• Title/Summary/Keyword: $Y_2O_3$ inclusion

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Variation of Inclusion Selectivities of the Cadmium Host Complexes with Ammonium Oniums for Aromatic Guest Molecules (암모니움 이온을 가진 카드뮴 호스트 착물의 방향족 게스트 분자에 대한 포접선택성 변화)

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.17 no.3
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    • pp.282-288
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    • 2004
  • Inclusion selectivities of the cyanocadmate host complexes with ammonium oniums, $[Cd_x(CN)_{2x}][onium{\cdot}zG]$ (onium = $NMe_3Et^+$, $NMeEt{_3}^+$ and $NEt{_4}^+$, G = guest), have been investigated for $C_6H_6$ (B), PhMe (T), PhEt (E), ortho (O), meta (M), and para (P) isomers of $C_6H_4Me_2$ as the aromatic guest molecules. From the binary, ternary, quaternary and quinary mixed guests of B, T, E, O, M and P, the order of preference in the $NMe_3Et+$-host is $B{\gg}$T>P${\fallingdotseq}O{\fallingdotseq}M$ and E>O${\gg}P{\fallingdotseq}M$; in the $NMeEt{_3}^+$-host is T>B>P${\gg}O{\fallingdotseq}M$ and E>P${\gg}$M>O; in the $NEt{_4}^+$-host is $B{\gg}T{\fallingdotseq}O{\fallingdotseq}M{\fallingdotseq}P$. However, the $NEt{_4}^+$-host complexes of E, O, M and P mixed-guests were not obtained. These inclusion selectivities were compared to our previous results of the $NMe{_4}^+$-host; T>B>P${\gg}$M>O and E>P${\gg}$M>O.

The Formation Behavior of Non-metallic Inclusion in the Ce-added Hyper Duplex STS (Hyper Duplex STS 중 Ce 첨가 시 비금속개재물 생성거동)

  • Hong, S.H.;Jang, P.Y.;Park, Y.M.;Byun, S.M.;Kim, K.T.;You, B.D.
    • Transactions of Materials Processing
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    • v.19 no.5
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    • pp.311-319
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    • 2010
  • Rare earth metal Ce has a relatively low melting point and high specific gravity. Because of its significantly high affinity to oxygen, nitrogen and sulfur, it is highly usable as a steel refining agent. However, because Ce compound has relatively high specific gravity, it is difficult to be separated from molten steel through floatation, and it degrades the purity of molten steel, or may clog the nozzle in continuous casting. Such problem may be solved by using an appropriate deoxidation agent together with Ce and settling molten steel sufficiently after refining. Thus a fundamental study in the formation behavior of non-metallic inclusion in Ce added Hyper Duplex STS melts was investigated. The addition amount of Ce, melt temperature were considered as experimental variables. A main non-metallic inclusion in mother alloy is 51(wt%MnO) - 27.6(wt%SiO$_2$)- 10.9(wt%$Cr_2O_3$). Non-metallic inclusion was dramatically decreased and the particle size was fined as the amount of Ce increased. Moreover (%MnO) and (%SiO$_2$) of non-metallic inclusion were decreased. But (%$Al_2O_3$)were relatively increased. The number of non-metallic inclusion were decreased and the large particle size were increased by increasing the temperature of molten steel.

LINDELÖFICATION OF BIFRAMES

  • Khang, Mee Kyoung
    • Korean Journal of Mathematics
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    • v.16 no.3
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    • pp.379-388
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    • 2008
  • We introduce countably strong inclusions ${\triangleleft}=({\triangleleft}_1,\;{\triangleleft}_2)$ on a biframe $L=(L_0,\;L_1,\;L_2)$ and i-strongly regular ${\sigma}$-ideals (i =1, 2) and then using them, we construct biframe $Lindel{\ddot{o}}fication$ of L. Furthermore, we obtain a sufficient condition for which L has a unique countably strong inclusion.

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Gemological Characteristics of Rubies and Sapphires from Tanzania (탄자니아산 루비 및 사파이어의 보석광물학적 특성)

  • Park Hee-Yul;Sung Kyu-Youl
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.4 s.46
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    • pp.313-323
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    • 2005
  • XRD, XRF, EPMA, FT-IR, and SEM-CL studies were carried out in order to characterize gemological features of corundum from Tanzania. Fluorescence reaction of the Tanzanian corundum to short and long wave ultraviolet rays was weakly detected. Inclusions in Tanzanian corundum are divided into five types, Type I is fluid-rich inclusion, Type II is gas-rich inclusion, Type III is liquid $CO_{2}$ inclusion, Type IV is solid-rich inclusion, and Type V is a mixture of fluid and solid inclusion and daughter minerals. SEM-CL images show twin structure with growth texture, microphenocryst of spinel solid inclusions, massive and growth texture. Ruby and sapphire from Tanzania are distinctly distinguished by concentrations of Fe and Cr, and plotted in the particular field at $Al_{2}O_{3}/100-Cr_{2}O_{3}-Fe_{2}O_{3}$ diagram. According to FT-IR analysis, all corundum specimens from Tanzania showed the similar patterns, and absorption peaks of $455.09\~459.23\;cm^{-1},\;603.15\~611.71\;cm^{-1},\;1509.00\~1655.05\;cm^{-1}\;and\;3436.41\~3468.87\;cm^{-1}$. These distinctive characteristics mentioned above can be used to identify the locality and source of corundum stones from Tanzania.

