• Title/Summary/Keyword: $Y_2O_2S$:Eu

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A Study on the Effect of Surfactant in Synthesizing Titanium Dioxide/Acrylate Core-Shell Polymer ($TiO_2$/Acrylate 코어-셀 합성에서 계면활성제의 영향에 관한 연구)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.1
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    • pp.56-60
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    • 2010
  • Titanium dioxide particles are used as photocatalysts, sensors, adsorbents and catalyst. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 0.5~2.0 wt% EU-S133D, Titanium dioxide / Acrylate core-shell polymerization was carried out on the surface of Titanium dioxide particle without forming the new Titanium dioxide particle during acrylate shell polymerized in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

Physico-Chemical Environment and Productivity of the Phytoplankton Community in the Jido Pond Ecosystem (지도지생태계의 물리화학적환경과 식물성 플랭크톤군집의 생산성)

  • Song Seung-Dal;M. Anwarul Huque
    • Journal of environmental and Sanitary engineering
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    • v.5 no.2
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    • pp.117-122
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    • 1990
  • The Jido Pond system was investigated from April, 1979 through March, 1980, in respect of seasonal changes in physico-chemical factors: i.e., temperature, pH, DO, BOD, COD, $Cl^-, \; Mg^{++}$, alkalinity, detergent, $SiO_2, PO_4\;^{3-}, NH_4\;^+, NO_2\;^-, NO_3\;^-$, total N, OM and OC; phytoplankton community growth; and the ecosystem metabolism. The phytoplankton community was represented by 23 species belonging to Chlorophyta, Bacillariophyta and Cyanophyta; each sharing 11, 9 3 respectively. The Chlorophyceans dominated the phytoplankton community contributing 75% of the total ?미 counts. The ranges of biotic diversity indices were, d, 0.85~2.80; H, 1.10~2.40; c, 0.13~0/40; and 3, 0.56~0.90. The chlorophyll standing crop varied in between 0.043 and 0.385g/$\textrm{cm}^2$ surface area. The ranges of photosynthetic and respiratory rates were 0.36~4.50; and 0.10~1.40 $O_2$ mg/1/hr, respectively. The monthly areal net primary production varied from 23.9 to 305.1C g/$\textrm{m}^2$/month. The Eu of the net production seasonally varied in between 0.31 and 7.80%, and the annual mean was 2.44%. The annual turnover times of phosphorus and nitrogen were 20 and 3 days, respectively.

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Geochemical Characteristics of the Cretaceous Jindong Granites in the Southwestern Part of the Gyeongsang Basin, Korea: Focussed on Adakitic Signatures (경상분지 서남부에 분포하는 백악기 진동화강암의 지화학적 특성:아다카이틱(adakitic)한 특성을 중심으로)

  • Wee, Soo-Meen;Choi, Seon-Gyu;Ryu, In-Chang;Shin, Hong-Ja
    • Economic and Environmental Geology
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    • v.39 no.5 s.180
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    • pp.555-566
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    • 2006
  • Major, trace and rare earth elements data of the Cretaceous Jindong granitic rocks were investigated in order to constrain the magma source characteristics and to establish the paleotectonic environment of the southwestern part of the Gyeongsang Basin. Geochemical signatures of the granitic rocks from the study area indicate that all of the rocks have characteristics of calc-alkaline series in the subalkaline field, and progressively shift from metaluminous to peraluminous with differentiation. In the variation diagrams, the overall geochemical features of the granites show systematic variations in major and trace elements. Chondrite normalized REE patterns show generally enriched LREE((La/Yb)c=4.2-12.8) and slight negative to flat Eu anomalies. Rb-Sr isotope data of the Jindong granites show that the whole rock age and Sr initial ratio are $114.6{\pm}9.1Ma$ and 0.70457, respectively. The Sr initial ratio of the Jindong granites is very similar to those of the Creataceous granites from Masan, Kimhae and Busan area($^{87}Sr/^{86}Sr=0.7049-0.707$). These results suggest that the magma have the mantle signature and intruded into the area during the early Cretaceous age. The Jindong granites have higher $Al_{2}O_{3},\;Na_{2}O$, Sr and lower $K_{2}O$, Y concentrations compared with typical calc-alkaline granitic rocks. These adakitic signatures are similar to those of adakitic pluton on Kyushu Island, southwest Japan arc. On the ANK vs. ACNK and tectonic discrimination diagrams, parental magma type of the granites corresponds to I-type, VAG granite. Interpretations of the geochemical characteristics of the granitic rocks favor their emplacement at continental margin during the subduction of Izanagi plate.

