• Title/Summary/Keyword: $Y_2O_3$ additive

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Effect of Antimony Sesquioxide on the Dielectric Property of Rutile $(TiO_2)$ ($TiO_2$ 의 유전성에 미치는 $Sb_2O_3$ 영향)

  • 윤기현;김창수;강영환
    • Journal of the Korean Ceramic Society
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    • v.17 no.2
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    • pp.75-79
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    • 1980
  • The effect of the additive on the dielectric property of $TiO_2$ containing 0-2.5wt %. $Sb_2O_3$ was investigated as a function of frequency from $5{\times}10^4$ to $6.3{\times}10^7$ cps and temperature from 25 to 375$^{\circ}C$. The dielectric constant increased with increasing $Sb_2O_3$ concentration from 0.25 to 0.5wt.% It is due to space charge polarization caused by increasing anion vacanices. The dielectric constant decreased for further increase in $Sb_2O_3$ concentration. It can be explained by increasing grain size effect rather than space charge polarization.

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Global Warming Gas Emission during Plasma Cleaning Process of Silicon Nitride Using C-C$_4$F$_8$O Feed Gas with Additive $N_2$

  • Kim, K.J.;Oh, C.H.;Lee, N.-E.;Kim, J.H.;Bae, J.W.;Yeom, G.Y.;Yoon, S.S.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.5
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    • pp.403-408
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    • 2001
  • In this work, the cyclic perfluorinated ether (c-C$_4$F$_{8}$O) with very high destructive removal efficiency (DRE) than other alternative gases, such as $C_3$F$_{8}$, c-C$_4$F$_{8}$ and NF$_3$ was used as an alternative process chemical. The plasma cleaning of silicon nitride using gas mixtures of c-C$_4$F$_{8}$O/O$_2$ and c-C$_4$F$_{8}$O/O$_2$+ $N_2$ was investigated in order to evaluate the effects of adding $N_2$ to c-C$_4$F$_{8}$O/O$_2$ on the global warming effects. Under optimum condition, the emitted net perfluorocompounds (PFCs) during cleaning of silicon nitride were quantified and then the effects of additive $N_2$ by obtaining the destructive removal efficiency (DRE) and the million metric tons of carbon equivalent (MMT-CE) were calculated. DRE and MMTCE were obtained by evaluating the volumetric emission using. Fourier transform-infrared spectroscopy (FT-IR). During the cleaning using c-C$_4$F$_{8}$O/O$_2$+$N_2$, DRE values as high as (equation omitted) 98% were obtained and MMTCE values were reduced by as high as 70% compared to the case of $C_2$F$_{6}$O$_2$. Recombination characteristics were indirectly investigated by combining the measurements of species in the chamber using optical emission spectroscopy (OES), before and after the cleaning, in order to understand any correlation between plasma and emission characteristics as well as cleaning rate of silicon nitride.silicon nitride.

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Dependence of the physical properties for magnetic core materials on the concentrations of $Bi_2O_3$ and CaO ($Bi_2O_3$와 CaO 첨가에 따른 PLC용 자심 재료의 물성)

  • An, Y.W.;Lee, H.Y.;Kim, J.R.;Kim, H.S.;Oh, Y.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.64-67
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    • 2002
  • The Physical and magnetic properties such as microstructure, permeability and power loss of Ni-Zn ferrite with composition of $Ni_{0.8}Zn_{0.2}Fe_2O_4$, were investigated as the function of $Bi_2O_3$ and CaO contents. The power loss increased in proportion to the amount of $Bi_2O_3$ up to 0.3 wt% but it decreased over than 0.3 wt% addition. The highest permeability of 134 was obtained to the specimen added 1.0 wt% $Bi_2O_3$ since $Bi_2O_3$ contents were strongly dominant to grain growth and size than that of CaO. $Bi_2O_3$ liquid phase created during sintering process promoted sintering and grain growth so that grain size and permeability increased compared to that of the specimens which were sintered with free-additive and CaO. Also, lots of pores existed in the specimen which was added $Bi_2O_3$ wt% with the biggest grain size.

