• Title/Summary/Keyword: $Y_2O_3$ particles

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Effect of Y2O3 and La2O3 on the Sintering Behavior of Alumina (Y2O3 및 La2O3 첨가가 알루미나의 소결거동에 미치는 영향)

  • Lee, Keun Bong;Kang, Jong Bong
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.90-94
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    • 2016
  • In this study, to increase the strength and enhance the sintering property of $Al_2O_3$, $Y_2O_3$ and $La_2O_3$ were added; the effects of these additions on the sintering characteristics of $Al_2O_3$ were observed. Adding 1% of $Y_2O_3$ to $Al_2O_3$ repressed the development of abnormal particles and reduced the grain boundary migration of $Al_2O_3$, curbing pores to capture particles; as such, the material showed a fine microstructure. But, when over 2% of $Y_2O_3$ was added, the sintering property was reduced because of abnormal particle grain growth and pore formation in particles. Adding 1% of $Y_2O_3$ and $La_2O_3$ to $Al_2O_3$ led to the development of abnormal particles and formed pores in the particles; when over 3% of $La_2O_3$ was added, the sintering property was reduced because the shape of the $Al_2O_3$ particles changed to angled plates.

Formation of Cobalt Ferrit Epitaxial Iron Oxide and Their Magnetic Properties(I) (코발트 훼라이트 에피탁시얼 산화철의 생성과 자기특성(I))

  • 변태봉;김대영;이재영;손진군
    • Journal of the Korean Magnetics Society
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    • v.2 no.1
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    • pp.8-14
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    • 1992
  • To improve the coercivity of ${\gamma}-Fe_{2}O_{3}$ particles. We have made cobalt ferrite epitaxial ${\gamma}-Fe_{2}O_{3}$ particles by crystallizing cobalt ferrite on the surface of ${\gamma}-Fe_{2}O_{3}$ particles. The coercivity of $Co_{x}Fe_{3-x}O_{4}$ which is conform to coating layer showed the most superior characteristic when the value of x was 1. On the formation of cobalt epitaxial ${\gamma}-Fe_{2}O_{3}$ particles, controlling reaction atmosphere as oxidation at. mosphere after non-oxidation atmosphere was the optimum condition to prepare cobalt epitaxial ${\gamma}-Fe_{2}O_{3}$ particles with superior magnetic properties. Epitaxial growth of cobalt ferrite on the surface of ${\gamma}-Fe_{2}O_{3}$ particles was accomplished at $90^{\circ}C$ for 30 minutes.

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Experiment on Heat Transfer and Absorption Performance Enhancement for Binary Nanofluids (NH3/H2O + Nano-Particles) (이성분 나노유체 (NH3/H2O + 나노입자)의 열전달 및 흡수성능 촉진실험)

  • Lee, Jin-Ki;Jung, Chung-Woo;Kang, Yong-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.9
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    • pp.669-675
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    • 2008
  • The objectives of this paper are to examine the effect of nano-particles on the pool type absorption heat transfer enhancement and to find the optimal conditions to design a highly effective compact absorber for ammonia/water absorption system. The effect of $Al_2O_3$ nano-particles and carbon nanotube(CNT) on the absorption performance is studied experimentally. The experimental ranges of the key parameters are 20% of ammonia concentration, $0{\sim}0.08\;vol%$ (volume fraction) of CNT particles, and $0{\sim}0.06 \;vol%$ of $Al_2O_3$ nano-particles. For the ammonia/water nanofluids, the heat transfer rate and absorption rate with 0.02 vol% $Al_2O_3$ nano-particles were found to be 29% and 18% higher than those without nano-particles, respectively. It is recommended that the concentration of 0.02 vol% of $Al_2O_3$ nano-particles be the best candidate for ammonia/water absorption performance enhancement.

