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Correlation between Tobacco Leaf and Smoke Compositions (잎담배 조성과 연기성분과의 관계)

  • 김정옥;박경희;박은수
    • Journal of the Korean Society of Tobacco Science
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    • v.1 no.2
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    • pp.93-102
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    • 1979
  • Chemical compositions of Flue - cured and Burley tobacco leaf and smoke were analyzed to find out simple correlation between compositions. Based on the simple correlation ( $r$ ) data, four regression equations were obtained for dry condensate and nicotine in smoke as follows, $Y_{FT}=\;0.816+4.638X_1+0.346X_2$......................................(1) $Y_{BT}=\;0.235+0.884X_3-0.088X_4$......................................(2) $Y_{FN}=\;0.015+0.090X_5+0.476X_1$......................................(3) $Y_{BN}=-0.026+0.101X_3-0.006X_4$.........................................(4) where, $Y_{FT}$ : dry condensate (mg/cig.) in cigarette smoke of Flue-cured $Y_{BT}$ : dry condensate (mg /cig. ) in cigarette smoke of Burley $Y_{FN}$ : nicotine contents (mg/cig.)in cigarette smoke of Flue-cured $Y_{BN}$ : nicotine contorts (mg/cig. ) in cigarette smoke of Burley $X_1$ : total alkaloid contents (%) of Flue-cured $X_2$ : curde ash contents (%)of Flue -cured $X_3$ : alcohol -benzene extract contents (%) of Burley $X_4$ : curde ash contents (%) of Burley $X_5$ : hexane extract content (%) of Flue -cured Standard deviation for regressions equations were obtained respectively. equation(1),$\pm$3.16 : equation (2),$\pm$1.94 : equation (3),$\pm$0.35 , equation (4) $\pm$ 0.33. Regression equations between dry condensate and nicotine contorts in cigarette smoke were also obtained in the forms of equation(5) and(6) $Y_{FN}$= 0.274 $Y_{FT}$- 3.259............................(5) $Y_{BN}$= 0.249 $Y_{BT}$ - 2.093.............................(6) Standard deviations, $\pm$ 0.061 and $\pm$ 0.152, were obtained for regression equation(5) and (6) respectively.

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A Study on the Hydrogenation Properties of MmNi4.5Al0.5Zrx(X=0.0-0.2) Alloys Containing the Zr by Excess (Zr을 과잉 첨가한 MmNi4.5Al0.5Zrx(X=0.0-0.2) 합금의 수소화 반응특성에 대한 연구)

  • Na, Young-Sang;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.4 no.1
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    • pp.31-39
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    • 1993
  • In order to improve the hydrogen storage capacity and the activation property of the $MmNi_{4.5}Al_{0.5}$ alloy, the multiphase alloy system are prepared by adding the excess Zr in $MmNi_{4.5}Al_{0.5}$ alloy. It is estimated from the X-ray diffraction pattern and the energy dispersive X-ray analysis that the 2nd phases in $MmNi_{4.5}Al_{0.5}Zr_x$ alloys are $ZrNi_3$, ${\beta}$-Zr. Their morphology is also examined by the scanning electron microscope, and it shows the needle-like precipitation. As the Zr contents increase, the activation time and the plateau pressure decrease, sloping of the plateau pressure increase. Amount of the 2nd phases increase with Zr contents in $MmNi_44.5Al_{0.5}Zr_x$ alloys. The $MmNi_44.5Al_{0.5}Zr_{0.05}$ alloy, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage.

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Dielectric and Piezoelectric Properties of the xPb$xPb(Al_{0.5}Nb_{0.5})O_3-(1-x)Pb(Zr_{0.52}Ti_{0.48})O_3$ System (1) ($xPb(Al_{0.5}Nb_{0.5})O_3-(1-x)Pb(Zr_{0.52}Ti_{0.48})O_3$계의 유전 및 압전특성 (1))

  • 이홍렬;윤석진;김현재;정형진
    • Electrical & Electronic Materials
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    • v.5 no.2
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    • pp.207-215
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    • 1992
  • 본 연구에서 xPb(A $l_{0.5}$N $b_{0.5}$) $O_{3}$-(1-x)Pb(Z $r_{0.52}$ $Ti_{o.48}$) $O_{3}$계의 조성변화에 따른 유전 및 압전특성에 관해 실험한 결과 다음과 같은 결론을 얻었다. PAN의 첨가량이 증가함에 따라 c축은 수축되고 a축은 팽창하여 tetragonality는 감소하였고 grain의 크기와 Curie온도 또한 PAN의 첨가량에 따라 감소하였으나 밀도와 유전상수는 PAN의 양이 5mol%까지 증가하다가 그 이상에서는 감소하는 경향을 보였다. PAN의 첨가량이 증가함에 따라 시편의 비저항은 증가하였고 Kp는 PAN의 양이 5mol%첨가시 60%로 최대치를 보였으나 Qm은 최소치를 나타내었다.다.

