• Title/Summary/Keyword: $Y_2O_3$ inclusion

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Occurrence and Genetic Environments of Quartz Veins from the Jukwangri area, Hwawon-myeon, Jeollanamdo, Republic of Korea (전남 화원면 주광리일대 석영맥의 산상 및 생성환경)

  • Yoo, Bong-Chul;Lee, Hyun-Koo;Choi, Dong-Ho
    • Economic and Environmental Geology
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    • v.39 no.6 s.181
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    • pp.653-662
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    • 2006
  • Quartz veins from the Jukwangri area of Hwawon-myeon are epithermal quartz veins that are filling the NW or NE-trending faults within Precambrian metasedimentary rocks. Based on their prolongation and ore grades, No. 1 quartz vein can be traced for about 200 m and varies 0.1 to 3 m in thickness. Mineralization of No. 1 quartz vein can be divided into hypogene and supergene stages. Hypogene stage is associated with hydrothermal alteration minerals(phyllic and argillic zones) such as illite, sericite and sulfides such as pyrite, arsenopyrite, sphalerite. chalcopyrite, galena, argentian tetrahedrite. Supergene stage is composed of Fe-Mn oxide, Zn-Fe oxide and Pb oxide. Fluid inclusion data indicate that homogenization temperature and salinity of hypogene stage range from 187 to $306^{\circ}C$ and ken 0.0 to 6.2 wt.% eq. NaCl, respectively. They suggest that ore forming fluids were progressively cooled and diluted from mixing with meteoric water. Oxygen($-4.1{\sim}4.1%o$) and hydrogen($-107{\sim}-88%o$) isotope com-positions indicated that hydrothermal fluids were derived from meteoric and evolved by progressive mixing with meteoric water during mineralization.

Pretreatment of normal responders in fresh in vitro fertilization cycles: A comparison of transdermal estradiol and oral contraceptive pills

  • Pereira, Nigel;Petrini, Allison C.;Zhou, Zhen N.;Lekovich, Jovana P.;Kligman, Isaac;Rosenwaks, Zev
    • Clinical and Experimental Reproductive Medicine
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    • v.43 no.4
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    • pp.228-232
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    • 2016
  • Objective: The aim of this study was to investigate the impact of pretreatment with transdermal estradiol ($E_2$) compared to oral contraceptive pills (OCPs) on controlled ovarian stimulation (COS) response in normal responders undergoing fresh in vitro fertilization (IVF)-embryo transfer (ET) cycles. Methods: A retrospective cohort study was performed of normal responders undergoing fresh IVF-ET cycles who received pretreatment with transdermal $E_2$ versus OCPs prior to fresh IVF-ET. The total days of ovarian stimulation, total dosage of gonadotropins, total number of oocytes, and mature oocytes retrieved were noted. Pregnancy outcomes after ET were also recorded. Results: A total of 2,092 patients met the inclusion criteria: 1,057 and 1,035 patients in the transdermal $E_2$ and OCP groups, respectively. Patients in the OCP group had a longer duration of COS ($10.7{\pm}1.63days$, p< 0.01) than the $E_2$ group ($9.92{\pm}1.94days$). Patients in the OCP group also required higher cumulative doses of gonadotropins ($2,657.3{\pm}1,187.9IU$) than those in the $E_2$ group ($2,550.1{\pm}1,270.2IU$, p= 0.002). No statistically significant differences were found in the total and mature oocytes retrieved or in the rates of biochemical pregnancy, clinical pregnancy, spontaneous miscarriage, and live birth between the groups. Conclusion: Our findings suggest that compared to OCPs, pretreatment with transdermal $E_2$ is associated with a shorter duration of ovarian stimulation and lower gonadotropin utilization, without compromising the oocyte yield or pregnancy outcomes in normal-responder patients undergoing fresh IVF.

