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Structural Study of 90K Superconductor Gd1Ba2Cu3O9-x (90K 초전도체 Gd1Ba2Cu3O9-x의 구조에 관한 연구)

  • 이성익;권기정;이기봉;박병규;박병학;신현준
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.577-584
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    • 1988
  • Gd1Ba2Cu3O9-x has been found to be a high Tc superconductor with a transitiion onset at 91K and zero resistance achieved at 87K. The structure as determined from x-ray diffraction is orthorhombic, with lattice constants b=3.842$\pm$0.002$\AA$, b=3.895$\pm$0.003$\AA$, and c=11.684$\pm$0.007$\AA$. The structural similarities between the Gd1Ba2Cu3O9-x compound and the well-studied single phase perovskite, Y1Ba2Cu3O9-x are discussed. A correlation between the observed x-ray spectrum and the effect of oxygen deficiencies in several of the unit cell planes is also discussed.

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Synthesis of Gd2O3 : (Li, Eu) Films using Phosphor Powders Coated with SiO2 Nano Particles (SiO2 나노 입자로 코팅된 형광체 분말을 이용한 Gd2O3 : (Li, Eu) 필름 제조)

  • Park, Jung-Chul
    • Journal of the Korean Chemical Society
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    • v.47 no.6
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    • pp.619-624
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    • 2003
  • The $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ (x=0.02, 0.05, 0.08, and 0.12) powders (${\thickapprox}1{\mu}m$) synthesized by sol-gel method, whose surfaces are modified in a colloidal silica suspension (size of $SiO_2$ particles: ${\sim}30$ nm), have been fabricated to highly stable and effective luminescent films on the glass substrates. Thanks to the fused $SiO_2$ nano particles in the vicinity of the glass softening temperature (at around $700^{\circ}C$), $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ powders are strongly attached onto the surface of glass substrate (>9H, pencil hardness tester). This simple and low-cost method to get $Gd_{1.9-x}Li_{0.1}Eu_xO_3$ phosphor films without any loss of luminescence brightness would promise for applications to display devices.

Magnetic Propertes of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ Nanocrystalline Alloys ($Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ 초미세결정립합금의 자기특성)

  • 조용수;김만중;천정남;김택기;박우식;김윤배
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.880-894
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    • 1995
  • Magnetic properties of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ rrelt-spun alloys with 6 at% B content were studied aiming for finding out a new $\alpha$-Fe based Nd-Fe-B nanocrystalline alloy with good hard magnetic properties. $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys prepared by RSP crystallized to nanocrystalline phase. An optimally annealed $Nd_{3}{(Fe_{0.9}Co_{0.1})}_{87}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys had larger volume ratio of $\alpha$-Fe(Co) than that of higher Nd content alloy and showed high remanence of about 1.6 T. On the contrary, the increase of Nd content in $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ alloys gave rise to gradual increase of an amount of $Nd_{2}{(Fe,\;Co)}_{14}B$ phase and improved coercivity. An optimally annealed $Nd_{5}{(Fe_{0.9}Co_{0.1})}_{85}B_{6}Nb_{3}Cu_{1}$ alloy showed the most improved hard mag¬netic properties. The remanence, coercivityand energy product of the alloy were 1.35 T, 219 kA/m (2.75 kOe), and $129\;kJ/m^{3}$ (16.2 MGOe), respectively.

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A Study on Photoreceptor by Using the Effect of Additives

  • Yu, Jin;Kim, Yeong Sun;Yu, Guk Hyeon
    • Bulletin of the Korean Chemical Society
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    • v.22 no.7
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    • pp.709-715
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    • 2001
  • We have been studied photosensitization mechanism's additive effect, of perylene 3,4,9,10-tetracarboxyl-diimide and X-phthalocyanine (charge generation materials), using the photochemical and photoelectrochemical approach. It was found that the photoreceptor on the excited state reacts with metal oxide, which creates the charge transfer on the interface of SnO2/electrolyte. In the electrode (X5P1) made of five X-phthalocyanine and single perylene 3,4,9,10-tetracarboxyldiimide layers, the cathodic photocurrent of X-phthalocyanine in the 400-600 nm region was increased by the addition of perylene 3,4,9,10-tetracarboxyldiimide. The maximum wavelength of fluorescence of perylene 3,4,9,10-tetracarboxyldiimide showed no dependence on the temperature. The addition of 4-dibenzylamino-2-methylbenzaldehyde diphenylhydrazone known as charge transport material was represented as decreasing photocurrent for X-phthalocyanine and perylene 3,4,9,10-tetracarboxyldiimide, respectively. In the electrode (X1P1) made of single X-phthalocyanine and single perylene 3,4,9,10-tetracarboxyldiimide layers, an anodic photocurrent of about 10.5 nA was generated by addition of hydroquinone at 550 nm. And the characteristic of photoinduced discharge was shown to decrease by a factor of 5 and the speed of dark decay was increased by a factor of 1.2.