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Optical Properties of $AgGa_{1-x}In_{x}Se_{2}$ Thin Films ($AgGa_{1-x}In_{x}Se_{2}$ 박막의 광학적 특성)

  • Kim, Hyung Gon;Kim, Wha Tek
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.5
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    • pp.706-711
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    • 1986
  • The AgGa1-xInxSe2 films are deposited by a flash evaporation method onto pyrex glass substrates at temperatures between 5\ulcorner and 360\ulcorner. The single crystalline films which have X-ray diffraction peak of only (112) plane are preared at substrate temperature above 360\ulcorner. The prepared AgGa 1-xInxSe2 films are high photosensitive. The temperature coefficients of energy gap are found to be (-1.2~-4.0)x10**4 eV/K and (-3.1~-5.2)x10**-4 eV/K, and that of peak energy of spectral photoresponse curve are found to be (-1.1 ~ -3.0)x10**-4 eV/K(50K~100K) and (-2.4~-5.1)x10**-4 eV/K(100K~300K).

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The Effect of Sintering Atmosphere on the Microwave Dielectric Properties of $(1-x)CaTiO_3-xLaAlO_3$ System (소결 분위기가 $(1-x)CaTiO_3-xLaAlO_3$계의 마이크로파 유전특성에 미치는 영향)

  • 여동훈;김현재;문종하
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.505-511
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    • 1997
  • The effects of sintering atmospheres(air, O2, N2) on the sintering and microwave dielectric properties of (1-x)CaTiO3-xLaAlO3 system was investigated. The sintered density of (1-x)CaTiO3-xLaAlO3 under air atmosphere increased linearly with increasing x, but it decreased in the range of x>0.5 under O2 atmosphere and x>0.6 under N2 atmosphere in spite of the increament of the smaller La(1.06$\AA$) and Al(0.5 $\AA$) ion than Ca(0.99$\AA$) and Ti(0.6$\AA$). In case of the air sintering atmosphere of (1-x)CaTiO3-xLaAlO3 the two phases of orthorhombic and rhombohedral crystal system were coexisting, and the XRD peak of rhombohedral crystalsystem was to be higher with increasing x. However, the sintering atmosphere of O2 and N2 made the monophasic crystal system of orthorhombic keep up by x=0.5 and x=0.6, respectively, and it transformed to pseudo-cubic crystal system in x>0.5 and x>0.6. The XRD peak intensity of (1-x)CaTiO3-xLaAlO3 was to be gradually higher with increasing x under the air atmosphere of sintering. Whereas, its XRD peak intensity increased till x=0.6 but decreased with increasing x in the range of x>0.6 under O2 and N2 atmosphere. The relative dielectric constant of (1-x)CaTiO3-xLaAlO3 sintered under air atmosphere decreased linearly and the Q.f0 value increased according as x increased. On the other hand, the relative dielectric constant of (1-x)CaTiO3-xLaAlO3 under O2 and N2 atmosphere decreased in the range of x$\leq$0.5 with increasing x, but increased rapidly in the range of x$\geq$0.6. And the Q.f0 value increased till x=0.6 but decreased in the range of x>0.6 with increasing x. The temperature coefficient of resonant frequency had no relation to sintering atmosphere.

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Study on the Crystal Phases of $Ca_{1.5-1.5x}Bi_xVO_4$ Compositions by Bi Substitution (Bi 치환에 따른 $Ca_{1.5-1.5x}Bi_xVO_4$ 조성 화합물의 결정상에 관한 연구)

  • Kim, Myung Seab;Park, Sun Min;Kim, Ho Kun
    • Journal of the Korean Chemical Society
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    • v.43 no.5
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    • pp.547-551
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    • 1999
  • The phase change upon Bi substitutions in $Ca_{1.5-1.5x}Bi_xVO_4$ has been systematically studied. The x value corresponding to the maximum Bi substitutions reades to 0.14 and in this range($x{\leq}0.14$), the single phasic $Ca_3(VO_4)_2$ can be identified. However, a new phase of $BiV_{1.025}O_{4+x}$ is apparently formed along with the $Ca_3(VO_4)_2$ phase, when the x value exceeds beyond 0.18 ($x{\geq}0.18$). As a result of Bi substitution in the range of x$\leq$0.14, the interplanar space($d_300$) becomes larger as the Bi content increases. Since the composition of single phasic $Ca_{1.29}Bi_{0.14}VO_4$ (x=O.14) is, however, incongruent melting one, no definite melting point could be observed. But we found that its solidus temperature was 1182$^{\circ}C$ by DTA analysis.