Nuclear Magnetic Resonance Spectroscopic Study on Inclusion Complexation of Paracyclophane with Naphthalene Derivatives in Aqueous Solution (프로톤 핵자기공명스펙트럼 측정법에 의한 수용액중 파라시클로판과 나프탈렌 유도체들간의 포접 복합체 형성에 관한 연구)

  • Chun, In-Koo
    • Journal of Pharmaceutical Investigation
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    • v.23 no.3
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    • pp.155-163
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    • 1993
  • Inclusion complexation of 1,7,21,27-tetraaza[7.1.7.1]paracyclophane (CPM 55) with 2,7-dihydroxynaphthalene (2,7-DHN) or 1,3-dihydroxynaphthalene (1,3-DHN) in pD 1.17 $DCl-D_2O$ solution was investigated by $^1H$ nuclear magnetic resonance spectroscopy (NMR) using 4,4'-dimethylaminodiphenylmethane (ACM 11) as an acyclic analog of CPM 55. In CPM 55-naphthalene derivative complex, alkyl protons located in the cavity of CPM 55 were shown to be subjected to anisotropic shielding and protons of naphthalene moiety shifted remarkably to upfield. However, in ACM 11-naphthalene derivative systems, chemical shifts for protons of both DHN compounds were not significant. The remarkable chemical shift changes suggested that the naphthalene moiety of 2,7-DHN or 1,3-DHN was included in the hydrophobic cavity of CPM 55 in aqueous solution. From the continuous variation plots of induced chemical shifts of 2,7-DHN, it was found that 2,7-DHN was included in the cavity of CPM 55 at 1:1 molar stoichiometry. Both computer simulation of a inclusion complex and strong upfield chemical shift changes of 2,7-DHN protons supported the conformation of pseudoaxial inclusion as the presumed geometry of the host-guest complex.

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Anti-Proliferative Effects of β-Cyclodextrin Inclusion Complexes with Coumarinolignans from Acer mono (고로쇠 Coumarinolignan의 β-Cyclodextrin 포접화합물 제조 및 암세포증식 억제활성)

  • Yim, Soon-Ho;Jung, Da-Woon;Williams, Darren R.;Geckeler, Kurt E.;Kim, Kyung Keun;Shin, Boo Ahn;Lee, Ik-Soo;Kim, Huyn Jung
    • Korean Journal of Pharmacognosy
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    • v.46 no.2
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    • pp.133-139
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    • 2015
  • Two coumarinolignans, cleomiscosins C (1) and D (2) were isolated from the heartwood of Acer mono, together with four compounds, 5-O-methyl-(E)-resveratrol-3-O-${\beta}$-D-glucopyranoside (3), 5-O-methyl-(E)-resveratrol-3-O-${\beta}$-D-apiofuranosyl-(1$\rightarrow$6)-${\beta}$-D-glucopyranoside (4), scopoletin (5), and (E)-resveratrol-3-O-${\beta}$-D-glucopyranoside (6). Of them, cleomiscosins C (1) and D (2) were applied to preparing inclusion complex molecules with ${\beta}$-cyclodextrin (${\beta}$-CD) to improve the very poor solubility in cell media. The CD complexes of 1 and 2 exhibited an enhancement of water solubility which is feasible to measure their cytotoxicity using a spectrophotometer in a cell-based assay. Anti-proliferative activity of these complex molecules was successfully estimated on HCT116 human colon cancer cells, and cleomiscosin D (2) showed anti-proliferative effects at the concentration of 1.95~31.2 ${{\mu}g}$/mL in a dose-dependent manner.