BIOLOGICAL STUDIES ON THE FRESH-WATER SHRIMPS IN KOREA 2. The Ecology of Palaemon modestua (한국산 민물 새우류에 관한 생물학적 연구 2. Palaemon modestua의 생태)

  • CHUNG Kyung-Suk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.3 no.2
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    • pp.110-116
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    • 1970
  • The fresh_water shrimp, Palaemon modestua is one of the most important types of bait f[r fishing and can be found abundantly in the Nak-Dong River. The larval development of Palaemon modestua in the laboratory was reported by Liu (1949), Kown and Uno (1968), but they didn't give any ecological features in the natural environments. Shrimps were collected from the Nak-Dong River near Pusan, once a month from July to December 1953 and from February to June 1969 respectively. The following is a summary of the results: 1. They breed from April to September, mainly in July. 2. A generation of this type of shrimps appears to be approximately one year and after breeding they die off up untill the end of October. 3. The sex ratio (female=100) is $44.2\~95.5$ (mean 78.5) and goes down during spawning seasons. 4. The minimum size of the ovigerous female is approximately 0.5 gram in body weight, 29mm in body length and 7mm in carapace length. 5. Most shrimps of $31\~41mm$ In body length lay eggs. 6. The relationship between the boby length (X) and the number of eggs (Y) is: $$Y=0.0000203937X^{3.5668}$$ 7. The relationship between the body length (X) and the body weight (Y) is: $$Y=0.099801X^{2.85407}$$ in female. $$Y=0.004198X^{3.40614}$$ in Male. 8. The relationship between the carapace length (X) and the body weight (Y) is: $$Y=5.56008X^{2.25503}$$ in female. $$Y=5.09541X^{2.28875}$$ in male. 9. The relationship between the carapace length (X) and the body length (Y) is: Y= 5.07540+3.36057X in female. Y=4.90514+3.47791X in male.

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Perovskite-Like Strontium Titanium Zirconium Oxide Solid Solutions Prepared at Atmospheric Pressure

  • Choy, Jin-Ho;Kim, Ha-Suck;Kwon, Young-Uk;Kim Chong Hee
    • Bulletin of the Korean Chemical Society
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    • v.6 no.6
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    • pp.344-347
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    • 1985
  • Perovskite type oxides of $SrTiO_3,SrZrO_3,and\;SrTi_{1-x}Zr_xO_3$ have been systematically synthesized at $1250^{\circ}C$and $1550^{\circ}C$ with specimens containing additions of up to x=0.9 of zirconium by solid state reactions and characterized by X-ray diffraction. X-ray diffraction studies showed that the compound $SrTi_{1-x}Zr_xO_3$ has cubic structure. The lattice paramters of $SrTi_{1-x}Zr_xO_3$ solid solutions obey the Vegard's law and fairly large increase in volume can acompany the formation of this solution with increasing Zr content(X). Assuming the lattice constants of perovskite type compounds $A(B_{1-x}B'_x)O_3$where $B_{1-x}B'_x$ is $Ti_{1-x}Zr_x$, to be a linear function of the ionic radii of B and B' ions, the disordered ion pair of $Ti^{4+}$and $Zr^{4+}$ was verified from the lattice constants of a series compounds varying x=0,0.05, 0.25, 0.5, 0.75, 0.9, and 1.0 with known isovalent pairs.

