• Title/Summary/Keyword: 가소화

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Preparation and Properties of Cellulose Diacetate/$CaCO_3$ Composite (Cellulose Diacetate/$CaCO_3$ 복합체의 제조 및 물성)

  • Lim, Hwan-Kyu;Kye, Hyoung-San;Won, Sung-Ho;Nam, Jae-Do;Lee, Young-Kwan
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.178-182
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    • 2008
  • Cellulose diacetate (CDA) and calcium carbonate ($CaCO_3$) biodegradable composites were prepared by melt mixing in a twin screw extruder and their physical properties were examined. In the melt processing, triacetine and epoxidized soybean oil were added to the composites as a plasticizer and lubricant, respectively. The optimal conditions for the preparation of the biodegradable composites were determined. Acetic acids ($CH_3COOH$) were made by pyrolysis acetyl group ($-OC (O)CH_3$) of CDA and TA in melt processing. Increasing the amount of $CaCO_3$ in the composites resulted in further enhancement of the $CH_3COOH$ absorption effects. The tensile strength and elongation were decreased, and Young's modulus and $T_g$ value increased with increasing amount of $CaCO_3$.

Studies on Productivity and Nutrient Quality of Forage Rape (Brassica napus Subsp. oleifera) IV. Influence of sowing time on growth, yield and nutrient quality of forage rape. (사초용유채 ( Brassica napus Subsp. Oleifera ) 의 생산성과 사료가치에 관한 연구 IV. 파종기가 사초용 유채의 생육특성 , 수량 및 영양가치에 미치는 영향)

  • ;;Ichiro Goto
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.9 no.2
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    • pp.103-107
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    • 1989
  • To determine optimal sowing time of forage rape in southern areas of Korea, forage rape cv. Velox, the highest yielding variety among seventeen introduced varieties of forage rape, was grown under five different sowing times. The results obtained are summarized as follows: 1. Yield components such as plant length, number of branches and number of leaves etc. were highest at the sowing time of Sep. 14 and Sep. 24. 2. Plants sown at Sep. 14 and Sep. 24 also showed highest'fresh and dry matter yield. 3. As plants were grown under later sowing time, they showed higher values in content of crude protein and lower values in contents of crude fiber such as NDF, ADF, cellulose and lignin. 4. There was no relationship between variation of IVDMD and sowing time. Plants sown at Sep. 14 and Sep. 24 showed highest digestible dry matter yields.

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Comparative Studies on Ammonium Ion Selective Electrodes Using Poly(Vinyl Chloride) and Polyurethane as Substrate Matrix Materials (Poly(Vinyl Chloride)와 Polyurethane을 지지체로 사용한 암모늄이온 선택성 전극의 특성비교)

  • Cho Chang-Ae;Park Su-Moon
    • Journal of the Korean Electrochemical Society
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    • v.7 no.3
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    • pp.148-154
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    • 2004
  • Ammonium ion selective electrodes have been prepared using nonactin as an ionophore and poly(vinyl chloride) (PVC) or polyurethane(PU) as a polymer matrix with or without a plasticizer, bis(2-ethylhexyl) adipate, and their performances have been evaluated. The reults indicate that PU-based electrodes can be designed to perform better although PVC-based electrodes generally show better performances. In efforts to explain the obervation, we also carried out atomic force microscopy as well as impedance studies, and the results suggests that islands of ion-ophores are formed in the PVC membranes through which ion transfers appear to be more facile than through the PU membranes. The PU membranes appear to have ionophores better dispersed throughout the film and are more resistive to ion mobilities in comparison to PVC films.

