• Title/Summary/Keyword: [ph]

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Binding energy study from Photocurrent signal in $CdGa_2Se4$ layers

  • Lee, Sang-Youl;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.47-47
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    • 2009
  • The photoconductive $CdGa_2Se4$ layer has been investigated using photocurrent (PC) spectroscopy as a function of temperature. Three peaks corresponding to the band-to-band transitions were observed in the PC spectra for all temperature ranges. Also, contrary to our expectation, the PC intensities decreased with decreasing temperatures. From the relation of log $J_{ph}$ vs 1/T, where $J_{ph}$ is the PC density, two dominant levels by the exponential variation of the PC with varying temperature were observed, one at high temperatures and the other at low temperatures.

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Concise Synthesis of Biologically Interesting Mollugin and Its Analogues

  • Lee, Yong-Rok;Wang, Xue;Kim, Yun-Mi;Shim, Jae-Jin;Kim, Byung-Nam;Han, Do-Hung
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1735-1738
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    • 2007
  • The synthesis of naturally occurring mollugin and its analogues, 3,4-dihydromollugin, cis-3,4-dihydroxy-3,4- dihydromollugin, and trans-3,4-dihydroxy-3,4-dihydromollugin was achieved starting from 1,4-dihydroxynaphthalene- 2-carboxylic acid. The key reaction is an electrocyclization for pyranyl ring formation in the presence of PhB(OH)2/AcOH.

Theoretical Investigation of Triple Bonding between Transition Metal and Main Group Elements in (η5-C5H5)(CO)2M≡ER (M = Cr, Mo, W; E = Si, Ge, Sn, Pb; R = Terphenyl Groups)

  • Takagi, Nozomi;Yamazaki, Kentaro;Nagase, Shigeru
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.832-836
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    • 2003
  • To extend the knowledge of triple bonding between group 6 transition metal and heavier group 14 elements, the structural and bonding aspects of ($η^5-C_5H_5$)$(CO)_2$M≡ER (M = Cr, Mo, W; E = Si, Ge, Sn, Pb) are investigated by hybrid density functional calculations at the B3PW91 level. Substituent effects are also investigated with R = H, Me, $SiH_3$, Ph, $C_6H_3-2,6-Ph_2$, $C_6H_3-2,6-(C_6H_2-2,4,6-Me_3)_2$, and $C_6H_3-2,6-(C_6H_2-2,4,6- iPr_3)_2$.

Characterization of Acid Phosphatase from Carrots (당근 Acid Phosphatase의 특성)

  • Kim, Gi-Nahm
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.3
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    • pp.490-495
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    • 1994
  • Acid phosphatase (EC3.1.3.2) from carrots was partially purified by ammonium sulfate fractionation (30%-80%), Sephacryl S-200 gel filtration, cm-Sepharose CL-6B and DEAE -Sephacel ion exchange chromatography. The optimum ph and temperature of acid phosphatase from carrots were pH 5.5 and 55$^{\circ}C$, respectively. The enzyme was most stable at ph 6.0 and relatively unstable below pH 4.0 . The activation energy of the enayme was determined to be 10.6kcal/mole. The enzyme utilized p-nitrophenyl phosphate as a substrate among tested possible substrates, whereas it hydrolyzed 5' -IMP and 5'-GMP poorly. The Michaelis -Menten constant(Km) of the enzyme with p-nitrophenyl phosphate as a substrate was identified as 0.55mM. Amongtested metal ions and inhibitors, Al+++ Zn++, Cu++ , fluoride, metavanadate and molybdate ions inhibited the enzyme activity drastically.

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The effect of annealing method on dopant-activation and damage-recovery in ion-shower-doped Poly-Si using $PH_3/H_2$

  • Kim, Dong-Min;Kim, Dae-Sup;Ro, Jae-Sang;Choi, Kyu-Hwan;Lee, Ki-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1072-1075
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    • 2004
  • Ion shower doping using a source gas of $PH_3/H_2$ was conducted on excimer-laser-annealed (ELA) Poly-Si. As-implanted damage is accumulated more and more with the increase of an acceleration voltage and a doping time. In this study we found that dopant-activation is relatively a rapid kinetic-process while damage-recovery is not.

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Treatment of Rice-Washing Wastewater by ph Adjustment (ph 조절에 의한 쌀세척 폐수의 처리)

  • 노홍균;김지숙;이문이;조영인
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.4
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    • pp.660-665
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    • 1994
  • Treatment of rice-washing wastewater was considered under various pH levels and chitosan concentrations. Compared with the control test, addition of chitosan at the various concentrations did not noticeably enhanced turbidity reduction at pH 4 and 5 , but greatly enhanced at above pH 6. However, reduction of turbidity in the wastewater, irrespective of chitosan concentrations, was the greatest at pH 4 and became lower by increasing pH. Suspended solids in the wastewater were the most effectively recovered by pH adjustment of the wastewater to 4 followed by centrifugation, with over 99% reduction in turbidity . Different concentrations of suspended solids in the wastewater and various kinds of acids used for p/H adjustment did not affect turbidity reduction. Increasing storage periods of the wastewater resulted in lower reductions in turbidity.

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Plant morphological symptom caused by simulated acidic rain made by fuel gases (排氣가스로 만든 人工酸性雨에 의한 植物의 形態的 症狀)

  • Chang, Nam-Kee;Yun-Sang Lee;Soo-Jin Yi
    • The Korean Journal of Ecology
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    • v.16 no.1
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    • pp.17-26
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    • 1993
  • We investigated the ph change of water caused by several fuel gases regarded as the main cause of the air pollution, To find out the main cause of increase of the acidity of the rain. We measured it while injrcting each fuel gas directiy to the distilled water. It was observed that bunker-c oil gas and anthracite coal gas were the main cause to make the ph of the solution lowest. We examined the effects of simulated acidic water solutions on several plant species. Simulated acidic rain made by bunker-c oil gas has significant symptom on the saxifraga stolonifera and commelina communis, while no injury was observed on plants exposed to simulated rainfall made by anthracite coal gas.

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Voltammetric Determination of Ag(I) ion using Carbon Paste Electrode Modified with $Ph_2O_2S_3$ ($Ph_2O_2S_3$로 변성된 탄소반죽전극에 의한 Ag(I) 이온의 전압-전류법적 정량)

  • Lee, Ihn Chong
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.171-175
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    • 1999
  • Carbon paste electrodes, modified with podands containing more than two sulfur atoms, have been employed for the voltammetric determination of Ag(I) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(I) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(I) ion concentration ranging from $1.0{\times}10^{-6}$ to $9.0{\times}10^{-5}M$, and detection limit was $5.0{\times}10^{-7}M$.

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