• Title/Summary/Keyword: $T_D$-space

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Crystal Structure of Probenecid, $C_{13}H_{19}NO_4S$ (Probenecid, $C_{13}H_{19}NO_4S$의 結晶構造)

  • Kim, Eui-Sung;Shin, Hyun-So
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.603-606
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    • 1991
  • The crystal structure of Probenecid has been determined from 2574 independent reflections collected on an automatic ENRAF-NONIUS CAD-4 diffractometer using graphite-monochromated $Mo-K{\alpa}$ radiation. The crystal is triclinic, space group P$\bar{1}$ with unit cell dimensions a = 7.535(2)${\AA}$, b = 18.473 (5)${\AA}$, c = 5.317(9)${\AA}$, ${\alpha} = 92.00(5)^{\circ}$, ${\beta} = 99.02(5)^{\circ}$, ${\gamma} = 94.89(2)^{\circ}$, V = 727.4(2)${\AA}^3$, Z = 2, $D_m$ = 1.310, $D_x$ = $1.302 gcm^{-3}$, ${\mu}$ = $1.88 cm^{-1}$, F(000) = 304, and T = 298 K. Final R = 0.0676 and $R_w$ = O.0630 for 1209 reflections > 5${\sigma}(F_o)$. In the spacial arrangement about N(13), the sum of bond angles about nitrogen is 350.9° and the nitrogen lies only 0.268(6)${\AA}$ out of S(1)-C(14)-C(17) plane. The S(1)-C(4) distance is 1.792(6)${\AA}$ and the C(4)-S(1)-N(13) angle is $106.5(3)^{\circ}$. The overall conformation of the molecule is folded with respect to sulfur.

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A Study on the Damage level of Pavement For The Landscape Urban Community Parks - In case of Dukjin, Choongang, and Dosan Park - (도시 근린 공원내 조경 포장면의 손상 정도에 관한 연구 -덕진(전주), 중앙(청주), 도산(서울) 공원을 중심으로-)

  • 신병철;권상준
    • Journal of the Korean Institute of Landscape Architecture
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    • v.24 no.3
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    • pp.96-108
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    • 1996
  • This study aimed at choosing the urban community parks such as D Kjin, Chungang, Dosan Park as the target place for this study, and at analyzing the damage level of the pavement surfaces focusing on the spaces and the materials. We devided the damage level within $1.5\times$1.5m grid int the grade from one to five points, and made use of the method of giving marks to get hold of the damage level of the pavement surfaces. Especially we took and analyze Duncan test for the spaces suffering severe damage. The result is as follows : 1. The damage of unenenness turned out to be a most excessive damage in the damage level according to the pavement materials in case of D kjin, and Chunggnag Park. Especially the concrete blocks proved to be the exessive damage in comparison with the other pavement materials, and the demolitional damage of the damage types to the most severe damage. The corner damage turned relatively out to be a heavy damage in case of Dosan Park in Seoul. 2. In the event of the damage level of pavement surfaces according to the spaces, the space which was made the more use of and which was the more concentrated, turned out to be the degree of the more excessive damage. 3. We took the Duncan test to verify the deference of the damage type between the spaces and the pavement materials of the target places for survey. The result of verification was that there was no difference of the damage type between the corner and block damage itself in case of the enterance area and the square of D kjin Park in Ch nju, and that the damage level of the pavement materials proved to be the more execssive damage than that of the spaces. The corner damage of Chungang Park in Hj ngju, showed the same result as D kjin Park in Ch nju and the uneveness didn't have any difference of damage type in all spaces. In case of Dosan in Seoul, the damage of crevice, demolition, and pumping didn't have any difference of damage type and the damage of the cross area was the most high. In conclusion, we proposed that we should get hold of whether the cause of pavement damage is caused by the defect of materials of by the construction problem including the foundation, or the unsuitableness of the method for using the pavement materials, and also that we should take a sensus of the user type and should decide a suitable design load and the necessary thickness of the pavement materials. In this study, not only we aimed at the external damage of the materials, but we tried to propose rather reasonable and developed construction method by studying the material experiment, the foundation state, and the type of using the spaces and materials, and by examining into the fundamental damaged cause.