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Anisotropic etching of polysilicon in a $Cl_2/CH_3Br/O_2$ Plasma

  • Yi, Whi-Kun
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.1
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    • pp.24-29
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    • 1999
  • The characteristic behaviors of CH3Br were examined first for the dry etching of polysilicon in a Cl2/CH3Br/O2 plasma. CH3Br is revealed one of the excellent additive gases to control anisotropy of etching profile and to give no undercutting for various typed of polysilicons. CH3Br acts as a passivation precursor on the side wall in etch cavity by forming polymer-like films such as CHxBry(x+y=1,2). The decrease of etch selectivity due to the reaction if the C-containing species from CH3Br with the surface O atoms of SiO2 was overcome by the addition of O2 into plasma, resulting that the selectivity increased by 2~3 times. According to the results of optical emission signals, CH3Br should be dissociated into several fragments to give more hydrogen atoms than bromine atoms in our helical resonator system.

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Effect of Transition Metal Oxides Addition on Yttria - stabilized Zirconia for improving Physical and Mechanical Properties

  • Park, Jaesung;Lee, Yeongshin
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.12 no.3
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    • pp.25-31
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    • 2016
  • Mechanical properties of Y2O3-containing tetragonal ZrO2 polycrystals(Y-TZP) were investigated. Several additives were used to modify the hardness and fracture toughness of Y-TZP. The effects of these individual additives were discussed and their interactions were also analysed. Each additive, such as CoO, Fe2O3, MnO2 was found to deteriorate the mechanical properties of Y-TZP when it was used singly. But the fracture toughness of Y-TZP was significantly improved when these additives and Al2O3 were added in combination at a certain ratio. The addition of CoO, Fe2O3 and MnO2 into Y-TZP resulted in the more complex behavior of fracture toughness and hardness. The specimen with 1.5 wt%-Fe2O3, 3.0 wt% -Al2O3 and 1.5 wt%-CoO showed the monoclinic to tetragonal phase ratio of 18% and the highest toughness of $10.8MPa{\cdot}m1/2$ with Vickers hardness of 1201 kgf/mm2. However, the toughness decreased as the ratio increased and macrocracks developed beyond the ratio of 25%. Sample No. 16 is improved high Physical and Mechanical Properties.

Effects of Oxide Additions on Mechanical Properties and Microstructures of AlN Ceramics Prepared from Al-isopropoxide (Al-isopropoxide로부터 제조한 AlN 세라믹스의 기계적 성질과 미세구조에 미치는 산화물 첨가제의 영향)

  • 이홍림;황해진
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.799-807
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    • 1990
  • In this study, effects of oxide additives on mechanical properties and microstructure of A1N and A1N polytype ceramics were investigated. Fine A1N powder was synthesized by nitriding alumiuim hydroxide prepared from Al-isopropoxide, at 1350$^{\circ}C$ for 10h in N2 atmosphere. By adding 3w/o Y2O3, 0.56w/o CaO, and 10w/o SiO2 to AlN powder, AlN and AlN polytype ceramics were prepared by hot-pressing under the pressure of 30 MPa at 1800$^{\circ}C$ for 1h. AlN ceramics with no additives formed considerable amount of AlON phase, while AlN ceramics doped with Y2O3 or CaO decreased AlON phase and formed Y-Al or Ca-Al oxide compound. AlN+10w/o SiO2(+3w/o Y2O3) composition produced AlON and AlN polytype compound having 21R as a major phase. Room temperature flexural strength of AlN ceramics with no additive was 246MPa, and room temperature flexural strength and critical temperature difference by thermal shock(ΔTc) of AlN ceramics dooped with Y2O3 or CaO were 532MPa/340$^{\circ}C$ and 423MPa/300$^{\circ}C$, respectively. Y2O3 and CaO used as sintering agent played roles of densification and oxygen removal of AlN ceramics, and affected grain growth/grain morphologies of AlN ceramics.

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Evaporation Characteristics of a Water Droplet Containing Sodium Acetate Trihydrate as an Additive (첨가제로 아세트산 나트륨-3수화물을 함유한 물 액적의 증발 특성)

  • Park, Jae-Man;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.61-68
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    • 2004
  • The evaporation phenomena of waterr droplet which has sodium acetate trihydrate($CH_3COONa{\cdot}3H_2O$) as a fire suppression additive were studied. Solutions of sodium salt up to 50% and heated stainless-steel surface were used in the experiment. The evaporation process was recorded using a charge-coupled-device camera at 120 frames per second. The average evaporation rate of the sodium acetate trihydrate soluation was lower than that of pure water at a given surface temperature and decreased with the concentration increase due to the precipitation of salt in the liquid film and change of surface tension. The variation of liquied film diameter was measured by time and it was increased by the hot surface temperature increase.