Study on Tribological Characteristics of Machine Component in Boundary Lubrication (경계윤활에서 기계 부품 소재의 트라이볼로지적 특성에 관한 연구)

  • Kim, Myeong-Gu;Seo, Kuk-Jin;Nam, Jahyun;Kim, Dae-Eun
    • Tribology and Lubricants
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    • v.35 no.6
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    • pp.356-361
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    • 2019
  • The friction and wear between machine components directly influence the energy loss and failure in various machines. Therefore, there is always a demand for finding methods to reduce friction and wear. Of the possible methods, lubrication is a widely used method for reducing friction and wear. In the case of lubrication, it is important to analyze the tribological behavior in the boundary lubrication because most of friction and wear occurs in the boundary lubrication regime. Cast iron has been regarded as a good material for industrial applications due to the excellent mechanical properties and high productivity. Especially, nodular cast iron is a material that shows better mechanical properties and wear-resistance compared with cast iron due to inclusion of spheroidal graphite. In this work, we investigated the tribological characteristics of nodular cast iron with respect to different counter parts in boundary lubrication regime. Sliding tests were conducted with SUJ2, ZrO2, Si3N4 balls as counter parts using a pin-on-disk type tribotester. The results showed different friction and wear behaviors with different counter parts. The case of ZrO2 showed the lowest wear rate in specimen and no significant ball wear. In case of SUJ2, it showed similar wear rate with ZrO2 case in specimen and the highest friction coefficient. The case of Si3N4 showed the lowest friction coefficient, 33% lower than the case of SUJ2. It showed 16.9 times larger wear rate in specimen and 43% larger wear rate in ball compared to that of the SUJ2 case.

Talc Mineralization in the Middle Ogcheon Metamorphic Belt (II) : Poongjeon Talc Deposit (중부옥천변성대의 활석광화작용에 관한 연구 (II) : 풍전활석광상을 중심으로)

  • Park, Hee-In;Lee, In Sung;Hur, Soon Do;Shin, Dong Bok
    • Economic and Environmental Geology
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    • v.30 no.6
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    • pp.543-551
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    • 1997
  • Poongjeon talc deposits is emplaced in dolomite and dolomitic limestone of the Cambro-Ordovician Samtaesan Formation. Ore in Poongjeon is low grade talc and the deposit has been known as the contact metasomatic or hydrothermal replacement type related to the intrusion of late Cretaceous granite in this area. X-ray diffraction, electron microprobe analysis, fluid inclusion and stable isotope analysis were utilized to examine the mineralogy of the ore and the origin of the ore fluid. The ore from Poongjeon mine mainly consists of talc and tremolite with minor amount of illite, vermiculite, smectite, and chlorite-vermiculite mixed layer. Occurrence of ore body indicates that the talc-tremolite ore was formed through the replacement by the $SiO_2$-rich hydrothermal fluid along the bedding and dike boundaries, or contact of amphibolite and basic dike with carbonate rocks. The temperature and pressure of the ore forming fluids at the time of the talc mineralization were estimated as $350^{\circ}C$ and 400 bar, respectively, based on the heating and freezing data of the fluid inclusions in quartz from talc-tremolite veins. During the talc-tremolite formation, fluids were divided into $CO_2$-enriched fluid and $CO_2$-poor fluid from $CO_2$ immiscibility (or effervescence). Oxygen isotope values (${\delta}^{18}O$) of the talc-tremolite fall within a range between 12.2 and 12.9‰. Hydrogen isotope values(${\delta}D$) of the ore range from -60 to -85‰ and $H_2O$ contents range from 2.0 to 3.4 wt.%. ${\delta}^{18}O$ and ${\delta}D$ values of talc ore indicate that the hydrothermal fluid involved in talc-tremolite formation was of igneous origin. Oxygen and hydrogen isotopic exchange between talc ore and the surface water was negligible after talc-tremolite ore formation.

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Effect of Dietary Supplementation of Blood Meal and Additional Magnesium on Carnosine and Anserine Concentrations of Pig Muscles