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Development of Accelerator Control System for Wet Shotcrete Spraying Equipment (습식 숏크리트 뿜칠 장비의 급결제 유량 제어 시스템 개발)

  • Tae-Ho, Kang;Soo-Ho, Chang;Soon-Wook, Choi;Jin-Tae, Kim;Bong-Gyu, Kim;Chulho, Lee
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.353-362
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    • 2022
  • The wet shotcrete refers to a method in which all materials are mixed and then supplied to the spraying device, compressed air is added to the nozzle, and the spraying speed is improved to spray on the target surface. In order to reproduce the amount of shotcrete used in the wet method in the field and the situation at the laboratory scale, it is essential to control the discharge amount of the equipment. In this study, in order to increase the reproducibility of field conditions at the laboratory scale, a flow control system for shotcrete mortar spraying equipment was developed and applied to the equipment. To verify the developed equipment, a discharge control test using water and mortar was performed. In the developed control system, the discharge was smoothly controlled according to the user input value for the mono pump, but the discharge was not properly controlled according to the input value for the screw pump because of a reducer. When a speed reducer is attached, it is necessary to adjust the operation rate of the screw pump close to the target flow rate by increasing the operation rate of the screw pump while lowering the operation rate of the mono pump.

PROPOSAL OF NEW DENIAL COLOR-SPACE FOR AESTHETIC DENIAL MATERIALS (치과용 심미 수복 재료들의 색상 연구를 통한 새로운 치과용 색체계의 제안)

  • Oh, Yun-Jeong;Park, Su-Jung;Kim, Dong-Jun;Cho, Hyun-Gu;Hwang, Yun-Chan;Oh, Won-Mann;Hwang, In-Nam
    • Restorative Dentistry and Endodontics
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    • v.32 no.1
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    • pp.19-27
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    • 2007
  • The purpose of this study is to develope new dental color-space system. Twelve kinds of dental composites and one kind of dental porcelain were used in this study. Disk samples (15 mm in diameter, 4 mm in thickness) of used materials were made and sample's CIE $L^*a^*b^*$ value was measured by Spectrocolorimeter (MiniScan XE plus, Model 4000S, diffuse/$8^{\circ}$ viewing mode, 14.3 mm Port diameters, Hunter Lab USA) The range of measured color distribution was analyzed. All the data were applied in the form of T### which is expression unit in CNU Cons Dental Color Chart. The value of $L^*$ lies between 80.40 and 52.70. The value of $a^*$ are between 10.60 and 3.60 and $b^*$ are between 28.40 and 2.21. The average value of $L^*$ is 67.40, and median value is 67.30. The value of $a^*$ are 2.89 and 2.91 respectively. And for the $b^*$, 14.30 and 13.90 were obtained. The data were converted to T### that is the unit count system in CNU-Cons Dental Color Chart. The value of $L^*$ is converted in the first digit of the numbering system. Each unit is 2.0 measured values. The second digit is the value of $a^*$ and is converted new number by 1.0 measured value. For the third digit $b^*$ is replaced and it is 2.0 measured unit apart. T555 was set to the value of $L^*$ ranging from 66.0 to 68.0, value of $a^*$ ranging from 3 to 4 and $b^*$ value ranging from 14 to 16.

