• Title/Summary/Keyword: $Y_2O_3$ additive

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The Effect of Additive Zirconia on Properties in Sintered Body of Chamotte-Kaolin-Agalmatolite System (Chamotte-Kaolin 납석계 소결체의 특성에 미치는 $ZrO_2$의 첨가효과)

  • 박금철;이석로
    • Journal of the Korean Ceramic Society
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    • v.21 no.4
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    • pp.366-372
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    • 1984
  • Unstabilized Zirconia was added to basic composition under 44$mu extrm{m}$ of 57.80wt% Clay-22.20wt% Chamotte-20.00wt% Agalmatolite system. Here the amount and the particle size of Zirconia were 5-25wt% and -20${\mu}{\textrm}{m}$ respectively and the body of these composition was first at 135$0^{\circ}C$. The results obtained from examining the properties of sintered body were as follows. 1. Firing linear shrinkage apparent density and bulk density apparent porosity and water absorption of the samples had the tend to increase according as the particle size of zirconia became larger and the amount of zirconia increased. 2. Modulus of rupture was inversely proportional to the particle size and the additive amount of zirconia, . Especially in case that the particle size of zirconia over 5${\mu}{\textrm}{m}$ and the additive amount of zirconia was 25wt% the modulus of rupture had shrunk drastically. 3. The maximum value of KIC was obtained at 20wt% additive amount of zirconia according to the each particle size of zirconia. Especially the highest value of KIC is 2, 173 M. Pa. M1/2 when the particle size of zirconia is 5~10${\mu}{\textrm}{m}$ and the additive amount is 20wt%.

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Effects of Oxides Added in the Base of Low Voltage ZnO Varistors (저전압용 ZnO 바리스터의 기본조성에 첨가된 산화물의 영향)

  • 진희창;마재평;박수현
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.8
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    • pp.1211-1216
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    • 1989
  • To enhance the breakdown properties of low voltage-oriented ZnO varistor, sample were fabricated with additive oxides and sintering conditions. Addition of TiO2 lowered breakdown voltage` nonlinear resistances were lowered about 10V/mm and nonlinear exponents were not lowered with respect to it with the basic composition. To the samples added TiO2, V2ko5, and Cr2O3, microstructures were observed by SEM, moreover Ti was detected at grainboundaries and within the grain by EDS. Addition of Si-oxides and Sb2O3 increased nonlinear exponent and also increased nonlinear resistance, by addition of TiO2 to these samples at the sintering conditions of 1250\ulcorner and 1 hour we could fabricate low voltage-oriented ZnO varistors with nonlinear exponent of 30 or more and with real breakdown voltage of 30V/mm.

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Magnetic Properties of Sr-ferrite Powder Prepared by Intensive Mechanical Milling Technique

  • Kwon, H.W.;Bae, J.W.
    • Journal of Magnetics
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    • v.8 no.3
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    • pp.118-120
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    • 2003
  • As an alternative promising way of producing high coercivity Sr-ferrite for a permanent magnet application, intensive mechanical milling process was applied to the raw materials of the Sr-ferrite with different composition. Synthesising reactivity for the Sr-ferrite of the mechanically milled raw material containing $SrCO_3$, $La_2O_3$, $Fe_2O_3$, $Co_3O_4$, and $SiO_2$ was inferior to that of the raw material containing $SrCO_3$ and $Fe_2O_3$, The Sr-ferrite prepared from mechanically milled raw materials had profoundly improved magnetic properties compared to the Sr-ferrite prepared by conventional method. Beneficial effect of the substituting ($La_2O_3$, $Co_3O_4$) and additive ($SiO_2$) oxides for improving the magnetic properties was not exploited in the Sr-ferrite prepared from the mechanically milled raw material. The Sr-ferrite powder prepared from the mechanically milled raw materials was magnetically isotropic in nature.

