• Journal of Microbiology and Biotechnology
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• v.31 no.3
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• pp.419-428
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• 2021

To efficiently recycle GH78 thermostable rhamnosidase (TpeRha) and easily separate it from the reaction mixture and furtherly improve the enzyme properties, the magnetic particle Fe3O4-SiO2-NH2-Cellu-ZIF8 (FSNcZ8) was prepared by modifying Fe3O4-NH2 with tetraethyl silicate (TEOS), microcrystalline cellulose and zinc nitrate hexahydrate. FSNcZ8 displayed better magnetic stability and higher-temperature stability than unmodified Fe3O4-NH2 (FN), and it was used to adsorb and immobilize TpeRha from Thermotoga petrophilea 13995. As for properties, FSNcZ8-TpeRha showed optimal reaction temperature and pH of 90℃ and 5.0, while its highest activity approached 714 U/g. In addition, FSNcZ8-TpeRha had better higher-temperature stability than FN. After incubation at 80℃ for 3 h, the residual enzyme activities of FSNcZ8-TpeRha, FN-TpeRha and free enzyme were 93.5%, 63.32%, and 62.77%, respectively. The organic solvent tolerance and the monosaccharides tolerance of FSNcZ8-TpeRha, compared with free TpeRha, were greatly improved. Using naringin (1 mmol/l) as the substrate, the optimal conversion conditions were as follows: FSNcZ8-TpeRha concentration was 6 U/ml; induction temperature was 80℃; the pH was 5.5; induction time was 30 min, and the yield of products was the same as free enzyme. After repeating the reaction 10 times, the conversion of naringin remained above 80%, showing great improvement of the catalytic efficiency and repeated utilization of the immobilized α-L-rhamnosidase.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.4
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• pp.472-482
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• 2007

This study deals with the design and implementation results for a high-capacity vol-oxidizer that can convert Uranium Dioxide pellets to $U_3O_8$ powder for up to several tens of kg HM/batch. We developed two versions of the $1^{st}$ vol-oxidizer and the $2^{nd}$ vol-oxidizer. Through an experiment with the $1^{st}$ vol-oxidizer, we deduced some problems concerning the design considerations such as the recovery rate of $U_3O_8$, the oxidation time of the Uranium Dioxide pellets, the exothermic reaction, and the powder dispersion. From the analyses of the drawbacks of the $1^{st}$ vol-oxidizer, we devised some novel items such as a folding type mesh, vibrators, and mixing blades. Also, we used the Stokes and Density ratio Eq. to determine the most reasonable flux for preventing a powder dispersion. Compared with the results of the $1^{st}$ vol-oxidizer, we showed that both the permeability of the $U_3O_8$ powders and the oxidation rate of the Uranium Dioxide pellets of the $2^{nd}$ vol-oxidizer were remarkably increased, and the temperature of the reactor was controlled well in spite of an exothermic reaction. Also, the powder was not entirely dispersed through the outlet of the voloxidizer. The experimental results of this work can help in the design of a novel and efficient vol-oxidizer with a higher capacity.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.2
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• pp.105-112
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• 2005

The electrolytic reduction of uranium oxide in a LiCl-Li$_{2}$O molten salt system has been studied in a 10 g U$_{3}$O$_{8}$ /batch-scale experimental apparatus with an integrated cathode assembly at 650$^{\circ}C$. The integrated cathode assembly consists of an electric conductor, the uranium oxide to be reduced and the membrane for loading the uranium oxide. From the cyclic voltammograms for the LiCl-3 wt$\%$ Li$_{2}$O system and the U$_{3}$O$_{8}$-LiCl-3 wt$\%$ Li$_{2}$O system according to the materials of the membrane in the cathode assembly, the mechanisms of the predominant reduction reactions in the electrolytic reactor cell were to be understood; direct and indirect electrolytic reduction of uranium oxide. Direct and indirect electrolytic reductions have been performed with the integrated cathode assembly. Using the 325-mesh stainless steel screen the uranium oxide failed to be reduced to uranium metal by a direct and indirect electrolytic reduction because of a low current efficiency and with the porous magnesia membrane the uranium oxide was reduced successfully to uranium metal by an indirect electrolytic reduction because of a high current efficiency.