Nonmetallic Inclusion in the Large Steel Ingot Casting Process (대형강괴 주조공정 중 비금속개재물 저감연구)

  • NamKung, J.;Kim, Y.C.;Kim, M.C.;Oho, S.H.;Kim, N.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.52-56
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    • 2008
  • Inclusions in forged large steel ingots of plan carbon steel and tool steel are investigated using optical microscop observation and WDX analysis. The large nonmetallic inclusions which is over $30\sim300{\mu}m$ in their diameter were observed in the samples that has been no good on a nondestructive test. The most of the inclusions were consist of some kind of oxides, ${Al_2}{O_3}$, $SiO_2$, CaO, MgO in forms of particles and glassy with an iron particles. The experimental large steel ingot was cast with a pouring temperature which is about ten centigrade higher than the field standard. The inclusions were observed in the test ingot are the smaller than that was in a usual forged steel ingot and is spherical shape with a glassy agglomerated ${Al_2}{O_3}-SiO_2-CaO-MgO$ particle. The pouring temperature is affected on removing the nonmetallic inclusions during the solidification by a floating mechanism.

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Improved methods for the preparation of $(Y_{1-x}Eu_x)_2O_3$:MX and $(Y_{1-x-y}Gd_xEu_y)_2O_3$:MX as red phosphor materials

  • Lee, You-Hui;Han, Sang-Do;Kim, Jung-Duk;Chang, Mi-Yeon;Singh, Ishwar.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.715-718
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    • 2004
  • Substantially improved methods for the preparation of europium-doped yttrium oxide red phosphor with the inclusion of alkali metal halides having a general formula $(Y_{1-x}Eu_x)_2O_3$:MX where 0.025${\leq}$x${\leq}$0.2 and MX is alkali halide in the mole ratio 0.025 to 0.6, more preferably between 0.05 to 0.2 mole, are reported. Another series of the red phosphor materials with general formula $(Y_{1-x-y}Gd_xEu_y)_2O_3$:MX where 0.05${\leq}$x${\leq}$0.40 and 0.025${\leq}$y${\leq}$0.20 and MX is alkali halide in the mole ratio 0.025 to 0.5, more preferably between 0.1 to 0.2 mole, has also been presented. The inclusion of alkali halide greatly increase the luminance of the materials. The materials are very soft with fine particle size less than 100nm. The phosphorescent materials have good luminance in VUV region.

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The Effect of Different Flaked Lupin Seed Inclusion Levels on the Growth of Growing Korean Native Bulls

  • Kwak, B.O.;Kim, C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.8
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    • pp.1129-1132
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    • 2001
  • Seventy-two Korean native bulls, with an average initial body weight of $247.2{\pm}2.34kg$ were used to determine the effect of different flaked lupin seed inclusion levels (0%, 15% and 30%; Control, LS15, LS30, respectively) on growth with a $3{\times}3$ randomized complete block design at the experimental farm of TS Corporation in Korea for 150 days. There were no significant differences in average daily gain (ADG) and feed:gain among treatments, However, LS30 increased concentrate intake and total feed intake (p<0.05) and decreased rice straw intake compared with Control and LS 15 (p<0.05), With inclusion of flaked lupin seeds, concentrate intake and total feed intake increased (p<0.01) and rice straw intake decreased (p<0.05) compared with Control. There were no specific changes in the health status of animals used in this experiment with inclusion of flaked lupin seeds in concentrates. Inclusion of flaked lupin seeds in the concentrates showed a tendency of reduced average daily total feed cost per kg weight gain compared with Control by 1.6% and 3.4%, respectively, in LS15 and LS30.

Ore Minerals, Fluid Inclusion and Stable Isotope Studies of the Bongsang Gold-silver Deposit, Republic of Korea (봉상 금-은광상의 광석광물, 유체포유물 및 안정동위원소 연구)

  • Yoo, Bong-Chul;Lee, Jong-Kil;Lee, Gil-Jae;Lee, Hyun-Koo
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.1-14
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    • 2008
  • The Bongsang gold-silver deposit consists of quartz veins that fill along the fault Bone within Cretaceous andesitic lapilli tuff. Mineralization is occurred within fault-breccia zones and can be divided into two stages. Stage I which can be subdivided into early and late depositional stages is main ore mineralization and stage II is barren. Stage I began with deposition of wall-rock alteration minerals and base-metal sulfides, and was deposited by later native silver, Ag-bearing tetrahedrite, polybasite and base-metal sulfides such like pyrite, sphalerite, chalcopyrite and galena. Fluid inclusion data indicate that homogenization temperatures and salinities of stage I range from 137 to $336^{\circ}C$ and from 0.0 to 10.6 wt.% NaCl, respectively. It suggests that ore forming fluids were cooled and diluted with the mixing of meteoric water. Also, temperature and sulfur fugacity deduced mineral assemblages of late stage I are $<210^{\circ}C\;and\;<10^{-15.4}$ atm, respectively. Sulfur(3.4%o) isotope composition indicates that ore sulfur was mainly derived from a magmatic source as well as the host rocks. The calculated oxygen{2.9%o, 10.3%o(quartz: 7.9%o, 8.9%o, calcite: 2.9%o, 10.3%o)}, hydrogen(-75%o) and carbon(-7.0%o, -5.9%o) isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.