Growth and nutrient uptake by Palmaria palmata integrated with Atlantic halibut in a land-based aquaculture system

  • Corey, Peter;Kim, Jang K.;Duston, Jim;Garbary, David J.
    • ALGAE
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    • v.29 no.1
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    • pp.35-45
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    • 2014
  • Palmaria palmata was integrated with Atlantic halibut Hippoglossus hippoglossus on a commercial farm for one year starting in November, with a temperature range of 0.4 to $19.1^{\circ}C$. The seaweed was grown in nine plastic mesh cages (each $1.25m^3$ volume) suspended in a concrete sump tank ($46m^3$) in each of three recirculating systems. Two tanks received effluent water from tanks stocked with halibut, and the third received ambient seawater serving as a control. Thalli were tumbled by continuous aeration, and held under a constant photoperiod of 16 : 8 (L : D). Palmaria stocking density was $2.95kg\;m^{-3}$ initially, increasing to $9.85kg\;m^{-3}$ after a year. Specific growth rate was highest from April to June (8.0 to $9.0^{\circ}C$), 1.1% $d^{-1}$ in the halibut effluent and 0.8% $d^{-1}$ in the control, but declined to zero or less than zero above $14^{\circ}C$. Total tissue nitrogen of Palmaria in effluent water was 4.2 to 4.4% DW from January to October, whereas tissue N in the control system declined to 3.0-3.6% DW from April to October. Tissue carbon was independent of seawater source at 39.9% DW. Estimated tank space required by Palmaria for 50% removal of the nitrogen excreted by 100 t of halibut during winter is about 29,000 to $38,000m^2$, ten times the area required for halibut culture. Fifty percent removal of carbon from the same system requires 7,200 to $9,800m^2$ cultivation area. Integration of P. palmata with Atlantic halibut is feasible below $10^{\circ}C$, but is impractical during summer months due to disintegration of thalli associated with reproductive maturation.

A theoretical Study on the Motive of Movement in Animation (애니메이션의 Movement 동인(動因)에 대한 이론적 고찰)

  • Lee Sang-Won
    • Journal of Science of Art and Design
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    • v.3
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    • pp.62-86
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    • 2001
  • This study is based on theoretical background about movements of visual communication highlighted in digital age. Such movements are variously expressed in animation with the advancement of media, and their expression has great effect on visual art. Artists' concern and endeavor about movement expression techniques have been continued by impressionism, expressionism, futurism, cubism closely related with the birth of movie from late 19th century to early 20th century. At that time, stationary 2D space in plane screen couldn't express movement or time directly. Later, artists and designers have attempted to approach illusions in pictures or 4 dimension and movements by 2D or 3D computer graphics. The visual image in present digital age is to see, to hear, to feel by timing, so it is necessary for the most efficient way of message communication. And then, it is the time to start new, scientific, and creative study about production techniques of animation and expression of movements, since domestic animation productions are rapidly changed from cell to digital. The aim of this study is to clarify the motive of movement by theoretical inquiry of animation. Various aspects of animation as synthetic art have been examined by mathematical, scientific, and philosophical viewpoint. The results will be useful to the expression of motions for maximization of emotional effect in animation production or basic data of virtual simulation about certain situation. Therefore, such study should be managed as multidisciplinary research in the rapidly changing visual culture paradigm. namely, animation includes much more imaginative & creative power than simple function or techniques, so it has to be recognized as special synthetic art(visual art) constructing an area, the formative art with philosophical viewpoint and scientific principles.

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The solid angle estimation of acetabular coverage of the femoral head using 3D method (입체각 측정을 통한 대퇴골두에 대한 관골구 coverage 측정)

  • Choi, K.H.;Kim, M.C.;Lim, C.T.;Kim, S.I.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.05
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    • pp.123-126
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    • 1997
  • We present a method for the estimation of 3D solid angle assessment of the acetabular coverage of the femoral head in 3D space. At first, femoral head and acetabulum is segmented from the original CT scan images. The slice thickness is 1.5mm and the number of slices is usually 30-40 to cover the entire acetabulum. The superior half of the femoral head is modeled as part of a sphere. Thus, the axial cross sections of the upper half of the femoral head are also modeled as circles. A set of points from each outline image of femoral head is fitted recursively into a circle by minimizing root-mean-square (RMS) error. With these fitted circles, a center point of the femoral head model is evaluated. This is a reference point for calculating the solid angle of the acetabular inner surface. Next, the tangent lines connecting from a set of points of the acetabular edge to the center of the fitted sphere are obtained. The lines pass through the unit sphere whose center is the same as that of the femoral head. With the points on the unit sphere, we calculate area and estimate the solid angle. Based on this solid angle, the deformity of the acetabulum is analyzed. In case of normal subject, the solid angle is about 4.3 (rad) and acetabular coverage is 68%.