Electrochemical Performance and Cr Tolerance in a La1-xBaxCo0.9Fe0.1O3-δ (x = 0.3, 0.4 and 0.5) Cathode for Solid Oxide Fuel Cells

  • Choe, Yeong-Ju;Hwang, Hae-Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.308-314
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    • 2015
  • The electrochemical performance and Cr poisoning behavior of $La_{1-x}Ba_xCo_{0.9}Fe_{0.1}O_{3-{\delta}}$ (LBCF, x = 0.3, 0.4, 0.5) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathodes were investigated for solid oxide fuel cells (SOFCs). The polarization resistance of the LBCF/GDC/LBCF symmetrical cell was found to decrease with increasing Ba content (x value). This phenomenon might be associated with the high oxygen vacancy concentration in the LBCF sample, with x = 0.5. In addition, there was no chromium poisoning in the LBCF cathode. On the other hand, the polarization resistance of the LSCF cathode was found to significantly increase after exposure to gaseous chromium species; it appears that this result stemmed from the formation of $SrCrO_4$ phase. Therefore, it can be expected that LBCF can be a durable potential cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFC).

NONLINEAR VARIATIONAL INEQUALITIES AND FIXED POINT THEOREMS

  • Park, Sehie;Kim, Ilhyung
    • Bulletin of the Korean Mathematical Society
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    • v.26 no.2
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    • pp.139-149
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    • 1989
  • pp.Hartman and G. Stampacchia [6] proved the following theorem in 1966: If f:X.rarw. $R^{n}$ is a continuous map on a compact convex subset X of $R^{n}$ , then there exists $x_{0}$ ..mem.X such that $x_{0}$ , $x_{0}$ -x>.geq.0 for all x.mem.X. This remarkable result has been investigated and generalized by F.E. Browder [1], [2], W. Takahashi [9], S. Park [8] and others. For example, Browder extended this theorem to a map f defined on a compact convex subser X of a topological vector space E into the dual space $E^{*}$; see [2, Theorem 2]. And Takahashi extended Browder's theorem to closed convex sets in topological vector space; see [9, Theorem 3]. In Section 2, we obtain some variational inequalities, especially, generalizations of Browder's and Takahashi's theorems. The generalization of Browder's is an earlier result of the first author [8]. In Section 3, using Theorem 1, we improve and extend some known fixed pint theorems. Theorems 4 and 8 improve Takahashi's results [9, Theorems 5 and 9], respectively. Theorem 4 extends the first author's fixed point theorem [8, Theorem 8] (Theorem 5 in this paper) which is a generalization of Browder [1, Theroem 1]. Theorem 8 extends Theorem 9 which is a generalization of Browder [2, Theorem 3]. Finally, in Section 4, we obtain variational inequalities for multivalued maps by using Theorem 1. We improve Takahashi's results [9, Theorems 21 and 22] which are generalization of Browder [2, Theorem 6] and the Kakutani fixed point theorem [7], respectively.ani fixed point theorem [7], respectively.

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Microwave Dielectric Properties of the (l-x)$TiTe_3O_{8}$-x$MgTiO_3$ Ceramics with Sintering Temperature (소결온도에 따른 (l-x)$TiTe_3O_{8}$-x$MgTiO_3$ 세라믹스의 마이크로파 유전 특성)

  • 최의선;김재식;이문기;류기원;이영희
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.9
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    • pp.459-463
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    • 2004
  • In this study, the (l-x)$TiTe_3O_{8}$-x$MgTiO_3$ ceramics were investigated to obtain the improved dielectric properties of a high temperature stability and a sintering temperature of less than $900^{\circ}C$ which was necessary for the LTCC. According to the X-ray diffraction patterns of the (l-x)$TiTe_3O_{8}$-x$MgTiO_3$(x=0∼1) ceramics, the columbite structure of $TiTe_3O_{8}$ and ilmenite structure of $MgTiO_3$ were coexisted. Increasing the $MgTiO_3$ mole ratio(x), the density and dielectric constant were decreased and temperature coefficient of resonant frequency was moved to the negative direction and the quality factor was increased. In the case of the 0.6$TiTe_3O_{8}$-0.4$MgTiO_3$ ceramics sintered at $830^{\circ}C$ for 3hr., the microwave dielectric properties were $\varepsilon_{\gamma}$=29.3, Q${\times}$$f_{\gamma}$=39.600GHz and $\tau$$_{f}$=+9.3ppm/$^{\circ}C$.