The Influence ${Sb_2}{O_3)$ Addition on Humidity Sensing Properties of $SnO_2$Thick Film Devices (${Sb_2}{O_3)$ 의 첨가가 $SnO_2$후막의 감습 특성에 미치는 영향)

  • 김종택;이덕출;김철수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.294-299
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    • 2000
  • For practical application as a humidity sensor SnO$_2$thick films devices were fabricated on the refresh type electrode by screen printing method and their material and humidity sensing properties were investigated. As a function of Sb$_{2}$/O$_{3}$ addition rate grain size was increased while porosity and initial resistance were rapidly decreased. And the area of resistance variation according to relative humidity was decreased with increasing heat treatment temperature. SnO$_2$thick film device heat treated at 95$0^{\circ}C$ and contained 0.05mole% Sb$_{2}$/O$_{3}$ had a best humidity sensing properties. From this result it is conformed that humidity sensing properties of SnO$_2$thick film devices could be approved by very small amount of Sb$_{2}$/O$_{3}$ addition.

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Effect of $TiO_2$ and $Al(OH)_3$ on Sintering Behavior of $UO_2 - Gd_2 O_3$ Fuel Pellets

  • Kang, Ki-Won;Kim, Keon-Sik;Song, Kun-Woo;Yang, Jae-Ho;Jung, Youn-Ho
    • Nuclear Engineering and Technology
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    • v.32 no.6
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    • pp.559-565
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    • 2000
  • The sintering behavior of UO$_2$-Gd$_2$O$_3$fuel pellets under H$_2$gas has been investigated using dilatometry and XRD methods. The addition of TiO$_2$or Al(OH)$_3$increased the density and grain size. A density of 95% TD and a grain size larger than 6 ${\mu}{\textrm}{m}$ are achieved by the addition of 0.1 wt% TiO$_2$or Al(OH)$_3$. It was found that the densification of UO$_2$-Gd$_2$O$_3$pellets was suppressed in the temperature range of 1300 to 150$0^{\circ}C$, compared to UO$_2$pellets. The formation of a (U,Gd)O$_2$solid solution is the main reason for the suppression of densification. The role of TiO$_2$in densification and grain growth is discussed on the basis of the densification cuwe and ceramography.

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A Study on the High Frequency Properties of Mn-Zn ferrite with Re2O3(R=Dy, Gd, Ho) Addition (Re2O3(R=Dy, Gd, Ho)첨가에 따른 Mn-Zn ferrite의 고주파 특성에 관한 연구)

  • 최우성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.6
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    • pp.538-548
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    • 2003
  • We studied effects by Re$_2$O$_3$(R=Dy, Gd, Ho) addition on the properties of Mn-Zn ferrite. The doping concentration range from 0.05 wt% to 0.25 wt%. All samples were prepared by standard fabrication of ceramics. With increasing the rare earth oxides, specific density and initial permeability increased on the whole. But, the tendencies such as upper result had the measured value on limitation and characteristics saturated or decreased properties after that. In case of excessive addition of additive beyond some level, initial permeability properties of ferrite have gone down in spite of anomalous grain. With increasing the content of additive, both the real and imaginary component of complex permeability and the magnetic loss (tan$\delta$) increased. Because the increased rate of real component had higher than imaginary component, magnetic loss increased none the less for increasing the real component related with magnetic permeability. But, the magnetic loss of ferrite doped with the rare earth oxides was lower than that of Mn-Zn ferrite at any rate. The small amount of present rare earth oxides in Mn-Zn ferrite composition led to enhancement of resistivity in bulk, and more so in the grain boundary. It was seem to be due to the formation of mutual reaction such as between iron ions and rare earth element ions.

Effect of $Al_2O_3$ and $Fe_2O_3$ Tribological Properties of Reaction Bonded SiC (반응 소결 SiC 소결체의 마찰마모특성에 미치는 첨가제 $Al_2O_3$$Fe_2O_3$ 의 영향)

  • 백용혁;박홍균
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1069-1075
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    • 1994
  • When ceramics are used as the parts of an engine and a machine, the tribological properties are very important. For the preparation of the resistance material for wear applications by the method of Reaction-Bonded Sintering, metal silicon and carbon black are mixed up into SiC powder, and Al2O3 and Fe2O3 are put as an additive. As the general properties, the bending strength and water absortion are measured in the normal temperature and the phase changies are investigated with XRD. The property of the resistance for wear applications is measured with the amount of friction and wear, friction coefficient and maximum asperties. And, the surface of wear is observed with SEM. With the results of this study, the optimal mol ratio of Si : C and the suitable quantity of the mixture of SiC are 7 : 3 and 40 wt%, respectively. In the case of the addition of Al2O3 (2 wt%), the resistance for friction and wear applications is prominent. The bending strength showed the highest peak when Al2O3 (4 wt%) and Fe2O3 (4 wt%) were added. The properties of friction and wear were related with the propagation velocity of crack rather than the bending strength.

