• Title/Summary/Keyword: $SrI_2$

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Formation and Intergrowth of the Superconducting Phase in the Bi2Sr2Can-1CunOx (n=2~4) System

  • Cheon, Min-Woo;Park, Yong-Pil
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.5
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    • pp.199-203
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    • 2004
  • Superconducting B $i_2$S $r_2$C $a_{n-l}$C $u_{n}$ $O_{x}$(n=2~4) thin films were prepared by single target DC-magnetron sputtering. And, that was compared with the B $i_2$S $r_2$C $a_{n-l}$C $u_{n}$ $O_{x}$(n=1~3) thin film fabricated by using the ion beam sputtering. Phase intergrowth among n=2-3, 3-4 and 4-5 phases was observed. The molar fraction of each phase in the mixed crystal of the deposited films was determined by x-ray diffraction analyses and investigated as a function of $O_2$ gas pressure during sputtering. We investigated the changes of the superconducting properties by molar fraction of each phase. Also, the thin film surface observation was carried out by atomic force microscope. The images show the average particle size decreases, and the distribution density of particles on the film surface was to increase with lower gas pressures. The fabrication conditions for selective growth of the single n=2, 3 and 4 phases in BiSrC $a_{n-l}$C $u_{n}$ $O_{x}$(n=2~4) thin film are discussed.e discussed.ussed.

Tropospheric Ozone over the Seoul Metropolitan Area Derived from Satellite Observations (MODIS) and Numerical Simulation (위성관측(MODIS)에서 유도된 수도권 지역의 대류권 오존 및 수치실험)

  • Yoo Jung-Moon;Park Yoo-Min;Lee Suk-Jo
    • Journal of the Korean earth science society
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    • v.26 no.3
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    • pp.283-296
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    • 2005
  • The effect of ozone and surface temperature on the ozone band at $9.7{\mu}m$ has been investigated from radiative transfer theory together with observations in order to derive empirical methods for remotely sensing ground-ozone concentration. Simultaneous observations of satellite (MODIS Aqua; ECT 13:30) and ground-ozone at 79 stations have been used over the Seoul Metropolitan Area (SMA; 125.7-127.2 E, 37.2-37.7 N) during four ozone-warning days in the year 2003. Cloud effect on the band in the methods was filtered out based on synoptic observations. Upwelling radiance values at $9.6{\mu}m$ which have been estimated at the given ozone concentration of 327-391 DU depend on surface temperature (Ts) showing $5.52\~5.78Wm^{-2}sr^{-1}\;at\;Ts = 290 K,\;and\;9.00\~9.57Wm^{-2}sr^{-1}$ Ts = 325K. Thus, the partitioned contributions of ozone and temperature to intensity of ozone absorption band are $0.26Wm^{-1}sr^{-1}/64\;DU\;and\;0.31 Wm^{-2}sr^{-1}/35K$, respectively. Here the intensity which has been used to remotely detect ground-ozone concentration from infrared satellite measurement is defined as the difference in brightness temperature between $11{\mu} m\;and\;9.7{\mu}m (i.e.,\; T_{11-9.7})$. The methods in this study have been applied to estimate ground-ozone from MODIS data in cases that there are significant correlations between the band intensity and ground-ozone. The values of estimated ozone significantly correlate (0.49-0.63) with ground observations at a significance level of $1\%$. For the improved methods, further study may be required to use tropospheric ozone rather than ground-ozone, considering the variation stratospheric ozone.

Coherent motion of fluxons in stacked intrinsic Josephson junctions of $Bi_2$$Sr_2$Ca$Cu_2$$O_{8+x}$ single crystals ($Bi_2Sr_2CaCu_2O_{8+x}$ 단결정 선천성 조셉슨 접합에서의 플럭손 결맞음 운동)

  • Doh, Yong-Joo;Chang, Hyun-Sik;Chang, Dong-In;Lee, Hu-Jong;Kim, Jinhee;Kim, Kyu-Tae;Lee, Woo;Choy, Jin-Ho
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.28-30
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    • 2001
  • We studied the flux-flow current-voltage characteristics of microwave-generated fluxons formed in serially stacked intrinsic Josephson junctions fabricated on$ HgI_2$-intercalated $Bi_2$$Sr_2$$CaCu_2$O/8+x/(Bi2212) single crystals. With increasing the irradiation power of 73$\square$76 GHz microwave, the supercurrent branch became resistive and split into multiple sub -branches. Each sub-branch represented a specific mode of collective motion of Josephson fluxons. We also observed similar branch splitting In a mesa prepared on an underdoped Bi2212 single crystal in a static magnetic field.

