• Title/Summary/Keyword: (L, N)-structure

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A Communication Structure of Science Gifted Students Based on the Social Network Analysis (사회연결망법을 이용한 과학영재들의 의사소통 구조 분석)

  • Chung, Duk-Ho;Yoo, Dae Young
    • Journal of the Korean earth science society
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    • v.34 no.1
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    • pp.81-92
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    • 2013
  • The purpose of this study was to investigate the communication structures that science gifted students used in small group activities, and to examine the relationship between communication styles and their achievement level. Eight small groups,5 members in each, participated in small group activities, in which they discussed how to calculate the average density of the earth. The communication structures and the achievement level presented in the group activities were analyzed using Pajek, Ucinet 6.0. As a result, we classified the communication styles of science gifted students into monopolistic type and co-ownership type according to the degree of dispersion of the interaction. We also classified it into $D_H{\cdot}N_H$ type, $D_H{\cdot}N_L$ type, $D_L{\cdot}N_H$ type, and $D_L{\cdot}N_L$ type based on the density and network centralization of interaction. The achievement levels of gifted students in their group work were affected by the density of interaction and the network centralization in small group activities, not by the dispersion of interaction among the members of the groups. Therefore, we recommend that teachers make the communication relevant to solving problem when they utilize a small group activity in science teaching.

Copper(II) Coordination Polymers Assembled from 2-[(Pyridin-3-ylmethyl)amino]ethanol: Structure and Magnetism

  • Han, Jeong-Hyeong;Shin, Jong-Won;Min, Kil-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1113-1117
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    • 2009
  • The one-dimensional coordination polymers, $[Cu^{II}(L)(NO_3)_2]_n$ (1) and {$[Cu^{II}(L)(NO_3)]{\cdot}2H_2O}_{2n} (2), were synthesized from $Cu(NO_3)_2{\cdot}3H_2O$ and 2-[(pyridin-3-ylmethyl)amino]ethanol (L, PMAE) in methanol by controlling the molar ratio of copper(II) salt. Copper(II) ion in 1 has one pyridine group of PMAE whose an aminoethanol group coordinates adjacent copper(II) ion. As the pyridine group is bonded to neighboring copper(II) ion, 1 becomes a one-dimensional chain. Contrary to 1, the structure of 2 shows that the oxygen atom of ethoxide group is bridged between two copper(II) ions, which forms a dinuclear complex. Additionally, the pyridine group of PMAE included one dinuclear unit is coordinated to the other dimeric one each other, which leads to a one-dimensional polymer. Due to the structural differences, 1 exhibits weak antiferromagnetic interaction, while 2 shows strong antiferromagnetic interaction. Due to direct spin exchange via oxygen of PMAE 2 has a much strong spin coupling than 1.

Anion-Dependent Exocyclic Mercury(II) Coordination Polymers of Bis-dithiamacrocycle

  • Siewe, Arlette Deukam;Kim, Seulgi;Choi, Kyu Seong;Lee, Shim Sung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3459-3464
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    • 2014
  • Synthesis and structural characterization of mercury(II) halides and perchlorate complexes (1-4) of bis-$OS_2$-macrocycle (L) are reported. L reacts with mercury(II) chloride and bromide to yield an isostructural 2D coordination polymers with type $[Hg(L)X_2]_n$ (1: X = Cl and 2: X = Br). In 1, each Hg atom which lies outside the cavity is six-coordinate with a distorted octahedral geometry, being bound to four adjacent ligands via monodentate Hg-S bonds and two remaining sites are occupied by two terminal chlorido ligands to form a fishnet-like 2D structure. When reacting with mercury(II) iodide, L afforded a 1D coordination polymer $\{[Hg_2(L)I_4]{\cdot}CHCl_3\}_n$ (3) in which each exocyclic Hg atom is four-coordinate, being bound to two sulfur donors from different ligands doubly bridging the ligand molecules in a head-to-tail mode. The coordination sphere in 3 is completed by two iodo terminal ligands, adopting a distorted tetrahedral geometry. On reacting with mercury(II) perchlorate, L forms solvent-coordinated 1D coordination polymer $\{[Hg_2(L)(DMF)_6](ClO_4)_4{\cdot}2DMF\}_n$ (4) instead of the anion-coordination. In 4, the Hg atom is five-coordinate, being bound to two sulfur donors from two different ligands doubly bridging the ligand molecules in a side-by-side mode to form a ribbon-like 1D structure. The three remaining coordination sites in 4 are completed by three DMF molecules in a monodentate manner. Consequently, the different structures and connectivity patterns for the observed exocyclic coordination polymers depending on the anions used are influenced not only by the coordination ability of the anions but also by anion sizes.