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Mechanical Properties of the Pressureless Sintered Al2O3-SiC Composites(2) : Dispersion Effects of SiC Whisker (상압소결한 Al2O3-SiC계 소결체의 기계적 성질(2) : SiC Whisker의 분산효과)

  • 김경수;이홍림
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.704-712
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    • 1988
  • In order to investigate the effect of the second phase on Al2O3 matrix, SiC whisker was dispersed in Al2O3 matrix as a second phase over the content range of 5vol% to 20vol%. To this mixture, Y2O3 or TiO2 powder was added as a sintering additive before isostatically pressing and pressureless sintering at 1800-190$0^{\circ}C$ for 90min in N2 atmosphere. With increasing SiC whisker content, relative densities of composites were decreased and the grain growth of Al2O3 was restricted. When Y2O3 was added as a sintering aid the sintering temperature was 180$0^{\circ}C$, the maximum values of flexural strength, hardness and fracture toughness were 537MPa, 12.1GPa, 3.7MPa.m1/2, respectively. However, when the sintering temperature was elevated to 190$0^{\circ}C$, maximum values of flexural strength, hardness and fracture toughness were 453MPa, 17.5GPa, 4.9MPa.m1/2, respectively. Improved mechanical properties are assumed to be attributed to the crack deflection by the second phase SiC whisker and whisker pullout mechanism.

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A study on the Radiation Properties of Far-infrared and PTC Effect in the $BaTiO_3$ system by $MnO_2$ Amounts of Additives ($MnO_2$ 첨가량에 따른 $BaTiO_3$계의 PTC효과와 원적외선 방사특성에 관한 연구)

  • Song, Min-Joon;Park, Choon-Bae;Kang, Dou-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.05a
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    • pp.3-5
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    • 1993
  • It is very important that a spectrum of reflectance is in accord wi th a spectrum of absorbance for a effective heating. Therefore. the objective of this study was to achieve a technical composite for material plan which PTC thermistor increase a radiation property of far-infrared and keep a characteristic of R-T The Ceramic speciman studies had the composition $BaTiO_3$ with additive of 1.67 $Al_2O_3$, 3.75 $SiO_2$, 1.25 $TiO_2$, 0.15 $Sb_2O_3$ and 0.00-0.182 $MnO_2$. $MnO_2$ amounts of additives was both increase on the anomalous resistivity-temperature characteristics and high efficiency on the radiation properties bodies of far-infrared. This result shows that specimens produced high emissivity(average 0.8) of far-infrared at 4.5-15$[{\mu}m]$ by measuring a characteristic of IR and R-T.

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Performance Evaluation of Cold Recycled Asphalt Mixtures with Asphalt Emulsion and Inorganic Additives (무시멘트 첨가제를 활용한 상온 재활용 아스팔트 혼합물의 성능 분석)

  • Park, Chang Kyu;Kim, kyungsu;Kim, Won Jae;Lee, Hyun Jong
    • International Journal of Highway Engineering
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    • v.19 no.2
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    • pp.137-142
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    • 2017
  • PURPOSES :The objective of this study is to evaluate the performance of asphalt mixtures containing inorganic additive and a high content of reclaimed asphalt pavement (RAP). METHODS : The laboratory tests verified the superior laboratory performance of inorganic additive compared to cement, in cold recycled asphalt mixtures. To investigate the moisture susceptibility of the specimens, tensile strength ratio (TSR) tests were performed. In addition, dynamic modulus test was conducted to evaluate the performance of cold recycled asphalt mixture. RESULTS :It was determined that NaOH solution mixed with $Na_2SiO_3$ in the ratio 75:10 provides optimum performance. Compared to Type B and C counterparts, Type A mixtures consisting of an inorganic additive performed better in the Indirect tensile strength test, tensile strength ratio test, and dynamic modulus test. CONCLUSIONS : The use of inorganic additive enhances the indirect strength and dynamic modulus performance of the asphalt mixture. However, additional experiments are to be conducted to improve the reliability of the result with respect to the effect of inorganic additive.