Electrophoretic Superconducting Film Applications

  • Fenghua, Li;Jue, Wang;Soh, Dea-Wha;Zhanguo, Fan
    • Journal of the Speleological Society of Korea
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    • no.76
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    • pp.15-17
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    • 2006
  • [ $YBa_2Cu_3O_{7-{\delta}}$ ] superconductor films have been prepared on silver substrates by electrophoretic deposition. As silver does not react with $YBa_2Cu_3O_{7-{\delta}}$ compound and has little influence on its superconductivity, it is usually doped in $YBa_2Cu_3O_7$ to improve the strength of the material and eliminate micro cracks. It has been proved that Ag additive can lower the melting temperature of $YBa_2Cu_3O_{7-{\delta}}$ and act as linking bridge among $YBa_2Cu_3O_{7-{\delta}}$ particles, thus in this paper Ag doped $YBa_2Cu_3O_{7-{\delta}}$ thick films are prepared by electrophoretic co deposition. As there are only some referenced experience formula and models for co electrophoretic deposition and does not exist unified explanation, the behavior of Ag particles during co electrophoretic deposition is also studied.

첨가제가 이산화염소 표백에 미치는 영향

  • 윤병호;왕립군;김세종;김용식;최경화
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.84-88
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    • 1999
  • In chlorine dioxide delignigication or bleaching, chlorate is mainly formed by the reaction between chlorite and hypochlorous acid, thus scavengers of chlorine or hypochlorous acid can be used to reduce the formation of chlorate which is unfavorable to environment. In this study, additives such as sulfamic acid, DMSO, hydrogen peroxide, or sodium chlorite was added to chlorine solution or pure $ClO_2$ solution to check their reactivity with $Cl_2$ and $ClO_2$. These additives were also added directly into general $ClO_2$ solution which contained certain amount of chlorine, then the additive-treated $ClO_2$ solution were used in bleaching stages. The aim of this procedure was to remove the original amount of chlorine that was thought to be possibly the main reason for the formation of chlorate and AOX. The additives were found to be able to eliminate chlorine very fast and selectively, but $H_2$ $O_2$ should be used under pH4, otherwise it also reacts with $ClO_2$. After the additives reacted With $Cl_2$, DMSO turned into an inactive product $(CH_3)_2SO_2$, While Sulfamic acid turned into $HClSO_3H$ that still remained active in oxidation, and $NaClO_2$ produced $ClO_2$. The addition of $HNaClO_2$ showed significant improvement in delignification but the deeper delignification led to higher formation of chlorate. When the additive-treated chlorine dioxide solutions were used in bleaching, both sulfamic acid, DMSO, and hydrogen peroxide showed no significant changes of DE brightness and Kappa number. The formation of chlorate was reduced by addition of sulfamic acid, DMSO and hydrogen peroxide.

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EFFECT OF $Na_{2}O$ ADDITION ON MAGNETIC PROPERTIES OF $SrZn_{2}-W$ TYPE HEXAGONAL FERRITE

  • Yamamoto, Hiroshi;Fujii, Hiroshi;Mitsuoka, Takayuki
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.735-739
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    • 1995
  • An experiment was carried out to investigate the effect of $Na_{2}O$ additive on the magnetic and physical properties of $SrZn_{2}-W$ type hexagonal ferrite. The specimens were prepared by the conventional manufacturing methods without atmosphere control. It was found that the magnetic properties of SrO.2ZnO.$8Fe_{2}O_{3}$ are considerably improved on adding 1.5wt% $Na_{2}O$. Theoptimum condition of making magnet with suitable properties are as follows : chemical analysis composition : $Sr^{2+}_{0.852}Zn^{2+}_{1.721}Na^{+}_{0.301}Fe^{2+}_{0.723}Fe^{3+}_{15.703}O_{27}$ ; semisintering condition : $1300^{\circ}C\;{\times}\;1h$ in air ; sintering condition : $1250^{\circ}C\;{\times}\;0.5h\;T_{c}=371^{\circ}C,\;H_{A}=1091.5kA/m,\;K_{A}=2.13{\times}10^{5}J/m^{3}\;and\;n_{B}=31.8\mu\textrm{B}$.

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