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INVESTIGATION ON FERROMAGNETIC $Mn_{1-x}Co_{x}Pt_{3}$ ORDERED ALLOYS

  • Kaneko, T.;Fujimori, H.;Yoshida, H.;Watanabe, K.;Abe, S.;Matsumoto, M.;Yoshida, T.;Kanomata, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.758-761
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    • 1995
  • The magnetization of $Mn_{1-x}Co_{x}Pt_{3}$ ordered alloys was measured at various temperatures and the pressure effect on $T_{c}$ for X=0.25, 0.5 and 0.6 was examined. The X dependence of $T_{c}$ determined by Arott plot has a minimum near X=0.6. The field-cooling effect measurement for X=0.5 shows a reentrant spin glass behavior. It is found that there is a concentration showing no pressure dependence of $T_{c}$ between X=0.25 and 0.5. These magnetic properties are discussed with a rigid band model.

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Molecular Orbital Interpretation on Antitumor Activity of trans-Palladium(Ⅱ) Complexes by Geometrical Structure of Ligands (Ⅰ) (리간드의 기하학적 구조에 의한 trans-팔라듐(Ⅱ) 착물의 항암활성에 관한 분자궤도함수론적 해석 (Ⅰ))

  • Song, Young Dae;Park, Byung Kak
    • Journal of the Korean Chemical Society
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    • v.39 no.4
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    • pp.244-251
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    • 1995
  • The palladium(II) complexes(where, [Pd(L)2X2], L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Phisox), and 4-amino, 3,5-dimethylisoxazole(4-ADI); X=Cl, Br] with isoxazole and its derivatives are investigated on antitumor activity by EHMO calculation. It is found that the net charge of the two halogen atoms in trans-isomers are greater than those in cis-ones, indicating that ionic character of Pd-X bond in trans-isomers is greater than that of cis-ones, and so dissociation of Cl- ion is easier than that of Br- ion in aqueous solution in body. Furthermore, it is found that the ${\sigma}MO$ energy of Pd(dx2-y2)-X(px) bond $(E{\sigma}(Pd-X))$ is higher than that of Pd(dx2-y2)-N(px) bond $(E{\sigma}(Pd-N))$ without exception, about all the complexes, and also the $E{\sigma}(Pd-X)$ of trans-isomers is higher than that of cis-isomers. From the above facts, the degree of dissociation in Pd-X bond would be related to antitumor activity. In fact, the linear equation of correlation coefficient 0.96 is fairly established between ${\Delta}E{\sigma}(N-X)(E\sigma(Pd-N)-E{\sigma}(Pd-X))$ and inhibitory activity coefficient, logIA.

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Formation of Ferromagnetic Ge3Mn5 Phase in MBE-grown Polycrystalline Ge1-xMnx Thin Films (다결정 Ge1-xMnx 박막에서 Ge3Mn5 상의 형성과 특성)

  • Lim, Hyeong-Kyu;Anh, Tran Thi Lan;Yu, Sang-Soo;Baek, Kui-Jong;Ihm, Young-Eon;Kim, Do-Jin;Kim, Hyo-Jin;Kim, Chang-Soo
    • Journal of the Korean Magnetics Society
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    • v.19 no.3
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    • pp.85-88
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    • 2009
  • Magnetic phases of polycrystalline $Ge_{1-x}Mn_x$ thin films were studied. The $Ge_{1-x}Mn_x$ thin films were grown at $400^{\circ}C$ by using a molecular beam epitaxy. The $Ge_{1-x}Mn_x$thin films were p-type and electrical resistivities were $4.0{\times}10^{-2}{\sim}1.5{\times}10^{-4}ohm-cm$. Based on the analysis of magnetic characteristics and microstructures, it was concluded that the ferromagnetic phase formed on the $Ge_{1-x}Mn_x/SiO_2$/Si(100) thin films was $Ge_3Mn_5$ phase which has about 310 K of Curie temperature. Moreover, the $Ge_{1-x}Mn_x$ thin film which had $Ge_3Mn_5$ phase showed the negative magnetoresistance to be about 9% at 20 K when the magnetic field of 9 T was applied.

The Multiferroic Properties Study of YMn2-xFexO5 (x=0.00, 0.01) by Neutron Diffraction (고 분해능 중성자 회절 실험에 의한 YMn2-xFexO5 (x = 0.00, 0.01)의 다강체 특성 연구)

  • Kim, Dong-Hyun;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.5
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    • pp.183-187
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    • 2007
  • Compounds of multiferroic materials $YMn_{2-x}Fe_xO_5$ (x = 0.00, 0.01) were prepared using the sol-gel method. The crystallographic, magnetic and electric properties are studied using x-ray diffraction (XRD), neutron diffraction, vibrating sample magnetometer (VSM) and physical property measurement system (PPMS). The crystalline structure of $YMn_2O_5$ was found to be orthorhombic (Pbam) at room temperature. The lattice constants of $YMn_2O_5$ were determined to be $a_0=7.275\;{\AA},\;b_0=8.487\;{\AA},\;c_0=5.674\;{\AA}$. The lattice constants not changed with Fe concentrations. Our data demonstrate the correlation of magnetic and electric properties in $YMn_2O_5$ materials.