• Title/Summary/Keyword: 가스-액체

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The Calculation of Flash Point for n-Nonane+n-Decane+n-Tridecane System by Raoult's Law and Multiple Regression Analysis (라울의 법칙과 다중회귀분석법에 의한 n-Nonane+n-Decane+n-Tridecane 계의 인화점 계산)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.52-58
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    • 2018
  • The flash point is one of the most important properties to characterize fire and explosion hazard of flammable liquid mixture. In this paper, the flash points of ternary liquid mixture, n-nonane+n-decane+n-tridecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and multiple regression analysis. The absolute average errors(AAE) of the results calculated by Raoult's law is $0.6^{\circ}C$. The absolute average errors of the results calculated by multiple regression analysis is $0.4^{\circ}C$. As can be seen from AAE, the calculated values based on multiple regresstion analysis were found to be better than those based on Raoult's law.

Study on Temperature Drop Rate during Pressurant Discharge (가압제 토출시 온도강하율에 대한 연구)

  • Chung, Yong-Gahp;Hong, Moon-Geun;Kwon, Oh-Sung;Kim, Young-Mog
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.116-121
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    • 2006
  • The pressurization system in a liquid rocket propulsion system provides a controlled gas pressure in the ullage space of the vehicle propellant tanks. It is advantage to employ a hot gas heat exchanger in the pressurization system to increase the specific volume of the pressurant and thereby reduce over-all system weight. Therefore a significant improvement in pressurization system performance can be achieved, particularly in a cryogenic system. For this study air and $CN_2$ are employed as external fluid and pressurant respectively Numerical analysis on the pressurant discharging characteristics have been compared with the experimental results performed at the PTF(Propellant-feeding Test Facility). It is shown that the discrepancy of analytic and experimental results is within about ${\pm}15%$. It is estimated that the temperature drop rate of cryogenic pressurant immersed liquid oxygen can be predicted using this analytic approach method.

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A Study on the Improvement of Risk Assessment Items and Index for Sunken Ship (침몰선박 위해도 평가항목 및 평가지수 개선에 관한 연구)

  • Lee, Seung-Hyun;Choi, Hyuek-Jin;Suh, Jae-Joon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.6
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    • pp.704-711
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    • 2015
  • In this study, we have conducted a survey of AHP technique through the ocean experts to derive new items and revise assessment items and indices for risk of sunken ships based on the survey results. As a result of the survey, two new items such as accident cause and tidal current are derived. And it shows that existing items such as toxic liquid substance, remaining oil and explosive gas which were evaluated as one group are desirable to be evaluated respectively. Accordingly, we analyze the indices of the new eleven assessment items adjusted from the existing seven assessment items. As a result, the indices are ordered by toxic liquid substance, possibility of leaking, explosive gas, carrying capacity of fuel oil, sensitivity of sea environment, marine traffic environment, cause of accident, tidal current, keel clearance, ship type, and ship size. Especially, as compared with the indices of existing assessment items, the indices of sensitivity of sea environment and possibility of leaking are higher and the index of keel clearance is lower.

A Numerical Simulation of Regenerative Cooling Heat Transfer Processes for the Liquid Propellant Rocket Engine (액체추진제 로켓엔진의 재생냉각 열전달과정 전산모사)

  • 서호원
    • Journal of the Korean Society of Propulsion Engineers
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    • v.2 no.3
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    • pp.54-61
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    • 1998
  • A numerical simulation is attempted for the regenerative cooling heat transfer processes of the liquid propellant rocket engine. The heat transfer from the combustion gases to the thrust chamber wall is called gas side heat transfer. This heat is conducted radially to the coolant through the carbon deposit and metallic wall of thrust chamber Finally, this heat is convected away by the coolant flowing along the passages in the thrust chamber. The equivalence of these three heat fluxes of the above processes is utilized to determine the coolant side wall temperature, gas side wall temperature and the heat flux. When the number and shape(width, height) of coolant passages, the shape(size) of thrust chamber, oxidant and fuel properties, coolant properties, oxidant/fuel mixture ratio, coolant inlet temperature, the thickness of carbon deposit formed along the thrust chamber wall during combustion are given, reasonable radial direction temperature distributions and heat fluxes along the thrust chamber axis are obtained.

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A Study on the Release Rate of Hazardous Materials from Liquid Pipeline (액체배관으로부터 위험물질 누출속도 산정에 관한 연구)

  • Tak Song-Su;Jo Young-Do
    • Journal of the Korean Institute of Gas
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    • v.6 no.1 s.17
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    • pp.81-85
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    • 2002
  • This paper presents the calculation methods of liquid release rate in the transition region when hazardous materials leak from the pipeline due to an unwanted accident. For the laminar and turbulent flow region, liquid release rate from a pipeline can be calculated by using a commercial software or by using calculator based on the models(equations) suggested by Crowl and Louvar et al. However, there has been no corresponding model for the transition flow region. In this paper. we showed that the turbulent model may be used as an equation generally used in the transition region for conservative hazard analysis if safety factor $30\%$ is added to the value calculated by the turbulent model. In this regard, we first calculated the release rate from liquid pipeline in the transition region by using experimental data on Fanning friction factor depending on Reynolds number which Lap-Mou Tam et al. had introduced, then compared it with that of the laminar and turbulent models in transition region.