Structural dependences of the extinction in an 1.55 $1.55{\mu}m$ InGaAsP/InGaAsP multiple-quantum-well electro-absorption modulator (1.55 $1.55{\mu}m$ InGaAsP/InGaAsP MQW 광흡수 변조기에서 구조변수가 소광특성에 미치는 영향)

  • 민영선;심종인;어영선
    • Korean Journal of Optics and Photonics
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    • v.12 no.1
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    • pp.40-47
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    • 2001
  • The structural dependence of the performance of an 1.55 $1.55{\mu}m$ InGaAsPIInGaAsP MQW electro-absorption modulator for highspeed digital fiber communication was systematically investigated. The effects of n-doped SCH region length $t_n$ as well as the general structure parameters including quantum well number $N_w$, well-thickness $t_w$, detuning wavelength $\Delta\lambda$, and device length L were thoroughly analyzed. Thereby, a high-pelfoIDlance electro-absorption modulator with device length L of $100{\mu}m$ was successfully designed. The designed structure showed excellent characteristics that have residual loss less than -1.5 dB, operational voltage from 0 V to -2V, and extinction ratios of -2.92 dB at $V_{\alpha}$=-1 V and -10 dB at $V_{\alpha}$=-2V.X>=-2V.

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Synthesis and Characterization of New Polyaza Macrocyclic Nickel(Ⅱ) and Copper(Ⅱ) Complexes Two Nitrile or Imidate Ester Pendant Arms: Metal-Mediated Hydrolysis and Alcoholysis of the Nitrile Groups

  • Kang, Shin-Geol;Song, Jeong-Hoon;Jeong, Jong-Hwa
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.824-829
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    • 2002
  • New di-N-cyanomethylated tetraaza macrocycle 2.13-bis(cyanomethyl)-5.16-dimethyl-2,6,13,17-tetraazatricyclo[$16.4.0.0^7.12$]docosane $(L^2)$ has been prepared by the reaction of 3, 14-dimethyl-2,6,13,17-tetraazatricyclo $(L^1)$ with bromoacetonitrile. The square-planar complexes $[ML^2](ClO_4)_2(M=Ni(II)$ or Cu(II) can be prepared by the reaction of $L^2$ with the corresponding metal ion in acetonitrile. The cyanomethyl groups of $[ML^2](ClO_4)_2readily$ react with water to $yield[ML^3](ClO_4)_2$ containing pendant amide groups. The trans-octahedral complexes $[ML^4](ClO_4)_2$, in which two imidate ester groups are coordinated to the metal ion, can be also prepared by the reaction of $[ML^2](ClO_4)_2with$ methanol under mild conditions. The hydrolysis and alcoholysis reactions of $[ML^2](ClO_4)_2are$ promoted by the central metal ion, in spite of the fact that the cyanomethyl group is not involved in intramolecular coordination. The reactions are also promoted by a base such as triethylamine but are retarded by an $acid(HClO_4).Interestingly$, the imidate ester groups of $[ML^4]^2$ are unusually resistant to hydrolysis even in 0.1 M $HCIO_4$ or 0.1 M NaOH aqueous solution. Crystal structure of $[NiL^4](ClO_4)_2shows$ that the Ni-N (pendant imidate ester group) bond is rlatively strong; the Ni-N bond distance is shorter then the Ni-N(tertiary) distance and is similar to the Ni-N (secondary) distance.

REAL HYPERSURFACES OF THE JACOBI OPERATOR WITH RESPECT TO THE STRUCTURE VECTOR FIELD IN A COMPLEX SPACE FORM

  • AHN, SEONG-SOO
    • Bulletin of the Korean Mathematical Society
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    • v.42 no.2
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    • pp.279-294
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    • 2005
  • We study a real hypersurface M satisfying $L_{\xi}S=0\;and\;R_{\xi}S=SR_{\xi}$ in a complex hyperbolic space $H_n\mathbb{C}$, where S is the Ricci tensor of type (1,1) on M, $L_{\xi}\;and\;R_{\xi}$ denotes the operator of the Lie derivative and the Jacobi operator with respect to the structure vector field e respectively.