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Geochronology and Cooling history of the Mesozoic Granite Plutons in the Central Part of the Ogcheon Fold Belt, South Korea (남한 습곡대 중앙부의 중생대 화강암 질암의 생선년대와 냉각사)

  • Myung-Shik JIN
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.153-167
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    • 1995
  • Emplacement ages for the granite plutons of the Jurassic and the Cretaceous times in the central Ogcheom Fold Belt were determined by Rb-Sr whole rock and mineral isocheon methods. In addition mineral ages for the plutons were determined by K-Ar and fission track methods. In turn, thermal histories and uplifting rates of the granitic bodies are elucidated from the isotopic ages. The Jecheon(~203 Ma) and Mungyeong(at lest~200 Ma) granites of the Jurassic and the Muamsa, Wolagsan and Daeyasan granites(~110 Ma) of the Cretaceous show high strontium initial ratios [$(^{87}Sr/^{86}Sr)_1$0.7100],suggesting that the granitic magmas have been generated by partial melting of crustal materials (S-type), or by mixing of mantle and crustal materials. Only mineral ages of the Sogrisan and Hyeongjebong granites (~90 Ma) were determined by K-Ar method, and petrogenesis of them were not defined yet. The two Jurassic granite plutons were cooled rapidly down to $300^{\circ}C$, right after the plutons were slowly cooled down since then, due to their deep emplacment. During the Middle Cretaceous period, the Jurassic Mungyeong granitic pluton was intruded and thermally affected much by the surrounding Wolagsan and Daeyasan granites. Accordingly the Rb-Sr mineral age, K-Ar hornblende and biotite ages of the Mungyeong granite appear to be reduced or reset due to the thermal effects above their blocking temperatures. All the cretaceous granites have been cooled much ore simply and rapidly down than the Jurassic ones below $300^{\circ}C$, owing to their shallow emplacement.

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The photocatalytic water splitting into $H_2$ and $O_2$ mimicking a Z-scheme mechanism (광합성을 모사한 광촉매 물분해 수소 제조)

  • Jeon, Myung-Seok;Hong, Joon-Gi;Chun, Young-Gab;Choi, Ho-Suk
    • Journal of the Korean Solar Energy Society
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    • v.23 no.4
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    • pp.29-35
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    • 2003
  • We studied the water splitting into $H_2$ and $O_2$ using two different semiconductor photo catalysts and redox mediator, mimicking the Z-scheme mechanism of the photosynthesis, $H_2$ evolution took place on a Pt-$SrTiO_2$ (Cr-Ta doped) photocatalyst using $I^-$ electron donor under the visible light irradiation. The Pt-$WO_3$ photocatalyst showed an excellent activity of the $O_2$ evolution using $IO_3^-$ electron acceptor under visible light. $H_2$ and $O_2$ gases evolved in the stoichiometric ratio($H_2/O_2$=2) under visible light using a mixture of the Pt-$WO_3$ and Pt-$SrTiO_3$ (Cr-Ta doped) suspended in NaI aqueous solution. We proposed a two-step photo-excitation mechanism using redox mediator under the visible irradiation.

Fabrecation and Characterization of $SrBi_2TaNbO_9$ Ferroelectric Thin Film Prepared by Sol-Gel Method (SOL-GEL법을 이용한 $SrBi_2TaNbO_9$ 강유전성 박막 제조 및 특성 평가)

  • 이진한;박상준;장건익
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.94-98
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    • 2000
  • Polycrystalline SBTN ferroelectric thin films were prepared by sol-gel method with various Nb mole ratios on Pt/ $SiO_2$/Si (100) substrates. The films were annealed at different temperatures and characterized in terms of phase and microstructure. Relatively a well saturated hysteresis pattern was obtained at x =0.2 in S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$)$_2$ $O_{9+}$$\alpha$/ thin films. At an applied voltage of 5V, the dielectric constant ($\varepsilon$$_{r}$) and dissipation factor (tan $\delta$) of typical S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$)$_2$ $O_{9+}$$\alpha$/ thin film (x=0.2) were about 236.2 and 0.034. Measured remanent polarization (2Pr) and coercive field (Ec) were 4.28C/c $m_2$, and 38.88kv/cm respectively. No fatigue was observed up to 6$\times$10$_{10}$ switching cycles at 5V and the normalized polarization reduced by a factor of only 4%.%. 4%.%. 4%.%.%.%.%.