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KIC 6220497: A New Algol-type Eclipsing Binary with δ Sct Pulsations

  • Lee, Jae Woo
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.41.1-41.1
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    • 2016
  • We present the physical properties of KIC 6220497 exhibiting multiperiodic pulsations from the Kepler photometry. The light curve synthesis represents that the eclipsing system is a semi-detached Algol with a mass ratio of q=0.243, an orbital inclination of i=77.3 deg, and a temperature difference of ${\Delta}T=3,372K$, in which the detached primary component fills its Roche lobe by ~87% and is about 1.6 times larger than the lobe-filling secondary. To detect reliable pulsation frequencies, we analyzed separately the Kepler light curve at the interval of an orbital period. Multiple frequency analyses of the eclipse-subtracted light residuals reveal 32 frequencies in the range of $0.75-20.22d^{-1}$ with semi-amplitudes between 0.27 and 4.55 mmag. Among these, four frequencies ($f_1$, $f_2$, $f_5$, $f_7$) may be attributed to pulsation modes, while the other frequencies can be harmonic and combination terms. The pulsation constants of 0.16-0.33 d and the period ratios of $P_{pul}/P_{orb}=0.042-0.089$ indicate that the primary component is a ${\delta}$ Sct pulsating star in p modes and, thus, KIC 6220497 is an oscillating eclipsing Algol (oEA) star. The dominant pulsation period of about 0.1174 d is considerably longer than the values given by the empirical relations between the pulsational and orbital periods. The surface gravity of log $g_1=3.78$ is significantly smaller than those of the other oEA stars with similar orbital periods. The pulsation period and the surface gravity of the pulsating primary demonstrate that KIC 6220497 would be the more evolved EB, compared with normal oEA stars.

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Mechanical properties of sustainable green self-compacting concrete incorporating recycled waste PET: A state-of-the-art review

  • Shireen T. Saadullah;James H. Haido;Yaman S.S. Al-Kamaki
    • Advances in concrete construction
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    • v.16 no.1
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    • pp.35-57
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    • 2023
  • Majority of the plastic produced each year is being disposed in land after single-use, which becomes waste and takes up a lot of storage space. Therefore, there is an urgent need to find alternative solutions instead of disposal. Recycling and reusing the PET plastic waste as aggregate replacement and fiber in concrete production can be one of the eco- friendly methods as there is a great demand for concrete around the world, especially in developing countries by raising human awareness of the environment, the economy, and Carbon dioxide (CO2) emissions. Self-compacting concrete (SCC) is a key development in concrete technology that offers a number of attractive features over traditional concrete applications. Recently, in order to improve its durability and prevent such plastics from directly contacting the environment, various kinds of plastics have been added. This review article summarizes the latest evident on the performance of SCC containing recycled PET as eco-friendly aggregates and fiber. Moreover, it highlights the influence of substitution content, shape, length, and size on the fresh and properties of SCC incorporating PET plastic. Based on the findings of the articles that were reviewed for this study, it is observed that SCC made of PET plastic (PETSCC) can be employed in construction era owing to its acceptable mechanical and fresh properties. On the other hand, it is concluded that owing to the lightweight nature of plastic aggregate, Reusing PET waste in the construction application is an effective approach to reduces the earthquake risk of a building.