NOTE ON NORMAL EMBEDDING

  • Yi, Seung-Hun
    • Bulletin of the Korean Mathematical Society
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    • v.39 no.2
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    • pp.289-297
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    • 2002
  • It was shown by L. Polterovich ([3]) that if L is a totally real submanifold of a symplectic manifold $(M,\omega)$ and L is parallelizable then L is normal. So we try to find an answer to the question of whether there is a compatible almost complex structure J on the symplectic vector bundle $TM$\mid$_{L}$ such that $TL{\cap}JTL=0$ assuming L is normal and parallelizable. Although we could not reach an answer, we observed that the claim holds at the vector space level. And related to the question, we showed that for a symplectic vector bundle $(M,\omega)$ of rank 2n and $E=E_1{\bigoplus}E_2$, where $E=E_1,E_2$are Lagrangian subbundles of E, there is an almost complex structure J on E compatible with ${\omega}$ and $JE_1=E_2$. And finally we provide a necessary and sufficient condition for a given embedding into a symplectic manifold to be normal.

Ecological Study on the Intertidal Zone around Cheju Island 1. Estimation of Plankton Production and Community Structure of Marine Shells - Community Structure of Molluscan Shells (제주도 조간대의 생태학적 기초연구 1. 플랑크톤에 의한 생산량추정 및 패류의 군집구조-패류의 군집구성)

  • 이정재;좌용우
    • The Korean Journal of Malacology
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    • v.4 no.1
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    • pp.17-29
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    • 1988
  • The study had been carried out three times, from April 1987 for the purpose of analysis on the community structure and the distribution patterns of the Molluscan shells at the intertidal zone of Cheju Island. 1) The Molluscan shells collected and identified at all studied sites were composed of 3 classes, 10 orders, 23 families and 42 species.2) In all studied sites, individual numbers according to species were Nodilittorina exigua, Monodonta neritoides, Lunella coronata coreensis, Heminerita japonica in order. On the other hand, the dominant species of the rocky sits were N. exigua, M. neritoides and the rocky and silty-sand sites was Batillaris multiformis.3) In the vertical zonation, in the supralitorial zone, N. exigua was dominant species and the wpper-tidal zone, N. exigua, H. japonica and B. Multiformis were dominant species, but B. multiformis was dominant in the rocky and silty sand sites. In the middle tidal zone, M. neritodes, H. japonica, L. coronata coreensis were dominant and in the lower tidal zond, M. neritodes, L. coronata coreensis, Liolophura japonica were dominant.4)In the analysis on community of Molluscan shells, Chagwi, Pyoson an dAewol sites were more diverse than other sites in the species diversity and environmental inhibits were also favorable.5) Community similarities among the studied sites based on the similarities values were divided into two groups according to the difference of the ground: Hagwi, Chongdal and Sehwa sites group and the others sites group.

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A Study on the Network Architecture for KEPCO SCADA Systems (한국전력 스카다 시스템의 네트워크 구조에 대한 연구)

  • Ryo, Woon Jong
    • Industry Promotion Research
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    • v.2 no.2
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    • pp.1-6
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    • 2017
  • SCADA (Supervisory Control and Data Acquisition) System was first introduced to the Seoul Electricity Authority, which manages the transportation part among the three business fields that produce, transport and supply electric power in Korea. Has been using the data link with 1200 bps and 9600 bps in 5 protocols such as HARRIS 6000, BSC, HDLC, L & N and Toshiba by configuring 3 layers of EMS, SCADA and RTU computer equipments in 1: N radial form. This paper presents the OSI standard network packet flow, analyzing DataLink and Network Layer, and presents a KEPCO SCADA network model composed of X.25 high - speed communication network using 3 layers of network. We proposed a future SCADA communication structure that improved the current SCADA communication structure, defined the SCADA DB structure, introduced the concept of the remote SCADA gateway to the SCADA functional structure, applied the standard communication protocol, Multiplexing of surveillance and control in other local facilities and ensuring communication openness.