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Microstructure and Properties of $(Sr_{1-x}Ca_x)TiO_3$Ceramic Thin film ($(Sr_{1-x}Ca_x)TiO_3$세라믹 박막의 미세구조 및 특성)

  • Kim, Jin-Sa;Lee, Jun-Ung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.10
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    • pp.504-508
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    • 2001
  • The$(Sr_{1-x}Ca_x)TiO_3$(SCT) thin films are deposited on Pt-coated electrode $(Pt-TiN /SiO_2Si)$ using RF sputtering method at various deposition temperature. The crystallinity of thin films was increased with increased of deposition temperature n the temperature range of 200~500 $[^{\circ}C]$. The capacitance changes almost linearly in temperature ranges of -80~+90$[^{\circ}C]$. All SCT thin films used in the study the phenomena of dielectric relaxation with the increase of frequency, and the relaxation frequency is observed above 200[kHz]. V-I characteristics of SCT thin films show the increasing leakage current with the increases of deposition temperature.

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A Study on the Structural Properties of $Al_2O_3$-doped (Ba,Sr,Ca)$TiO_3$ ceramics ($Al_2O_3$가 첨가된 (Ba,Sr,Ca)$TiO_3$계 세라믹의 구조적 특성에 관한 연구)

  • Lee, S.G.;Lim, S.S.;Lee, Y.H.;Park, I.G.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1493-1495
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    • 2001
  • $(Ba_{0.6-x}Sr_{0.4}Ca_x)TiO_3+yAl_2O_3$ wt% (x=0.10, 0.15, 0.20, y=0.5 $\sim$ 3.0) specimens were fabricated by the mixed-oxide method and then the structural properties as a function of the composition ratio and $Al_2O_3$ contents were studied. All BSCT specimens showed dense and homogeneous structure without the presence of the seconds phase. The sintered density was decreased with increase ad $Al_2O_3$ content. The Curie temperature and dielectric constant at room temperature decreased with increasing $Al_2O_3$ content. The dielectric constant and dielectric loss of the doped-0.5 wt% $Al_2O_3$ BSCT(50/40/10) specimen were about 3131 and 0.932% at 1KHz, respectively.

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Three-dimensional sensitivity design pattern development of Mobile Metal Case which used EF(INNET) (E/F(INNET)을 이용한 Mobile Metal Case의 3차원 감성 디자인패턴 개발)

  • Cheon, Sang-Hyeon;Ji, Sang-Won
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 2009.11a
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    • pp.20-24
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    • 2009
  • Mobile의 기술발달과 보편화에 따라 소비자들은 Mobil이 자기 개성 표현인 액세서리화되고, 더욱 감성적이고 차별화된 디자인을 요구함에 따라, 기업들은 이런 소비자들의 개성화 감성화의 니즈를 표면처리 디자인 기술로 효율적으로 적용해 소비자의 감성만족을 시키려 하고 있다. 국내외 Mobile 시장에서 Metal Case 외장의 2차원적인 디자인패턴은 다양한 표면처리 가공 접근이 용이하지 못하고, 패턴디자인의 한계에 이르렇다. E/F(INLET)의 도금 가공 기술의 Concept은 "원활한 모재의 제품 박리성" 에 있으나, 역발상으로 "Metal 모재와의 밀착성"으로 제품디자인을 구현하여, 제품의 도금 두께층 및 신뢰성 기술 확보함으로, 표면층에 사진, 그림, 인물 풍경, 자연물이미지 등의 다양한 감성디자인패턴의 구현이 가능해졌다. 산업기술자원부의 디자인혁신센터로 중소기업디자인개발 지원을 위해 설립된 중앙대학교 디자인경영센터와 SR I-TECH의 기술력으로 3차원 감성디자인패턴을 개발하게 되었다.

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