• Journal of Photoscience
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• v.4 no.2
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• pp.61-67
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• 1997

The model based on the idea that the p$_y$-orbital of the carbonyl oxygen is responsible to receiving hydrogen was devised for simulation of intramolecular hydrogen transfer. A Monte Carlo method was applied to free rotation of a molecular chain performed by changing the dihedral angles, and a "hit" was defined as the case when the migrating hydrogen comes within the region defined as the p$_y$-orbital and satisfies all the geometrical requirements for abstraction. A set of parameters was employed for defining the region and the requirements; $\tau$ was defined as the angle formed between O...H vector and its projection on the mean plane of the carbonyl group (- 43$\circ$ < $\tau$ < + 43$\circ$), $\Delta$ as the C=O...H angle (90 -15$\circ$ < $\Delta$ < 90 + 15$\circ$), $\theta$ as the O...H - C angle ( 180 - 80$\circ$< 0 < 180 + 80$\circ$), d as the distance from the center of the lobe of the p$_y$-orbital to hydrogen (0 < d < 1.04 ${\AA}$). The minimum value for the distance between carbonyl oxygen (O$_1$) and the migrating hydrogen (H$_i$) and for that between non-bonded atoms except the pair of O$_1$ and H$_i$ were assumed to be 0.52 ${\AA}$ and 1.54 ${\AA}$, respectively. The apphcation of this model to intramolecular $\beta$-, $\gamma$-, $\delta$-, $\epsilon$-, and $\zeta$-hydrogen abstraction in ketones and $\eta$- and $\theta$- proton transfer in oxoesters gave good results reflecting their photochemical behavior. The model was also used for prediction of photoreactivities of 2-(N,N-dibenzylamino)ethyl 2-, 3- and 4-benzoylbenzoate (1a - c). (1a - c).

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.72-72
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• 2011

국내 및 세계의 천연가스 수요가 증가하고, 원유가 상승에 의한 천연가스의 지속적인 가격상승이 예측됨에 따라 천연가스의 99%를 수입에 의존하는 우리나라의 에너지 안보 확보 방안을 위한 기술개발이 필요하다. 국내에서 천연가스를 확보할 수 있는 현실적인 방법중의 하나는 석탄가스화를 통해 얻어진 합성가스를 이용하여 SNG(synthetic Natural Gas, 합성천연가스)를 제조하는 것이다. 본 연구에서는 다양한 석탄, 다양한 석탄 가스화기를 적용하는 경우에 대한 CASE별 공정해석을 수행하여 각 경우의 SNG 생산 특성을 파악하였다. 석탄의 종류는 역청탄, 아역청탄, 갈탄을 대상으로 하였으며, 역청탄을 사용하는 경우는 General Electric Energy(GEE), Shell Global Solutions(Shell), ConocoPhillips(CoP)사의 가스화기를, 아역청탄을 사용하는 경우는 KBR의 TRIG$^{TM}$, Siemens사의 SFG, Shell, CoP 가스화기를, 갈탄을 사용하는 경우는 Shell, Siemens 가스화기를 적용하였다. 사용한 석탄과 석탄가스화기에서 발생된 합성가스 조성은 NETL에서 발행된 보고서에 제시된 수치들을 활용하였다. 역청탄을 사용하고 CoP 가스화기를 적용한 경우, SNG 합성공정에 유입되는 유량이 100 Nm3/h 일 때, 생산되는 SNG의 조성은 $CH_4$ 96.26%, $H_2$ 1.49%, $CO_2$ 0.69%, CO 0.004% 이고 생산유량은 24 Nm3/h 였다. SNG 효율을 SNG 합성공정에 공급되는 합성가스 열량 대비 최종 생산되는 SNG의 열량을 기준으로 하고, 각 CASE 별 SNG 효율을 살펴보면, 역청탄을 대상으로 한 경우 GEE 74.05%, CoP 76.65%였다. 아역청탄을 대상으로 한 경우 TRIG 78.14%, Siemens 71.22%, CoP 75.72%였고, 갈탄을 대상으로 하는 경우 Shell 71.48%, Siemens 71.49%였다. 역청탄을 사용하는 경우는 CoP 가스화기를 대상으로 한 경우 SNG 효율 및 생산량이 가장 높았고, 아역청탄을 사용하는 경우는 TRIG 가스화기를 대상으로 한 경우의 SNG 효율 및 생산량이 높았다. 갈탄을 사용하는 경우는 Shell 가스화기와 Siemens 가스화기가 거의 비슷한 결과를 나타내었다. $$SNG\;efficiency({\eta})={\frac{Q_B}{Q_A}}={\frac{Q_{SNG}(kcal/h)}{Q_{Syngas}(kcal/h)}}{\times}100(%)$$.