The Effects of the Early Intervention of V{\ddot{o}}jta Therapy for the Infant with Central Coordination Disturbance (영유아 뇌성 운동발달 장애아에 대한 보이타치료법 조기적용의 효과)

  • Yang, Eu-Jin;Kim, Chung-Sun;Ahn, So-Youn;Kim, Byung-Jo
    • The Journal of Korean Physical Therapy
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    • v.13 no.1
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    • pp.49-59
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    • 2001
  • The purpose of this study was to examine the effect of treatment when the V{\ddot{o}}jta therapy applied to the infant with central coordination disturbance in early stage. The subject were 10 cases : each one with the V{\ddot{o}}jta therapy applied to the group of the infants before 6 months old and the group of the infants over 6 months old. When the V{\ddot{o}}jta therapy was applied I analized the papper which was written about the infants who were diagnosed as moderate CCD and divided two groups which were the infants before 6 months old and the infants over 6 months old. These collected data were analyzed by using t-test. The results of study were as follow; 1. When I compared the locomotion stage after the V{\ddot{o}}jta therapy. t-test showed significant differences. The group of infants before 6 months old had the result 7 to over stage 7 and the group of infants over 6months old had the result 2(p<.05). 2. When I compared the result of the postural reaction after the V{\ddot{o}}jta therapy, 1-test showed significant differences. The group of infants before 6 months old had 6 cases was normalizes and the group of infants over 6 months old had 1 case was normalized(p<.05). 3. When 1 compared the duration of the V{\ddot{o}}jta therapy between the group of infants before 6 months old and the group of infants over 6 months old. t-test showed significant differences. The group of the infants before 6 months old had 5 cases for 1-6 months and 4 cases for 7-15 months, 3 cases for 16-24 months and the group of infants over 6 months old had 6 cases for 7-15 months and cases for 16-24 months, 1 case for 25-30 months(p<.01).

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Behavior of Rare Earth Elements in Synthetic Fluorapatites Revealed by Rietveld Structure Refinement Data (리트벨트법에 의한 합성인회석 내의 희토류 원소의 거동에 관한 연구)

  • 문용희;최진범;이병임
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.4
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    • pp.221-230
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    • 2000
  • 이성분 희토류 원소로 치환된 4종류의 합성불화인회석(synthetic fluorapatite) (Ap49: La+Gd, Ap50:Ce+Dy, Ap51: Pr+Er, Ap54: Eu+Lu; $Ca{10-x-2y}$ $Na_{y}$ $REE_{x+y}$($P_{1-x}$ //$Si_{x}$ $_{4}$)$_{6}$ $F_{2}$, x=0.13~0.12, y=0.26~0.42)을 대상으로 X-선 회절분석을 통해 얻어진 자료를 이용하여 리트벨트 구조분석을 실시하고 치환된 희토류원소의 거동을 단결정법으로 구해진 결과와 비교.분석하였다. 리트벨트 구조분석결과 합성불화인회석은 공간군 $P6_3$/m, 단위포는 평균하여 a=9.3906(1) $\AA$, c=6.8924(1) $\AA$, V=527.36 $\AA^3$의 값을 갖는다. 구조의 정밀도를 나타내는 R 지수를 보면 $R_{B}$ / 값은 17.29~18.80이고 S(GofF)값은 1.44~1.68로 계산되었다. 불화인회석은 9개의 산소를 배위하는 Ca1자리와 6개의 산소와 하나의 불소가 배위하는 Ca2자리가 있으며 Ca1-O의 평균거리는 2.563 $\AA$이고 Ca2-O의 평균거리는 $2.460 \AA$으로 Ca1자리가 Ca2자리보다 다소 크다. 구조자리 치환식에서는 $Ca^{2+}$ / 자리를 치환하는 $REE^{3+ }$ 로 인하여 전하균형을 맞춰주기 위해서 인과규소가 함께 참여하였다. ($REE^{3}$+Si$^{ 4+}$ $2Ca^{2+}$ : Ca1) 계산된 희토류원소의 자리점유율(REE-Ca2/REE-Cal)은 원자번호가 증가함에 따라 일정하게 감소하는 경향을 보여주며 이는 희토류원소의 거동이 LREE는 크기가 상대적으로 작은 Ca2 자리에 우선 치환되고 HREE는 크기가 큰 Ca1자리에 우선 치환되는 경향을 지시한다.