  • Park, Se Won;Kim, Chan Ho;Kim, Jong Woong;Shin, Hye Seong;Paik, In Kee;Kil, Dong Yong
    • Food Science of Animal Resources
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    • v.34 no.2
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    • pp.252-256
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    • 2014
  • The objective of this study was to investigate the effect of dietary supplementation of blood meal as a source of L-histidine, and the addition of magnesium (Mg) as a catalyst of carnosine synthetase for the carnosine and anserine concentrations of pig muscles (longissimus dorsi, LD and vastus intermedius, VI). A total of twenty-four pigs with an average body weight of $60.2{\pm}4.2$ kg were randomly allotted to one of three dietary treatments (eight replicates), during 56 d of the feeding trial. Dietary treatments included: (1) Basal: basal diet; (2) BM: 95% basal diet + 5% blood meal; and (3) BM+Mg: 94.8% basal diet + 5% blood meal + 0.2% MgO (60% Mg). Results indicated that drip loss in the LD was less (p<0.05) for meat with BM+Mg treatment than that with Basal treatment, but the values for BM treatment did not differ from those of the other two treatment groups. The concentrations of carnosine in the LD were increased by 10.0% in both BM and BM+Mg treatment groups over the Basal treatment group (significance not verified). The concentrations of carnosine and anserine in the VI were not affected by the dietary treatments. Inclusion of additional Mg in diets had no effect on carnosine and anserine concentrations in the LD and VI. In conclusion, dietary supplementation of blood meal could be a potential method of fortifying the pork with carnosine. Inclusion of additional Mg in the diets containing blood meal had no benefit on carnosine and anserine depositions in pig muscles.

Gold Mineralization of the Youngbogari Mine, Youngdong Area (영동지역 영보가리 광산의 금광화 작용)

  • Heo, Chul-Ho;Chi, Se-Jung
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.115-124
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    • 2007
  • Electrum-sulfide mineralization of the Youngbogari mine area occurred in two stages of massive quartz veins that fill the fractures along the fault/shear zones in the Precambrian gneiss. Ore mineralogy is simple, consisting of arsenopyrite $(31.4{\sim}33.4atom.%As)$, pyrite, sphalerite $(4.1{\sim}17.6mole%FeS)$, galena, chalcopyrite, argentite, and electrum. Electrum $(60.3{\sim}87.6atom.%Ag)$ is associated with galena, chalcopyrite and late sphalerite infilling the fractures in quartz and sulfides. Fluid inclusion data show that ore mineralization was formed from $H_2O-CO_2-CH_4-NaCl$ fluids $(X_{CO2+CH4}=0.0\;to\;0.2)$ with low salinities (0 to 10wt.% eq. NaCl) at temperatures between $200^{\circ}\;and\;370^{\circ}C$. Gold-silver mineralization occurred later than the base-metal sulfide deposition, at temperatures near $250^{\circ}C$ and was probably a result of cooling and decreasing sulfur fugacity caused by sulfide precipitation and/or $H_2S$ loss through fluid unmixing.

Visible Light Driven ZnFe2Ta2O9 Catalyzed Decomposition of H2S for Solar Hydrogen Production

  • Subramanian, Esakkiappan;Baeg, Jin-Ook;Kale, Bharat B.;Lee, Sang-Mi;Moon, Sang-Jin;Kong, Ki-Jeong
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.2089-2092
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    • 2007
  • Tantalum-containing metal oxides, well known for their efficiency in water splitting and H2 production, have never been used in visible light driven photodecomposition of H2S and H2 production. The present work is an attempt in this direction and investigates their efficiency. A mixed metal oxide, ZnFe2Ta2O9, with the inclusion of Fe2O3 to impart color, was prepared by the conventional ceramic route in single- and double-calcinations (represented as ZnFe2Ta2O9-SC and ZnFe2Ta2O9-DC respectively). The XRD characterization shows that both have identical patterns and reveals tetragonal structure to a major extent and a minor contribution of orthorhombic crystalline system. The UV-visible diffuse reflection spectra demonstrate the intense, coherent and wide absorption of visible light by both the catalysts, with absorption edge at 650 nm, giving rise to a band gap of 1.9 eV. Between the two catalysts, however, ZnFe2Ta2O9-DC has greater absorption in almost the entire wavelength region, which accounts for its strong brown coloration than ZnFe2Ta2O9-SC when viewed by the naked eye. In photocatalysis, both catalysts decompose H2S under visible light irradiation (λ ≥ 420 nm) and produce solar H2 at a much higher rate than previously reported catalysts. Nevertheless, ZnFe2Ta2O9-DC distinguishes itself from ZnFe2Ta2O9-SC by exhibiting a higher efficiency because of its greater light absorption. Altogether, the tantalum-containing mixed metal oxide proves its efficient catalytic role in H2S decomposition and H2 production process also.