Interfacial Electrical Studios on Adhesion of Hematite Particles to Polyester Fabric and their Removal from the Fabric(Part 2) (Polyester 직물에의 Hematite 입자의 부착과 제거에 관한 계면 전기적고찰 (제2보))

  • 강인숙;김성련
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.5
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    • pp.765-773
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    • 1995
  • Effect of interfacial electrical conditions such as, the f potential of PET fiber and u-Fe203 particles, the stability parameter and potential energy of interaction on adhesion of a-Fe903 particles to PET fabric and their removal from the fabric, were investigated as functions of pH, electrolyte and ionic strength. The stability parameter, potential energy of interaction between a-Fe2O3 particles and PET fabric were calculated by using the heterocoagulation theory for a sphere-plate model The adhesion of a-Fe2O3 particles to PET fabric and their removal from PET fabric were carried out by using water bath shaker and Terg-O-Tometer under various solution conditions. The adhesion of a-Fe2O3 particles to the PET fabric and the removal of a-Fe2O3 particles from the PET fabric were biphasic and were maximum and minimum at pH 7~8, respectively. With high pH and polyanion electrolytes in solution, the adhesion of a-Fe2O3 particles to the PET fabric was low but effects of electrolytes on the removal of a-Fe2O3 particles from the PET fabric was small. The adhesion of a-Fe2O3 particles to the PET fabric and the removal of a-Fe2O3 Particles from the PET fabric were biphasic, and were lowest and highest at the ionic strength 1$\times$10-3, respectively. The adhesion of a-Fe2O3 particles to PET fabric was well related with the interfacial electrical conditions; it was negatively correlated with the f potentials of a-Fe2O3 Particles of its absolute value, the stability parameter and the maximum of total potential energy, while, the adhesion was not related with the t potentials of PET fiber itself. Therefore, the primary factor determining the adhesion of a-Fe203 particles to PET fabric may be the stability of dispersed particles caused by the electrical repulsion of particles. The removal of a-Fe203 particles from PET fabric was not related to such interfacial electrical conditions as the t potentials of PET fiber, the stability parameter and the maximum of total potential energy but removal was related to t potential of a-Fe203 particles.

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Interfacial Characteristics of $Al-2024/Al_2O_{3p}$ Composite Fabricated by Rheo-compocasting (Rheo-compocasting법으로 제조된 알루미나 입자강화 Al합금 복합재료의 계면반응)

  • Hyun, Suhk-Jong;Ye, Byung-Joon
    • Journal of Korea Foundry Society
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    • v.13 no.3
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    • pp.285-294
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    • 1993
  • Aluminum alloy 2024 matrix composites reinforced with $Al_2O_3$ particles, were prepared by rheo-compocasting, a process which consists of the incoporation distribution of reinforcement by stirring within a semi-solid alloy. The microstructures and characteristics of the interfaces have been studied using optical microscope and scanning electon microscope in 2024 aluminum alloy composites reinforced with $Al_2O_3$ particles. The main results are as follows: (1) $Al_2O_3$ particles were well distributed in composites by using rheo-compocasting. (2) As the addition of $Al_2O_3$ particle increases, the average dendrite numbers and the hardness were increased. (3) Interaction between $Al_2O_3$ particles and alloy 2024 resulted in the formation of Mg and Cu element rich region around the $Al_2O_3$ particles.

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Experimental of Absorption Performance Enhancement for Binary Nanofluids($NH_3/H_2O$ + Nano Particles) (이성분 나노유체($NH_3/H_2O$+나노입자)의 흡수성능 촉진실험)

  • Lee, Jin-Ki;Jung, Chung-Woo;Koo, June-Mo;Kang, Yong-Tae
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.124-129
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    • 2008
  • The objectives of this paper are to examine the effect of nano-particles on the pool type absorption heat transfer enhancement and to find the optimal conditions to design a highly effective compact absorber for $NH_3/H_2O$ absorption system. The effect of $Al_2O_3$ and CNT particles on the absorption performance is studied experimentally. The experimental ranges of the key parameters are 20% of $NH_3$ concentration, $0{\sim}0.08%$ (volume fraction) of CNT particles, and $0{\sim}0.06%$ (volume fraction) of $Al_2O_3$ nano-particles. For the $NH_3/H_2O$ nanofluids, the heat transfer rate and absorption rate with 0.02 vol% $Al_2O_3$ nano-particles were found to be 28.9% and 17.8% higher than those without nano-particles, respectively. It is recommended that the concentration of 0.02 vol% of $Al_2O_3$ nano-particles be the best candidate for $NH_3/H_2O$ absorption performance enhancement.