• Mineral and Industry
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• v.21 no.1
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• pp.56-66
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• 2008

이 동향자료는 Geoscience Australia에서 2001년 발간한 "Geoscience Australia Mineral Resources Report No.1"과 역시 동 기관에서 2007년 발행한 "Australia's Identified Mineral Resources 2007" 중 일부 내용을 발췌하여 정리 한 것으로서 요약하면 다음과 같다. OECD/NEA와 IAEA(2000)는 세계적으로 분포하는 우라늄 광상유형을 지질학적인 형성환경에 따라 15개 유형으로 분류하였으며 호주에서는 각력복합형, 부정합형, 사암형, 지표형, 변성교대형, 변성형, 화산형, 관입형 및 맥상형이 보고되어 있다. 유형별 자원량은 각력복합형, 부정합형 및 사암형 3개 유형 광상이 약 93%를 차지하며, 각력복합형광상의 자원량이 63%에 달한다. 현재 개발되는 광상은 각력복합형의 올림픽댐 광산, 부정합형인 레인저 광산 및 사암형인 베벌리 광산이다. 호주는 세계 총 우라늄 자원량의 27%를 보유하고 있어 세계 1위를 차지한다. 올림픽댐광상이 항내채광을 하는 우라늄 광산으로서는 세계에서 가장 큰 광상으로서 US$80 이하에서 회수가능한 RAR(적정확정자원량)이 476,000톤이다. 이 자원량은 세계 총 자원량의 18%를 차지하며, 단일 광산으로서는 세계최대규모이다. 2006년 호주의 우라늄 총생산량은 $U_3O_8$ 8,943톤(7,584톤 U)이며 이는 세 광산에서 생산된 양으로서 캐나다에 이어 두 번째로 많은 양(세계 생산량의 19%)이다. 2006년 우라늄 수출량은 $U_3O_8$ 8,660톤(7,344톤 U)이며 수출가는 호주달러 5억2천9백만불에 달한다. 호주는 우라늄 수출국들과 "원자력협력협약"을 맺어 평화적 목적을 위해서만 공급한다는 단서를 달고 있으며 IAEA에 의해 관리/감독되고 있다. 최근 호주 정부는 지구과학연구소에 많은 예산을 투여하여 육상에너지안전대책을 발의하여 자원개발에 요구되는 탐사자료 확보에 주력하고 있다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2007.11a
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• pp.285-285
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• 2007

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1591-1593
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• 1997

The purpose of this study is to research and develop $Li_xV_3O_8$ composite cathode for lithium polymer battery. We investigated electrochemical, interfacial properties and charge/discharge cycling of $Li_xV_3O_8$/SPE/Li cell. The radius of semicircle associated with the interfacial resistance of $Li_xV_3O_8$/SPE/Li cell increased very slowly during discharge process from 100% SOC to 90% SOC. And then the cell resistance was increased at discharge process from 10% SOC to 0% SOC. The discharge capacity based on $Li_xV_3O_8$ was 212mAh/g at 15th cycle. The $Li_xV_3O_8$/SPE/Li cell has a good properties.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.479-482
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• 2002

Riblets with longitudinal grooves along the streamwise direction have been used as an effective flow control technique for drag reduction. A flexible micro-riblet with v-grooves of peak-to-peak spacing of $300{\mu}m$ was made using a MEMS fabrication process of PDMS replica. The flexible micro-riblet was attached on the whole surface of a NACA0012 airfoil with which grooves are aligned with the streamwise direction. The riblet surface reduces drag coefficient about $7.9{\%}\;at\;U_o=3.3m/s$, however, it increases drag about $8{\%}\;at\;U_o=7.0m/s$, compared with the smooth airfoil without riblets. The near wake has been investigated experimentally far the cases of drag reduction ($U_o\;=\;3.3 m/s$) and drag increase ($U_o\;=\;7 m/s$). Five hundred instantaneous velocity fields were measured for each experimental condition using the cross-correlation PIV velocity field measurement technique. The instantaneous velocity fields were ensemble averaged to get spatial distribution of turbulent statistics such as turbulent kinetic energy. The experimental results were compared with those of a smooth airfoil under the same flow condition. The micro-riblet surface influences the near wake flow structure largely, especially in the region near the body surface

• Journal of the Korean Electrochemical Society
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• v.3 no.3
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• pp.141-145
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• 2000

Anodically Polymerized conducting Polypyrrole film electrode was employed to Pick up uranyl ion with the type of Gr/ppy, xylenol orange modified electrode. To have Porous and oriented ppy film, NBR was applied as precoating agent. The rate constant of polymerization was $3.22\times10^{-3}s^{-1}$ which was 1.6 times smaller value than bare graphite surface. The deposited amount of uranyl iou on $1.70Ccm^{-2}$ of ppy was $1.55\times10^{-4}g$. The matrix effect in artificial seawater was $6.8\%$. The polymer film electrode has a diffusion controlled process in conduction, but the modified Gr/ppy, $X.O^{4-}UO^+$ type was influenced on the ion doping and electronic conduction of film itself owing to increasing of impedance. The capacitance of electrical double layer was respectively enhanced to 56 and 130 times in Gr/ppy, $X.O.^{4-}$ and Gr/ppy, $X.O^{4-}UO^+$ than Grippy type electrode.

