장 시스템이 갖고 있는 많은 문제점들을 해결할 수 있을 것으로 기대되는 연료전지를 이용한 엔진 개발 중 최신 기술이다. 특히 전투 상황에서 차량이 폭발하기 쉬운 수소 저장 탱크를 장착한 채 전 장으로간다는 것은적에게 노출 될 경우자살과마찬가지인 치명적인 피해를 입을수 있다. 이 프로젝트의 개요를 살펴보면, 수소 저장 시스템은 적어도 약 lOkg의 수소를 적은 용적 내에 낮은 압력에서 안전하게 고체 상태로 저장할 수 있다. 이 고체 저장 용기는 하루에 두 번 1.7kg의 수소를 10분 이내에 재급유할 수 있다. 수소는대부분고압가스형태나저온액체 형태로보관된다. 기체나액체 형태의 수소는 연료전 지에 사용되기에는 적합하지 않은 점이 많다. Ovonie 수소 저장 방법은 수소를 저압 고체 형태 ( (metal hydride)로 보관하는 방법으로, 고압 기체나 저온 액체가 갖고 있는 많은 문제점들을 해결 할수있다. 그림을 참조하면 고체 형태의 수소 보관 방법이 다른 보관 방법에 비교해 단위 체적당 최고 6배 많은수소질량을보관할수 있다. 이 고체 형태의 보관방법은수소가적절한합금과평형 압력 이 상의 환경에 놓일 경우 합금에 홉착되는 현상을 이용하고 있다. 수소를 흡수한 합금은 새로운 특성 을 가진 metal hydride로 변하게 된다. 이 과정 에서 열이 부산물로 발생한다. 반대로 수소를 metal hydride로부터 분리시키기 위해서는 합금을 가열해야 한다.

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Evaluation of the Inherent Flow Coefficient of the Control Valve in the Liquid Propellant Rocket Engine (액체로켓 엔진 성능 보정용 제어밸브의 고유유량특성 계산)

  • Park, Soon-Young;Cho, Won-Kook;Seol, Woo-Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.4
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    • pp.73-78
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    • 2011
  • When a liquid rocket engine - specifically for the gas-generator cycle engine has throttle valves to control the thrust level and mixture ratio of the engine, it is possible to adjust the inherent flow characteristics of the control valves in order to secure a linearized correlation between the control-process-parameters like the thrust or mixture ratio of an engine and the throttle angle of valve. These linearities can reduce the complexity of the control process and make the process more explicit by ensuring the intuitive control. In this point, we proposed an algorithm within the frame of the in-house-developed program to obtain the control valves' inherent flow characteristics which satisfy the linearity, and calculated the sensitivities of control valves with respect to the throttle angle. Also, we compared the obtained inherent flow characteristics with the existed data and concluded the results are satisfactory.

Evaluation of the Inherent Flow Coefficient of the Control Valve in the Liquid Propellant Rocket Engine (액체로켓 엔진 성능 보정용 제어밸브의 고유유량특성 계산)

  • Park, Soon-Young;Cho, Won-Kook;Seol, Woo-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.585-589
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    • 2010
  • It is important for the liquid rocket engine to meet the exact performance requirements in order to guarantee the successful mission of the launch vehicle. Usually, a ground combustion test for the engine is conducted to reduce the performance error and for the tuning. For the gas-generator (GG) cycle engine, this adjustment process can be easily tuned by means of the control valves. A linearized correlation between the process parameters of the control - the combustion chamber pressure and the mixture ratio of engine - and the independent parameter of the control- rotational angle of the control valve - could be suitable to reduce the tuning errors. Also this linearity can reduce the effort for the tuning and make the process more explicit by ensuring a more intuitive control. In this point, we proposed an algorithm in the frame of the in-house-developed program to obtain the control valves' inherent characteristics which satisfy the linearity.

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Cycloaddition and Crosslinking Reactions of CO2 and Glycidyl Methacrylate using Ionic Liquid (이온성 액체를 이용한 CO2와 glycidyl methacrylate의 고리화 첨가 및 고분자 가교 반응)

  • Kim, Dong Hyun;Kang, Tae Won;Lee, Jong Jib;Ko, Young Soo
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.342-346
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    • 2013
  • In this study the cycloaddition of glycidyl methacrylate (GMA) and $CO_2$ using ionic liquid as catalyst was performed for the technology of $CO_2$ reduction. The structure of synthesized cyclic carbonate, [2-oxo-1,3-dioxolan-4-yl]methacrylate (DOMA) was analyzed and confirmed by FT-IR and $^1H$-NMR. The change in conversion with respect to reaction time was investigated using $^1H$-NMR. Interestingly, the ionic polymerization of vinyl groups and crosslinking reaction between cyclic carbonate rings of DOMA were observed following completion of cycloaddition.

Development of Smart Cargo Level Sensors Including Diagnostics Function for Liquid Cargo Ships (액체운반용 선박을 위한 진단기능을 가지는 스마트 카고 센서 개발)

  • Bae, Hyeon;Kim, Youn-Tai;Park, Dae-Hoon;Kim, Sung-Shin;Choi, Moon-Ho;Jang, Yong-Suk
    • Journal of the Korean Institute of Intelligent Systems
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    • v.18 no.3
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    • pp.341-346
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    • 2008
  • This paper is to develop a monitoring system with diagnosis for smart cargo sensors that is for management and maintenance of the liquid cargo ships. The main goal of the system is to achieve the total automation system of the cargo sensor. By this study, the active smart sensor for the liquid cargo ships is designed and developed that guarantees high-confidence, stability, and durability. The proposed system consists of a monitoring part of the steam pressure, high-level monitoring, over flowing monitoring, gas monitoring, and tank temperature monitoring. The signals transferred from each unit system are used for sensor diagnosis based on confidence and accuracy. Finally, in this study, the total supervisory monitoring system is developed to maintain and manage the cargo effectively based on fault diagnosis and prognosis of the each sensor system.