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Evaluation of image acquisition using synchrotron radiation in CMOS sensor. (Synchrotron Radiation을 이용한 CMOS sensor image 획득평가)

  • Kim, D.H.;Park, J.K.;Choi, J.Y.;Chang, G.W.;Youn, G.J.;Moon, C.W.;Nam, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.396-399
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    • 2003
  • In this paper, the purpose is to develop imaging technique of synchrotron radiation using CMOS image sensor. The detector using hybrid method to be research in this lab was used, in order to increase image signal. We made experiments with 1B2 Whitebeam/microprobe beamline in PAL (Pohang Accelerator Laboratory). Phosphor materials such as ZnS:(Ag,Li), ZnS:(Cu,Al), $Y_2O_2S:Eu$ were produced by spin coating on glass. Synchrotron radiation images were acquired and evaluated from monochromatic light from monochromoator in PAL 1B2line. From obtained object and phantom, MTF was 0.15 in ZnS:(Ag,Li) phosphor, and 0.178 in ZnS:( Cu,Al) at 151p/mm. MTFs were unsystematic because thickness of phosphor and uniformity of surface were not optimized. It's expected to improve MTF and the qualify of images as uniformity's optimized.

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The Study on Composition ratio of Iodine in Hybrid X-ray Sensor (혼합형 X선 센서에서 a-Se 의 Iodine 첨가비 연구)

  • Gong, Hyung-Gi;Park, Ji-Koon;Choi, Jang-Yong;Moon, Chi-Wung;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.366-369
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    • 2002
  • At present, the study of direct digital X-ray detector and indirect digital X-ray detector proceed actively. But it needs high thickness and high voltage in selenium for high ionization rate. Therefore, we carried out the study of electric characteristics of a-Se with additive ratio of Iodine in drafting study for developing Hybrid X -ray Sensor for complementing direct digital X -ray detector and indirect digital X-ray detector in this paper. On this, there are formed Amorphous selenium multi-layers by sticking phosphor layer$(Gd_{2}O_{2}S(Eu^{2+}))$ using optical adhesives of EFIRON Co. Amorphous selenium multi-layers having dielectric layer(parylene) has characteristics of low dark-current, high X-ray sensitivity. So we can acquired a enhanced signal to noise ratio. We make Amorphous selenium multi-layers with $30{\mu}m$ thickness on glass.