• Analytical Science and Technology
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• v.16 no.2
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• pp.117-124
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• 2003

Oxygen to metal ratio has been measured by wet and dry chemical analysis to study the properties of sintered $UO_2$ pellets and $U_3O_8$ in the lithium reduction process of spent pressurized water reactor fuels. Uranium dioxide pellets simulated for the spent PWR fuels with burnup values of 20,000~60,000 MWd/MtU were prepared by mixing $UO_2$ powder and oxides of fission product elements, pelleting the powder mixture and sintering it at $1,700^{\circ}C$ under a hydrogen atmosphere. For wet chemical analysis, the simulated spent fuels were dissolved with mixed acid (10 M HCl : 8 M $HNO_3$, 2.5 : 1, v/v) using acid digestion bomb technique. The total amount of uranium and fission products added in the simulated spent fuels were measured using inductively coupled plasma atomic emission spectrometry. Weight change of the simulated fuel during its oxydation was measured by thermogravimetry and then the O/M ratio result was compared to that obtained by wet chemical analysis. Influence of $Mo_{0.4}-Ru_{0.4}-Rh_{0.1}-Pd_{0.1}$, quaternary alloy, on the determination of O/M ratio was investigated.

• Korean Journal of Acupuncture
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• v.21 no.1
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• pp.175-199
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• 2004

Objectives : To study acupuncture and moxibution treatments for stomatopathy( aphthae, oral ulceration, mycolic stomatitis, halitosis, thirst, bitter) the ancient and the present literatures were reviewed. Methods : We've got compared and analyzed 55 kinds of literatures. Results and Conclusions : 1. The acupuncture meridians used frequently for stomatopathy were $Su-yangmy\bar{o}ng-Taejang-ky\bar{o}ng(LI),\;Chok-yangmy\bar{o}ng-Wi-Ky\bar{o}ng(S),\;Immaek-Ky\bar{o}ng(CV)$. 2. The acupoints used frequently for aphthae were $Sungjang(CV_{24}),\;Yomchon(CV_{23}),\;Hapkok(LI_4),\;Nogung(P_8),\;Chok-samni(S_{36}),\;Hyopko(S_6),\;Sugu(GV_{26})$. 3. The acupoints used frequently for oral ulceration were $Hapkok(LI_4),\;Nogung(P_8),\;Chok-samni(S_{36}),\;Kokchi(LI_{11}),\;Sotaek(SI_1),\;Pisu(B_{20}),\;Wisu(B_{21}),\;Samgan(LI_3),\;Yomchon(CV_{23}),\;Chichang(S_4)$. 4. The acupoints used frequently for mycolic stomatitis were $Hapkok(L_4),\;Chichang(S_4),\;Hyopko\;(LI_4),\;Sungjang(CV_{24}),\;Samumgyo(SP_6)$. 5. The acupoints used frequently for halitosis were $Naejong(S_{44}),\;Chok-samni(S_{36}),\;Chung-wan\;(CV_{12}),\;Sang-wan(CV_{13}),\;Hawan(CV_{10}),\;Kongson(SP_4),\;Wisu(B_{21}),\;Nogung(P_8),\;Sugu(GV_{26}),\;Sungjang(CV_{24})$. 6. The acupoints used frequently for thirst were $Sosang(L_{11}),\;Sangyang(LI_1),\;Sotaek(SI_1),\;Kwanch'ung(TE_1),\;Ch'\bar{o}kt'aek(L_5),\;T'ae-gye(K_3),\;Kokt'aek(P_3),\;Sugu(GV_{26}),\;Samgan(LI_3),\;Igan(LI_2),\;T'aech'ung(Liv_3),\;Sojangsu(B_{27})$. 7. The acupoints used frequently for bitter were $Yangn\bar{u}ngch'\bar{o}n(G_{34}),\;Hy\bar{o}njong(G_{39}),\;Kwanch'ung(TE_1),\;Tamsu(B_{19}),\;Chokkyu\bar{u}m(G_{44}),\;Y\bar{o}n-gok(K_2),\;Shinmun(H_7),\;Chok-Samni(S_{36})$.