• 센서학회지
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• 제7권3호
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• pp.147-153
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• 1998

$Si_{3}N_{4}/SiO_{2}/Si_{3}N_{4}$(N/O/N) 다이아프램과 결합된 고감도의 광섬유 Fabry-Peort 압력센서를 개발하여 스트레인 및 그 응답특성을 조사하였다. 먼저, 44 wt% KOH 수용액을 이용한 실리콘 이방성식각기술로 600 nm 두께의 N/O/N 다이아프램을 제조하였으며, 제조된 다이아프램과 광섬유 Fabry-Perot 간섭계를 결합하여 광섬유 압력센서를 구성하였다. 단일모드 광섬유(SMF)내에 $TiO_{2}$ 유전체 박막을 용융접합하여 공극의 길이가 약 2 cm인 광섬유 Fabry-Perot 간섭계를 제작하였다. 광섬유 Fabry-Perot 간섭계의 한쪽 끝은 N/O/N 다이아프램과 결합하였으며, 나머지 한쪽을 3 dB 광결합기를 통해 광측정장치에 연결하였다. $2{\times}2\;mm^{2}$ 및 $8{\times}8\;mm^{2}$ 크기의 N/O/N 다이아프램에 대해 응답특성을 조사한 결과, 각각 약 0.11 rad/kPa과 1.57 rad/kPa의 압력감도를 나타내었으며, 선형오차는 0.2 %FS이내였다.

• 약학회지
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• 제26권1호
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• pp.9-23
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• 1982

The structure of 1-butyl-3-sulfanyl urea, ($C_{11}H_{17}N_{3}O_{3}S$) carbutamide has been determined from 575 significant independent reflections collected on an automated four-circle diffractometer. The crystals are orthorhomic, space group, $P2_{1}2_{1}2_{1}$, Z=4, with unit cell dimensions a=9.257 (2), b=9.928 (2), c=15.287 (3)${\AA}$. The structure was solved by the direct methods and refined by least-squares procedure to a final R value of 0.062. Features of the structure include layers of molecules joined by N-H....O hydrogen bond distances ranging from 2.745 to 3.100${\AA}$ involved in a bifurcated hydrogen bond across two fold screw along a and b axes. The atoms forming the urea system are essentially planar.

• 한국항해항만학회지
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• 제37권6호
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• pp.611-616
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• 2013

이 연구에서는 최근 25년간의 우리나라 기상청 및 일본 기상청 자료를 사용하여 선박의 안전에 크게 영향을 미치는 태풍과 엘니뇨 라니냐 현상과의 관계를 분석하였다. 주요 분석 결과는 다음과 같다. 엘니뇨 발생년의 연평균 태풍 발생 수는 23.9개이고, 라니냐 발생년의 그것은 24.9개이다. 엘니뇨 발생년에 태풍의 발생 수가 감소한다는 사실을 알 수 있다. 태풍의 세기를 나타내는 평균 중심최저기압과 평균 최대 풍속은 엘니뇨 발생년에 959.3hPa과 35.8m/s, 라니냐 발생년에 965.5hPa과 33.7m/s이었다. 즉, 엘니뇨 발생년의 태풍의 세기가 라니냐 발생년의 태풍의 세기보다 강함을 알 수 있다. 구체적으로 평균 중심최저기압은 6.2hPa 낮고, 평균 최대풍속은 2.1m/s 강하다. 이와 같은 결과는 태풍의 발생 해역과 밀접히 관련되어 있다. 즉, 엘니뇨 발생년에 태풍은 동경 150도 이동 해역과 북위 10도 이남 해역에서 상대적으로 더 많이 발생하고, 라니냐 발생년의 태풍은 동경 120-150도 해역과 북위 20도 이북 해역에서 더 많이 발생한다. 동경 150도 이동 해역과 북위 10도 이남 해역에서 발생한 태풍은 북태평양 서부의 광범위한 고수온역을 보다 장시간 이동하게 되므로 더 강력하게 발달할 수 있다.