Synthesis of Poly(alkylene carbonate) from Carbon Dioxide (이산화탄소로부터 Poly(alkylene carbonate)의 합성)

  • Lee, Yoon-Bae;Choi, Jeong-Hyun
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.813-822
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    • 1996
  • In order to reduce carbon dioxide, one of the major greenhouse gases, a new type of copolymer, poly(alkylene carbonate) has been synthesized. The alternating copolymers have been obtained from carbon dioxide and various epoxides with zinc carboxylate as a catalyst. The number-average molecular weight of the polymer is about 50,000 and polydispersity is rather broad(5~10). The polymers are amorphous, and glass-clear materials that exhibit unusually facile and clean thermal decomposition behavior. Complete decomposition with no carbon residue is observed at elevated temperature even in an inert atmosphere. Terpolymers with bulkier epoxides improve the physical properties of the copolymer with simple epoxides. The decomposition properties of the polymer provide versatile applications such as ceramic, metal, and electronic binders and lost-foam casting. Further application of the polymer for the barrier film or the plasticizer will be investigated.

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Pwevaporation Separation of Aqueous Ethanol Solution Through Poly(vinyl alcohol) Membranes Crosslinked Poly(acrylic acid-co-maleic acid) (Poly(acrylic acid-co-maleic acid)로 가교된 Poly(vinyl alcohol)막을 이용한 에탄을 수용액의 투과증발분리 특성)

  • 남상용;성경수;천세원;임지원
    • Membrane Journal
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    • v.12 no.4
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    • pp.255-261
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    • 2002
  • Poly(vinyl alcohol) (PVA) membranes crosslinked with poly(acrylic acid-co-maleic anhydride) (PAM) as a polymeric crosslinking agent were prepared to investigate the pervaporation performance for the dehydration separation of aqueous ethanol solution. The characteristics of the resulting membranes crosslinked(x) were analysed by FT-IR and water swelling test. The water swelling decreased with increasing crosslinking agent content. The crosslinked PVA membranes with PAM showed lower water swelling than those of PVA membrane crosslinked with glutaraldehyde and modified PVA membrane. The swelling of water molecules in the crosslinked PVA membranes is more restricted by both chemical crosslinking between PVA and polymeric crosslinking agent chains and physical crosslinking by the entanglement between the PVA and polymeric crosslinking agent chains. For the pervaporation of aqueous ethanol solution through the crosslinked membrane, as the contents of crosslinking agent increased, the separation factor increased while the permeation flux decreased. The separation factor slightly decreased and permeation flux increased with increasing feed water content. As a result it could be considered that PVA-PAM membranes suppressed the plasticization effect even in the range of high water concentration in fled.

Preparation and Electrochemical Properties of Polymeric Composite Electrolytes Containing Organic Clay Materials (Organic Clay가 첨가된 고분자 복합 전해질의 제조 및 전기화학적 성질)

  • Kim, Seok;Hwang, Eun-Ju;Lee, Jea-Rock;Kim, Hyung-Il;Park, Soo-Jin
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.297-301
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    • 2007
  • In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt ($LiClO_4$), and sodium montmorillonite ($Na^+-MMT$) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of $Na^+-MMT$, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.

Age-related neurocognitive changes and exercise-induced benefits: A review of cognitive neuroscientific research (노화 관련 뇌인지 변화와 운동의 긍정적 영향: 인지신경과학적 연구 개관)

  • Shin, Eunsam
    • Korean Journal of Cognitive Science
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    • v.24 no.1
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    • pp.1-24
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    • 2013
  • The elderly population continues to increase in Korea and there has been a growing interest in understanding normal aging. In response to this public interest, the present paper reviewed human aging research focusing on recently published neuroimaging studies. For the first half of the paper, I reviewed the effects of aging on the brain and cognition. In normal aging, structural changes in the brain include atrophy and volume reduction in the prefrontal and temporal cortices. Functional changes are exhibited in the form of overactivation of the brain. Moreover, age-related cognitive decline is particularly observed in inhibition and memory, which are also associated with the age-related structural changes in the brain. For the second half of the paper, I introduced physical exercise studies showing that exercise played a protective role in the age-related neurocognitive decline. More specifically, engaging in physical exercise (particularly, aerobic exercise) for a relatively long period of time (e. g., > 6 mon.) protected older adults from volume loss in the prefrontal cortex and the hippocampus, and induced better inhibition and memory. These exercise-induced benefits appear to be associated with changes in neuronal levels, indicating that the aging brain is still plastic and this plasticity can be enhanced by physical exercise.