• Journal of Science Education
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• v.34 no.2
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• pp.327-341
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• 2010

The purpose of this study is to obtain science high school students' perceptions of scientists and their work before and after the Green Investigation program with scientists. This study also attempts to determine whether the program affected the participants' perceptions of scientists and their work. A modified DAST was carried out with 64 high school students. Findings revealed that Korean science high school students had normal perceptions of scientists, such as images of 20 to 30 year old males wearing laboratory coats and working alone in research labs with test tubes, flasks, and several machines in the background. After the intervention, students drew fewer typical items representing scientists and had significantly different perceptions of their work places between the pretest (M=1.69, SD=1.14) and posttest (M=1.96, SD=1.24, t=4.43, p<0.001) with the eta squared statistics (.24). These findings reflect the need for continued efforts of developing green investigation programs with scientists for students. Some future studies based on this study are also introduced.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3060-3065
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• 2009

A series of wholly aromatic Poly(ether-ether-ester)s with flexible side chain was synthesized by direct polycondensation from ether linkaged triad diol and 2,5-dialkoxyterephthalic acid. The chemical structures and physical properties of these polymers were investigated by using $^1H$-NMR, FT-IR, DSC and TGA. As results of investigations, the inherent viscosities($\eta$inh) measured at $40^{\circ}C$ in 1,1,2,2-tetrachloroethane(TCE) were 0.45~0.86 dl/g and initial decomposition(Td) in TGA occurred at 378~418 $^{\circ}C$ in N2 gas. The majority of these polymers were soluble in organic solvents used in this experiments at elevated temperatures. Melting temperatures(Tm) decreased with increasing the length of the side chain and showed odd-even effects.

• Korean Journal of Food Science and Technology
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• v.35 no.1
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• pp.44-51
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• 2003

찹쌀가루와 메주가루의 배합비율(무게비)을 달리한 고추장(찹쌀가루 : 메주가루 = 1:1, 1:2, 1:3, 2:1, 3:1)의 숙성 중 품질 변화를 평가하기 위해 12주 동안 숙성시키면서 고추장의 이화학적 특성, 효소 활성 및 레올로지 특성을 연구하였다. 숙성 중 고추장의 수분함량은 $47.4{\sim}47.9%$에서 점차 증가하여 8주에는 최대 수분함량을 보였다. 환원당 함량은 $2{\sim}4$주에 가장 높았으며 이후에서는 점차 감소하는 경향을 보였다. 아미노태 질소 함량은 지속적으로 증가하였다. ${\alpha}-amylase$와 ${\beta}-amylase$ 활성은 숙성 $2{\sim}4$주에 최대 역가를 나타냈다. Acidic protease와 neutral protease는 각각 숙성 2주와 4주에 가장 높은 활성을 보였다. Power law 모델에 의한 유동성 측정에서 고추장은 낮은 유동성지수(flow behavior index, $n=0.21{\sim}0.36$)를 가진 전단담화(shearing-thinning)거동을 보여주었으며, 점조도 지수(consistency index, K)와 겉보기점도 $({\eta}_{a,10})$는 숙성 2주에 급격히 증가하고 이후에는 감소하였다. Casson 모델식에 의한 항복응력$({\sigma}_{oc})$은 숙성 2주에 급격히 증가하고 이후에는 감소하였다. 동적 점탄성 측정에서는 저장 탄성률 (G#)이 손실탄성률 (G') 보다 높은 수치를 나타내었고 주파수(frequency, ${\omega}$)가 증가함에 따라 증가하는 경향을 보여주었다. 또한 숙성기간이 경과함에 따라 (G#)과 (G@)이 증가하는 경향을 나타냈다.

• Journal of the Korean Geosynthetics Society
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• v.12 no.3
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• pp.55-64
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• 2013

In this study, a series of the isotropic compression-expansion tests and the Undrained triaxial tests were performed on low-plastic silt of Pocheon stone sludge. Using the tests results the characteristic of the parameters of Lade's single hardening constitutive model were investigated. We also observed that predicted values from the Lade's single hardening constitutive model were well consistent with the observed data. In experimental results the deviator stress showed the work hardening behaviour after reaching its yield stress. Therefore practically useful failure criterion for low-plastic silt were required. The stress-strain behavior predicted by 11 soil parameters are compared with the results obtained 9 parameters by correlation between h and ${\eta}_1$ and constant ${\alpha}$. They are poor matched each other.