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Microstructure and Mechanical Properties of $Al_2$O$_3$/t-ZrO$_2$ Particulate Composites (Al$_2$O$_3$/t-ZrO$_2$ 입자복합체의 미세구조 및 기계적 성질)

  • 심동훈;이윤복;김영우;오기동;박홍채
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.734-741
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    • 1999
  • Al2O3/t-ZrO2 particulate composites were prepared by sintering at 150$0^{\circ}C$ and 1$600^{\circ}C$ for 2h in air and microstructure and mechanical properties of the composites were investigated. Although most ZrO2 particles existed at Al2O3 grain boundaries a few ZrO2 particles within Al2O3 grains. Al2O3 grain growth was depressed due to the pinning effect by ZrO2 particles. During sintering coarsening of intergranular ZrO2 particles occurred as a results of the elimination of ZrO2 intraagglomerate grain boundaries and the coalescence of dragged ZrO2 particles by migrating Al2O3 grain boundries. Changes in mechanical properties of Al2O3 composites were dependant on microstructure of Al2O3 matrix and on size and structure of dispersed ZrO2.

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The Formation of Hematite as Precursor for Magnetic Recording Media from Amorphous Ferric Hydroxide (비정질 수산화제이철로 부터 자기 기록 매체용 전구체인 헤마타이트 입자의 제조)

  • 변태봉;손진군;김태옥
    • Journal of the Korean Magnetics Society
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    • v.6 no.4
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    • pp.225-234
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    • 1996
  • Needle-like $\alpha-Fe_{2}O_{3}$ particles as precursor for magnetic recording media were prepared directly from amorphous ferric hydroxide in the aqueous solution by hydrothermal reaction. Ellipsoidal or rectangular $\alpha-Fe_{2}O_{3}$ particles were formed in the range of pH 10.75~11.75. The length and acicularity of $\alpha-Fe_{2}O_{3}$ particles were decreased gradually with increasing of citric acid concentration. The formation of needle-like $\alpha-Fe_{2}O_{3}$ particles was inhibited above citric acid concentration of $1.5{\times}10^{-4}\;mol$. We can synthesize $\alpha-Fe_{2}O_{3}$ particles with the most superior acicularity at $140^{\circ}C$ and can not expect a good needle-like particles above $220^{\circ}C$.

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Synthesis of Spherical Fine $PbTiO_3$ Particles by the Spray Pyrolysis Method Using Ultrasonic Vibrator (초음파 분무 열분해법에 의한 구형의 $PbTiO_3$ 미립자 제조)

  • 이서영;이동주;신건철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.1 no.1
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    • pp.107-116
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    • 1991
  • Fine $PbTiO_3$ Particles were synthesized from the $Pb(NO_3)_2$and $TiO(NO_3)_2$ solution by the spray pyrolysis method using the ultrasonic vibrator as a mist generator. The obtained particles were characterized. The mechanisms of particle formation were discussed in comparison with those if other particles, such as $BaTiO_3$, $ZnO_2$, ZnO ....., in the same spray pyrolysis process.

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Hydrothermal synthesis of $BaTiO_3$ fine particles (수열법에 의한 $BaTiO_3$ 미립자의 합성)

  • 최종건;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.49-54
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    • 1998
  • $BaTiO_3$ fine particles were synthesized by hydrothermal method. $TiO_2$ and $Ba(OH)_2{\cdot}8H_2O$ were used as staring materials, and it was possible to synthesize $BaTiO_3$ fine particles in pure water by using excess $Ba(OH)_2{\cdot}8H_2O$. The shape of synthesized particles are irregular but near spherical, and the particle size depends on the temperature and Ba/Ti atomic ratio.

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