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Vitrification of Highly Active Liquid Waste(I) (Thermal Decomposition of Nitrates and Additives for Glass-making)

  • Chun, Kwan-Sik;Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.9 no.4
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    • pp.211-222
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    • 1977
  • The decomposition of all the individual chemicals used in the Harwell inactive vitrification pilot plant has been studied by means of a thermal balance. Weight loss curves to 110$0^{\circ}C$ have been obtained. The four materials (sodium nitrate, cesium nitrate, lithium nitrate and ruthenium nitroso-nitrate solution) showed a greater weight loss than that based on an oxide yield, and hence these compounds of their products of decomposition are volatile below 110$0^{\circ}C$. The remaining materials suffered a weight loss no more than that corresponding to a full yield of the oxide, and hence they were not volatile below 110$0^{\circ}C$. Most of chemicals begin to decompose at less than 75$^{\circ}C$ but the nitrates of cesium, strontium, barium and sodium not until 295$^{\circ}C$ to 59$0^{\circ}C$. The results obtained can be used in the analysis of process conditions in the vitrification and calcination of highly radioactive wastes and also of the thermal decomposition behaviour of mixtures containing those materials.

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Refinement of Low-grade Clay using Iron-reducing Bacteria [I] : Comparison of Traditional Ripening and Biotechnological Ripening (철환원세균을 이용한 저품위 점토의 개량[I] : 전통적 수비법과 생물공학적 숙성법의 비교)

  • 류희욱;조경숙;김민주;강석영;최희락
    • KSBB Journal
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    • v.15 no.2
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    • pp.201-207
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    • 2000
  • The traditional ripening method of clay was analyzed. An advanced refining method of clay using enrichment cultures of iron r reducing bacteria was developed. After the traditional ripening, the whiteness of the clay was increased due to removal of | iron impurities by inhabitant dissilmaltien with iron reducing bacteria. Other characteristics of the refined clay such as v viscosity, plasticity, and strength were also improved by iron reducing bacteria. An advanced method of clay refinement with a anaerobic enrichment cultivation of iron reducing bacteria supplemented with an extra carbon source such as glucose was s suggested. When the clay was treated by the advanced method. the refinement time could be reduced to 1/6 of that r required by the traditional method. The physical properties of the refined clay by the advanced method were better than t those of the traditionally refined clay.

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The Neurological Effect and Mechanism of Mirror Therapy in Adults With Stroke (뇌졸중 환자를 대상으로 한 거울치료의 효과와 신경학적 기전)

  • Kim, Yeong-Jo
    • Therapeutic Science for Rehabilitation
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    • v.2 no.1
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    • pp.24-35
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    • 2013
  • The Purpose of this study was to determine the clinical effectiveness of mirror therapy for stroke. Moreover, this paper was designed to summarize clarified information of neurological plasticity by mirror therapy to finally define the neurological mechanism. Mirror therapy improves the stroke patients' hand and arm motor function. It also has a positive influence on recovering performance of activities of daily living and relieving pain. However, it is not evident that mirror therapy restores visual neglect. There are various ways of recovering stroke. Fundamentally, all the theories are on a bases of restoration of premotor area. Premotor area which is associated with motor control increases the activation of primary motor area and finally improves patients' motor function. If primary motor area is completely damaged, premotor area and supplementary motor substitute for primary motor area. In summary of literature survey, there are not enough evidence to verify the effectiveness and neurological mechanism of mirror therapy. In future, more researches should be conducted to verify the neurological recovery through mirror therapy. Then, mirror therapy will be acknowledged as a clinically effective treatment.