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Consequence Modeling Methodology for Prediction of Hazard Distance for Two-phase Flow Release from the Pressurized Chlorine Saturated Liquid Storage Tank (가압 염소포화액체 저장탱크의 2상 흐름 누출에 대한 유해위험거리의 예측을 위한 결과영향 모델링 방법론)

  • Song D. M.;Park Y. S.;Park J. K.
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.7-17
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    • 1998
  • This study is to develop the consequence modeling methodology for quantitative prediction of the hazard distance(or toxic buffer distance) for two-phase flow continuous releases from the pressurized chlorine saturated liquid storage tank of the chemical plant facilities. The source term modeling was peformed by the refined analysis method based on USEPA's guideline and SuperChems model self-calculation, respectively. The hazard distance was predicted for STEL, IDLH and ERPGs(ERPG-2 and ERPG-3) concentrations being used as the toxic regultaion concentration in hazard estimation. To use as hazard estimation guideline for the establishment of the emergency response planning, the effects of source characteristics and meteorological vaiations on the hazard distance was especially considered for ERPG-2 concentration.

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Ignition Characteristics of an Oxidizer Rich Preburner (산화제 과잉 예연소기 점화특성)

  • Moon, Il-Yoon;Moon, In-Sang;Hong, Moon-Geun;Kang, Sang-Hun;Yoo, Jae-Han;Ha, Seong-Up;Lee, Seon-Mi;Lee, Soo-Young
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.106-109
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    • 2012
  • It was designed and tested ignition that an oxidizer rich preburner for a staged combustion cycle liquid rocket engine propelled by kerosene and LOx. Operation conditions of the preburner are about 60 of OF ratio and 20 MPa of combustion pressure. Ignition characteristics were compared by propellants flowrate. As the results, the higher propellants flowrate, the shorter the ignition delay time and the higher ignition stiffness. The ignition delay time was affected by incoming the oxidizer flowrate through the refrigerative cooling channels. The oxidizer flowrate from the cooling channels decreased by inflow of combustion gas during initial ignition. The oxidizer flowrate of the cooling channels increases, it is rapid recovery by cooling effect, eventually the ignition delay time decreases.

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A Study on Prevention of Fire Accidents by Splash Filling in the Filtration Process of Pharmaceutical Companies (제약회사 여과 공정중 스플래쉬 필링에 의한 화재사고 예방대책에 관한 연구)

  • Kim, Sang Gil;Lee, Dae Joon;Yang, Seung Bok;Rhim, Jong Guk
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.29-34
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    • 2021
  • Flammable substances are often present in the raw materials of pharmaceutical products manufactured by pharmaceutical companies. In this case, an excessive amount of flammable substances is added to make an intermediate, and flammable substances that do not participate in the reaction are removed through filtration and drying steps. In addition, the flammable liquid separated in the filtration process is accumulated in the form of splash filling in the filtrate container. In this case, vapor and mist of flammable liquid are generated, which lowers the lower limit of explosion and minimum ignition energy, and increases the risk of fire and explosion due to complex charging. In this study, by analyzing fire accidents that occurred during the recent filtration process of pharmaceutical companies, it is proposed to prevent static electricity accumulation by measures of nitrogen supply facilities, capacity improvement, conductive filter fabric and so on.

Optimization of biomethane production by biogas upgrading process using response surface mothodolgy (반응표면분석을 이용한 바이오가스 고질화공정을 통한 바이오메탄)

  • Park, Seong-Bum;Sung, Hyun-Je;Shim, Dong-Min;Kim, Nack-Joo
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.62-73
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    • 2014
  • This research was focused to apply response surface methodology for optimization of bio-methane production by biogas upgrading process. Methane concentration(Y1) and methane efficiency(Y2) on biogas upgrading process were mathematically described as being modeled by the use of the Box-Behnken design on response surface methodology. The results of ANOVA(analysis of variance) about models, the probability value of the methane concentration and methane recovery response surface model are 0.0001 and 0.0001, respectively and coefficient of determination($R^2$) are 0.9788 and 0.9710, respectively. The response surface model is proved of high reliability and suitability. The operation pressure had the greatest influence to methane concentration than other operation parameters and the PSA rotary valve velocity had the greatest influence to methane recovery than other operation parameters. Optimal condition of biogas upgrading process for production of $100Nm^3/hr$ bio-methane were operation pressure 8.0bar and outlet flow rate 31.55RPM, respectively. At that operation condition the methane concentration of bio-methane was 97.13% and methane recovery in biogas upgrading process was 75.89%.

Numerical Analysis of Flow Characteristics in an Injection Tubing during Supercritical CO2 Injection: Application of Demonstration-scale CO2 Storage Project in the Pohang Basin, Korea (초임계 상태의 CO2 주입시 주입관내 유동 특성의 수치해석적 연구: 포항분지 중소규모 CO2 지중저장 실증 사업에 적용)

  • Jung, Woodong;Sung, Wonmo;Han, Jeongmin;Song, Youngsoo;Wang, Jihoon
    • Journal of the Korean Institute of Gas
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    • v.26 no.4
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    • pp.9-17
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    • 2022
  • This paper is the continuation of our previous paper, which we refer to as numerical analysis of phase behavior and flow properties in an injection tubing during gas phase CO2 injection. Our study in this paper show the results during supercritcal CO2 injection under the same project. Geological CO2 storage technology is one of the most effective method to decrease climate change due to high injectivity and storage capacity and economics. A demonstration-scale CO2 storage project was performed in a deep aquifer in the Pohang basin, Korea for a technological development in a large-scale CO2 storage project. A problem to consider in the early stage design of the project was to analyze CO2 phase change and flow characteristics during CO2 injection. To solve this problem, injection conditions were decided by calculating injection rate, pressure, temperature, and thermodynamic properties. For this research, we simulated and numerically analyzed CO2 phase change from liquid to supercritical phase and flow characteristics in injection tubing using OLGA program. Our results provide discharge pressure and temperature conditions of CO2 injection combined with a pressure of an aquifer.