• Journal of the Korean Ceramic Society
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• v.51 no.4
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• pp.362-366
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• 2014

Dye-sensitized solar cells (DSSCs) were synthesized using a $0.25cm^2$ area of a $TiO_2$ nanoparticle layer as the electrode and platinum (Pt) as the counter electrode. The $TiO_2$ nanoparticle layers (12 to 22 ${\mu}m$) were screen-printed on fluorine-doped tin oxide glass. Glancing angle X-ray diffraction results indicated that the $TiO_2$ layer is composed of pure anatase with no traces of rutile $TiO_2$. The Pt counter electrode and the ruthenium dye anchored $TiO_2$ electrode were then assembled. The best photovoltaic performance of DSSC, which consists of a $18{\mu}m$ thick $TiO_2$ nanoparticle layer, was observed at a short circuit current density ($J_{sc}$) of $14.68mA{\cdot}cm^{-2}$, an open circuit voltage ($V_{oc}$) of 0.72V, a fill factor (FF) of 63.0%, and an energy conversion efficiency (${\eta}$) of 6.65%. It can be concluded that the electrode thickness is attributed to the energy conversion efficiency of DSSCs.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.9
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• pp.818-824
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• 2006

The effects of high-temperature process required to fabricate the SiC devices on the surface morphology and the electrical characteristics were investigated for 4H-SiC Schottky diodes. The 4H-SiC diodes without a graphite cap layer as a protection layer showed catastrophic increase in an excess current at a forward bias and a leakage current at a reverse bias after high-temperature annealing process. Moreover it seemed to deviate from the conventional Schottky characteristics and to operate as an ohmic contact at the low bias regime. However, the 4H-SiC diodes with the graphite cap still exhibited their good electrical characteristics in spite of a slight increase in the leakage current. Therefore, we found that the graphite cap layer serves well as the protection layer of silicon carbide surface during high-temperature annealing. Based on a closer analysis on electric characteristics, a conductive surface transfiguration layer was suspected to form on the surface of diodes without the graphite cap layer during high-temperature annealing. After removing the surface transfiguration layer using ICP-RIE, Schottky diode without the graphite cap layer and having poor electrical characteristics showed a dramatic improvement in its characteristics including the ideality factor[${\eta}$] of 1.23, the schottky barrier height[${\Phi}$] of 1.39 eV, and the leakage current of $7.75\{times}10^{-8}\;A/cm^{2}$ at the reverse bias of -10 V.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.203-207
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• 2007

In this study, the combustion characteristics of HTPB was studied in hybrid propulsion system. In this experiments HTPB was used as fuel, GOX was used as oxidizer. The mass flow rate of GOX was controlled by the several chocked orifices that have different diameter, and the oxidizer supply range was $13.8{\sim}42.7g/sec$. The experimental result of HTPB was compared with the other studies of HTPB, and the combustion performance of HTPB was analyzed with that of PE. As a result, the homing rate and efficiency of HTPB as fuel were better than that of PE in the same hybrid motor.

• Structural Engineering and Mechanics
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• v.59 no.3
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• pp.455-473
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• 2016

Methods for the seismic demands evaluation of structures require iterative procedures. Many studies dealt with the development of different inelastic spectra with the aim to simplify the evaluation of inelastic deformations and performance of structures. Recently, the concept of inelastic spectra has been adopted in the global scheme of the Performance-Based Seismic Design (PBSD) through Capacity-Spectrum Method (CSM). For instance, the Modal Pushover Analysis (MPA) has been proved to provide accurate results for inelastic buildings to a similar degree of accuracy than the Response Spectrum Analysis (RSA) in estimating peak response for elastic buildings. In this paper, a simplified nonlinear procedure for evaluation of the seismic demand of structures is proposed with its applicability to multi-degree-of-freedom (MDOF) systems. The basic concept is to write the equation of motion of (MDOF) system into series of normal modes based on an inelastic modal decomposition in terms of ductility factor. The accuracy of the proposed procedure is verified against the Nonlinear Time History Analysis (NL-THA) results and Uncoupled Modal Response History Analysis (UMRHA) of a 9-story steel building subjected to El-Centro 1940 (N/S) as a first application. The comparison shows that the new theoretical approach is capable to provide accurate peak response with those obtained when using the NL-THA analysis. After that, a simplified nonlinear spectral analysis is proposed and illustrated by examples in order to describe inelastic response spectra and to relate it to the capacity curve (Pushover curve) by a new parameter of control, called normalized yield strength coefficient (${\eta}$). In the second application, the proposed procedure is verified against the NL-THA analysis results of two buildings for 80 selected real ground motions.