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A study on the manufacturing of durable and long afterglow phosphorescent paints added with rare earths for night visibility of pavement (야간 시인성 확보를 위한 희토류 첨가 고내구성 장잔광 축광도료 제조에 관한 연구)

  • Eunseok Woo;Yunseok Noh;Jinho Lee;Yong-Wook Choi;JongGee Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.2
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    • pp.152-159
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    • 2023
  • The night visibility of pavement is being considered as a global issue in the field of traffic safety. Although the spreading glass beads on the lane paints has been mainly used to secure night-visibility by utilizing the effect of retroreflection, obvious shortcoming of this method is that retroflection does not occur in the range where the headlights do not reach the glass beads. The use of functional paints including phosphorescent constituents could be a solution for overcoming fore-mentioned problem. SrAl2O4 based chemicals have not only good phosphorescent property, but also are chemically stable compared to existing ZnS based materials. However, this chemicals also need the improvement due to slightly reduced luminous effect in time. Herein, we developed novel paints showing enhanced phosphorescent properties by putting rare earth elements such as Eu, Dy and Y into SrAl2O4. These prepared phosphorescent pigments have displayed improved properties in terms of durability and long afterglow. For instance, the property of afterglow has been persisted after 5 hours with luminace of 20.6 mcd/m2.

p" Color Field Emission Displays Using Carbon Nanotube Emitters

  • Lee, N.S.;Park, W.B.;Kim, J.M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.211-211
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    • 2000
  • Carbon nanotubes (CNTs) have been spotlighted as one of promising field emission displays(FEDs). For the first time, to authors knowledge, we have developed the 9" color CNT-FEDs with the resolution of 240x576 lines. The 9" CNT-FEDs with diode-type and triode-type structures are presented. The well-dispersed CNT paste was squeezed onto the metal-patterned cathode glass. For the anode plate, the Y2O2S:Eu, ZnS:Ag,Cl low-voltage phosphors were printed for red, green, and blue colors, respectively. The vacuum-packaged panel maintained the vacuum level of 1x10-7 Torr. The uniform moving images vacuum-packaged panel maintained the vacuum level of 1x10-7 Torr. The uniform moving images were demonstrated at 2 V/um. High brightness of 800, 200, and 150cd/m2 was observed on the green, red, and blue phosphors at V/um, respectively. Field emission characteristics of a triode-type CNT-FED were simulated using a finite element method. the resultant field strength on the cathode was modulated by gate bias and emitted electrons were focused on the anode. A relatively uniform emission image was experimentally achieved at the 800V anode. A relatively uniform emission image was experimentally achieved at the 800V anode and the 50-180 V gate biases. Energy distribution of electrons emitted from CNTs was measured using an energy analyzer. The maximum peak of energy curve corresponded to the Fermi energy level of CNTs. The whole fabrication processed of CNT-FEDs were fully scalable and reproducible. Our CNT-FEDs has demonstrated the high potential of large-area and full-color applications with very low cost fabrication and low power consumption.

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A Study on the Effective Utilization of Intensifying Screens in the Region of Diagnostic Radiology (진단방사선 영역에서 증감지의 유효이용에 관한 연구)

  • Kim, Young-Keun;Lee, Kyung-Sup
    • Journal of radiological science and technology
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    • v.22 no.1
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    • pp.43-47
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    • 1999
  • In order to obtain effective utilization of intensifying screens[$CaWO_4(W),\;Gd_2O_2S:Tb(Gd)$, BaFCl : Eu(Ba)] over the diagnostic radiology range, we calculated absorption coefficient (${\mu}$), absorption efficiency (${\eta}_{\alpha}$) and absorbed energy ratio(R) and analyzed effects of these properties on X-ray image, finally concluded as below. Regardless of presence of contrast media, absorption coefficient of Gd the highest and decreased with increase of thickness and kVp. Absorption efficiency related with absorbance of fluorescent materials showed the highest value for the Gd, and discontinuous points exhibited at around $80{\sim}90\;kVp$ and $90{\sim}100kVp$ for the Ba and the Gd, respectively. Furthermore, the absorbed energy ratio(R) correspond to contrast of reflection showed the largest value for the W in the absence of contrast media, and for the Gd in the case of the existence of it, and the ratio was decreased with increasing of incident energy. Owing to these properties, we assumed that it was more preferable to use rare earth type intensifying screen for the radiography using in the C.M.(I, Ba), while in the general radiography, $CaWO_4$ intensifying screen was applicable.

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