Nutrient Utilization, Body Composition and Lactation Performance of First Lactation Bali Cows (Bos sondaicus) on Grass-Legume Based Diets

  • Sukarini, I.A.M.;Sastradipradja, D.;Sutardi, T.;Mahardika, IG.;Budiarta, IG.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.12
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    • pp.1681-1690
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    • 2000
  • A study on energy and protein utilization, and milk production of Bali cows on grass-legume diets was carried out using 12 first lactation cows (initial BW $263.79{\pm}21.66kg$) during a period of 16 weeks starting immediately post calving. The animals were randomly allotted into 4 dietary treatment groups R1, R2, R3 and R4, receiving from the last 2 months of pregnancy onwards, graded improved rations based on a mixture of locally available grass and legume feed ad libitum. R1 contained on a DM basis 70% elephant grass (PP, Penisetum purpureum) plus 30% Gliricidia sepia leaves (GS), R2 was 30% PP plus 55% GS supplemented with 15% Hibiscus tilliactus leaves (HT, defaunating effect), R3 and R4 were 22.5% PP+41.25% GS+11.25% HT+25% concentrate, where R3 was not and R4 supplemented with zinc di-acetate. TDN, CP and zinc contents of the diets were 58.2%, 12.05% and 18.3 mg/kg respectively for R1, 65.05%, 16.9% and 25.6 mg/kg respectively for R2, 66.03%, 16.71% and 29.02 mg/kg respectively for R3 and 66.03%, 16.71% and 60.47 mg/kg respectively for R4. Milk production and body weight were monitored throughout the experimental period. In vivo body composition by the urea space technique validated by the body density method and supported by carcass data was estimated at the start and termination of the experiment. Nutrient balance and rumen performance characteristics were measured during a balance trial of 7 days during the 3rd and 4th week of the lactation period. Results indicated that quality of ration caused improvement of ruminal total VFA concentration, increments being 52 to 65% for R2, R3 and R4 above R1, with increments of acetate being less (31 to 48%) and propionate being proportionally more in comparison to total VFA increments. Similarly, ammonia concentrations increased to 5.24 to 7.07 mM, equivalent to 7.34 to 9.90 mg $NH_3-N/100ml$ rumen fluid. Results also indicated that feed quality did not affect DE and ME intakes, and heat production (HP), but increased GE, UE, energy in milk and total retained energy (RE total) in body tissues and milk. Intake-, digestible- and catabolized-protein, and retained-protein in body tissues and milk (Rprot) were all elevated increasing the quality of ration. Similar results were obtained for milk yield and components with mean values reaching 2.085 kg/d (R4) versus 0.92 kg/d (R1) for milk yield, and 170.22 g/d (R4) vs 71.69 g/d (R1), 105.74 g/d (R4) vs 45.35 g/d (R1), 101.34 g/d (R4) vs 46.36 g/d (R1) for milk-fat, -protein, and -lactose, respectively. Relatively high yields of milk production was maintained longer for R4 as compared to the other treatment groups. There were no significant effects on body mass and components due to lactation. From the relationship $RE_{total}$ (MJ/d)=12.79-0.373 ME (MJ/d); (r=0.73), it was found that $ME_{m}=0.53MJ/kgW^{0.75}.d$. Requirement of energy to support the production of milk, ranging from 0.5 to 3.0 kg/d, follows the equation: Milk Prod. ($Q_{mp}$, kg/d)=[-2.48+4.31 ME($MJ/kg^{0.75}.d$)]; (r=0.6) or $Q_{mp}$=-3.4+[0.08($ME-RE_{body\;tissue}$)]MJ/d]; (r=0.94). The requirement for protein intake for maintenance ($IP_m$) equals $6.19 g/kg^{0.75}.d$ derived from the relationship RP=-47.4+0.12 IP; (r=0.74, n=9). Equation for protein requirement for lactation is $Q_{nl}$=[($Q_{mp}$)(% protein in milk)($I_{mp}$)]/100, where $Q_{nl}$ is g protein required for lactation, $Q_{mp}$ is daily milk yield, Bali cow's milk-protein content av. 5.04%, and $I_{mp}$ is metabolic increment for milk production ($ME_{lakt}/ME_{m}=1.46$).