Research Trend and Histories of Rocket Engines using Hydrogen Peroxide and Liquid Methane as Green Propellants (친환경 추진제인 과산화수소와 액체메탄의 활용 역사와 연구 동향)

  • Kim, Sun-Jin;Lee, Yang-Suk;Ko, Young-Sung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.4
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    • pp.46-58
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    • 2010
  • Hydrogen peroxide(HP) and liquid methane have deserved renewed considerations as green propellants in recent years, because main design concerns in the development of the new generation propulsion system for spacecrafts are concentrated on low operation cost and environmental cleanness. Although HP has a long history of application to aerospace propulsion systems due to high density, mono-propellant characteristics and low toxicity, it had been replaced by hydrazine and liquid oxygen due to extreme performance requirement during the cold war. But HP has received a renewed interest due to its increased stability and many researches have been conducted to develop high performance LREs(Liquid Rocket Engines) using HP. Liquid methane has also received a new interest in rocket propulsion system for the future space exploration according to its possibility of ISRU(In-Situ Resource Utilization).

Zeolite Based Membrane for Removal of Ammonium: A Review (효소 고정화막의 응용에 대한 총설)

  • Lee, Joo Yeop;Patel, Rajkumar
    • Membrane Journal
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    • v.32 no.3
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    • pp.173-180
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    • 2022
  • Presence of ammonia in drinking water is very toxic to human health. Soluble ammonia contaminates ground water due to activities such as the use of fertilizer in crop, industrial effluents and burning of fossil fuel. Even low concentration of ammonia present in water will damage aqua environment such as marine organism. Membrane technology is an important process to remove ammonia from effectively from water. Flat sheet membrane, membrane contactor and membrane distillation are some of the methods used for water purification from ammonia. Membrane contractor is an efficient process in which ammonia is removed through liquid-gas or liquid-liquid mass transfer without change of phase unlike membrane distillation. However, the cost of ammonia removal in this method is high due to maintenance of very high pH. Zeolite has excellent ion exchange ability that enhances its ability to interact with ammonia and adsorb from wastewater. Mixed matrix membranes containing zeolite enhance the efficiency of ammonia adsorption and separation from wastewater. In this review the above discussed issues are summarized in detail.

Development Trends of Liquid Methane Rocket Engine and Implications (액체로켓 메탄엔진 개발동향 및 시사점)

  • Lim, Byoungjik;Kim, Cheulwoong;Lee, Keum-Oh;Lee, Keejoo;Park, Jaesung;Ahn, Kyubok;Namkoung, Hyuck-Joon;Yoon, Youngbin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.2
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    • pp.119-143
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    • 2021
  • Selecting liquid methane as fuel is a prevailing trend for recent rocket engine developments around the world, triggered by its affordability, reusability, storability for deep space exploration, and prospect for in-situ resource utilization. Given years of time required for acquiring a new rocket engine, a national-level R&D program to develop a methane engine is highly desirable at the earliest opportunity in order to catch up with this worldwide trend towards reusing launch vehicles for competitiveness and mission flexibility. In light of the monumental cost associated with development, fabrication, and testing of a booster stage engine, it is strategically a prudent choice to start with a low-thrust engine and build up space application cases.

Ionic Liquid Consisted of Composite Membrane for Carbon Dioxide Separation: A Review (이산화탄소 분리를 위한 이온성 액체 기반 복합 멤브레인: 총설)

  • Young Simon Shi Young;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.5
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    • pp.240-247
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    • 2023
  • Even among gas separation methods, CO2 capture and separation via membranes is an ever-growing field, with many different membrane compositions continually being developed. Ionic liquid (IL) based composite membranes show excellent performance values in separating CO2. Similarly, various copolymer/IL composite membranes also display improved performance. The addition of fillers such as graphene oxide to these copolymer/IL composite membranes shows a further enhanced version of these fillers, most likely due to the strong interactions that occur between ILs and organic fillers, which consequently improves factors such as the affinity, selectivity, and adsorption of CO2. Copolymer/IL composite membranes utilizing a metal-organic framework (MOF) showed improved CO2 permeability. This review discusses the study of various combinations of ionic liquid and copolymer composite membranes for carbon dioxide separation.

Treatment of Halogen Gases, BCl3 and CF4, used in Semiconductor Process by Using Inorganic Gas Adsorption Agents (무기흡착제를 이용한 반도체 공정에서 사용되는 할로겐 가스 (BCl3, CF4) 의 처리 및 측정에 관한 연구)

  • Lim, H.B.;Hwang, Cheong-Soo;Park, Jeong-Jun
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.368-374
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    • 2003
  • Halogen gases such as $BCl_3$ and $CF_4$ are among the most problematic gases used in semiconductor process. They raise serious environmental and health problems due to their extreme toxicity. This study is to develop a method to effectively remove those gases during the process by using various types of inorganic gas adsorption agents such as zeolite A, modified AgA zeolite, ZnO, and $AgMnO_3$, which have not been attempted in the conventional methods. The removal efficiencies of the gases were both qualitatively and quantitatively measured by a FT-IR spectrophotometer. The whole device for the measurement has been designed and built in our lab. The removal efficiencies of the gases were compared between those used resins. The experimental result revealed that ZnO showed the best removal efficiency for BCl3 gas that had removed 0.094 g per 1 g of the resin used. For $CF_4$ gas, none of the solid resins was able to remove the gas effectively. However, liquid $CHCl_3$ showed some removal ability of the $CF_4$ gas.