The Machinability of 2011 P/M Al Alloys Extruded Rapidly solidified by Rotating Disc Atomization (원심 분부법으로 제조된 P/M 2011 Al 합금 압출재의 절삭성)

  • Jeon, Chang-Bae;Kim, Jong-Chan
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.641-647
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    • 1998
  • The machinability properties of P/M 2011 AI alloys extruded rapidly solidified by rotating disc atomization were investigated in this study. The Pb-Bi particles were very uniformly and finely dispersed in the P/M 2011 AI alloys extruded rapidly solidified. According to the increase of cutting speed, the short discontinuous chips were produceed and continuous chips were formed from the lower feed values of O.lmm/rev. The surface roughness is depend on the feed values, not cutting depth and cutting speed. The short discontinuous chips were formed due to dispersed $AI_20_3$ particles and Pb- Bi inclusion.

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Mineralogy and Genesis of Hydrothermal Deposits in the South-eastern Part of Korean Peninsula:(2) Bobae Sericite Deposits (우리나라 동남부 지역의 열수광상에 대한 광물학적 및 광상학적 연구:(2) 보배견운모 광상)

  • 김수진;추창오;박희인;노진환
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.2
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    • pp.129-140
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    • 1991
  • Two illite polytypes, 2M1 and 1Md, have been identified from the sericite deposits of the Bobae mine, Kimhae, Kyungsangnam-do. Each polytype has characteristic grain size, chemical composition, and occurrence. 2M1 illite occurs predominantly in the sericitic alteration zone, while 1Md illite occurs predominantly in the propylitic alteration zone, implying that the former was formed in the higher temperature than the latter. Illites can be subdivided into two types based on their crystal sizes;(1) the $\mu\textrm{m}$-sized illite which is below 0.01mm(100$\mu\textrm{m}$) in size and consists of 2M1 and 1Md type, (2) the mm-sized illite which is above 0.01mm in size and consists only of 2M1 type. Especially illite below 1$\mu\textrm{m}$ is premominantly of 1Md type. Therefore, it seems likely that illite crystal size is to some extent related to the polytype. XRD data show that there is no interstratified layer in illites regardless of the crystal size and polytype. Activity of muscovite component of the $\mu\textrm{m}$-sized illite is 0.843 while that of the mm-sized illite is 0.790. However, the latter is more similar to muscovite in crystal structure than the former is. The mm-sized illite has less Al and more Kthan the $\mu\textrm{m}$-sized illite. In both illites, Si contents show a positive relation to octahedral Mg. Fluid inclusion study and mineral association show that the formation temperature of illite is $270-330^{\circ}C$. The major chemical processes leading to the formation of sericitic deposit as well as the alteration zones are the leaching of SiO2 from the country rock and the addition of Al2O3 and K2O into the sericitic ores.

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Preparation and physical properties of flame retardant high density polyethylene utilizing inorganic waste shell powder (재활용(再活用) 굴 껍질 분말(粉末)을 이용(利用)한 고밀도 폴리에틸렌계 난연 소재(素材)의 제조(製造)와 물성(物性))

  • Choi, Jae-Won;Cho, Tae-Keun;Ahn, Jun-Hyung;Lee, Sung-Ho;Chung, Yong-Chan;Jeon, Ho-Seok;Chun, Byoung-Chul
    • Resources Recycling
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    • v.17 no.4
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    • pp.21-29
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    • 2008
  • Waste shell powder was added to the high density polyethylene(HDPE), and resultant mechanical properties and flame retardancy were analyzed in terms of shell content. Compatibilizer(PE-g-MA) was used to enhance the mechanical properties of the prepared HDPE/shell composites, and several flame retardant agents($Al_2O_3$, $Sb_2O_3$) were utilized to improve flame retardancy. Addition of the compatibilizer resulted in an improved mechanical properties due to the increased interfacial bonding between HDPE matrix and shell powder. In the case of impact strength, it even reached to the impact strength of pure HDPE. Also the addition of the flame retardant agents did not exhibit mechanical property decrease. UL-94 flammability test on the prepared HDPE/shell composites indicated that at 40wt% of shell only inclusion, time to ignite the flame and the total time of flame duration increased. When flame retardant agents mixed with shell powder were added to the HDPE matrix, improved flame retardancy was observed. Generally, flame retardancy effect of $Al_2O_3$ was better than $Sb_2O_3$. UL-94 V-0 classification was observed for the specimens with $Al_2O_3$ and compatibilizer at more than 40wt% shell, and also for specimens with $Sb_2O_3$ and compatibilizer at all shell content.