• 한국환경보건학회지
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• 제27권1호
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• pp.93-99
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• 2001

This study aims at finding out pertinent reaction conditions for treating high concentration ammonia contained in N-chemical factory wastewater with decompressed ammonia stripping method that was designed. And it also tries to investigate adsorption capability of removed ammonia to soil. The results from experiments are as follows ; 1. The removal rate of N $H_3$-N of synthetic wastewater was under 85% at pH 10 with decompressed ammonia stripping method. The reaction time in pressure 360 mmHg at pH 11 and 12 was shorter than in 460 mmHg, and the removal rate of N $H_3$-N with decompressed ammonia stripping method at 9$0^{\circ}C$ was 11~15% higher than air stripping 2. The optimum conditions for decompressed ammonia stripping with synthetic sample were shown as pH 12, temperature 9$0^{\circ}C$, internal reaction pressure 460 mmHg and reaction time 50 minutes. These conditions were applied to treat the wastewater containing organic-N 290.5mg/$\ell$, N $H_3$-N 168.9mg/$\ell$, N $O_2$-N 23.2mg/$\ell$, N $O_3$-N 252.4mg/$\ell$, T-N 735mg/$\ell$. Organic-N turned out to be removed 60%, the removal rate of N $H_3$-N IS 94%, T-N is 50%. But N $O_2$-N and N $O_3$-N were increased with 7.8% and 14.9% respectively. 3. The CO $D_{Sr}$ removal rate in decompressed ammonia stripping reaction was 42% and S $O_4$$^{2-}$ was removed 8.2%. It was turned out caused with higher pH and thermolysis. 4. In soil adsorption of ammonia desorbed from the decompressed stripping process of wastewater, the recovery rate was 76% in wet soil.

• 한국환경과학회지
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• 제7권5호
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• pp.707-716
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• 1998

The chemical characteristics of precipitation was investigated in Pusan area. Samples were collected from January to November in 1996 at 4 sites, and analyzed pH, major soluble ionic components(C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, N $a^{+}$, $K^{+}$, N $H_4$$^{+}$, $Mg^{2+}$, $Ca^{2+}$). The order of anion and cation concentrations for the initial precipitation were C $l^{[-10]}$ ＞ S $O_4$$^{2-}$ ＞ N $O_3$$^{[-10]}$ , and $Ca^{2+}$ ＞ N $a^{+}$ ＞ N $H_4$$^{+}$ ＞ $Mg^{2+}$ ＞ $K^{+}$, respectively. At coastal sites(P1 and P2) C $l^{[-10]}$ and N $a^{+}$ of maritime sources (seasalt) were high, but at inland sites(P3 and P4) nss-C $a^{2+}$ and nss-S $O_4$$^{2-}$ were high. Calcium ion for the initial precipitation showed high value of enrichement factor(EF) relative to seawater composition. The contribution of seasalt to the composition of precipitation was higher at bite P1 (53.5%) than those of the other sites. Throughout the year the concentrations of major ions for the initial precipitation were low in the heavy rain season. The mean pH for the initial precipitation was 5.4 and showed the negative relationship with the precipitaion amount. The S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ do not play an important role in rain acidification due to the high(97%) neutralizing effect of amonia and calcium species.and calcium species.

• 한국대기환경학회지
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• 제19권3호
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• pp.263-273
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• 2003

P $M_{2.5}$ fine particles have been collected at the Cosan measurement station in Jeju Island, and the major water-soluble components have been analyzed in order to Investigate the aerosol compositions and pollution characteristics. The mean concentrations of the components were in the order of S $O_4$$^{2-}$> N $H_4$$^{+}$> N $O_3$$^{[-10]}$ > N $a^{+}$> $K^{+}$>C $l^{[-10]}$ >C $a^2$$^{+}$>M $g^2$$^{+}$. The major components were S $O_4$$^{2-}$, N $H_4$$^{+}$ and N $O_3$$^{[-10]}$ , whose compositions were 58％, 18％ and 10％ of the total ions, respectively. Most of the components showed higher concentrations in spring season, and especially $Ca^2$$^{+}$, N $O_3$$^{[-10]}$ and S $O_4$$^{2-}$ concentrations were increased 2.8, 1.9 and 1.2 times higher than the annual mean concentrations. The most parts of S $O_4$$^{2-}$ and N $H_4$$^{+}$ were distributed in fine particles below 2.1 ${\mu}{\textrm}{m}$ size, but the $Ca^2$$^{+}$, N $a^{+}$ and C $l^{[-10]}$ showed relatively higher concentrations in coarse particles. Based on the factor analysis, the P $M_{2.5}$ fine particles were considered to be largely influenced by anthropogenic sources, and followed by sea salt and soil sources. In the variations of concentrations as a function of wind direction, most components have shown higher concentrations notably as the northwesterly prevails.thwesterly prevails.

• 한국세라믹학회지
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• 제30권2호
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• pp.85-92
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• 1993

Oxynitride glasses in Na-Ca-Si-O-N system were prepared by melting at 135$0^{\circ}C$ for 2 hours in N2 gas. The effects of Si/Na mole ratio and the various Si3N4 contents were investigated. Stable oxynitride glasses can be obtained up to 9wt.% Si3N4 content in case the Si/Na mole ratio was 2.12 and 1.62, but $\beta$-Si3N4 was precipitated at 9wt.% Si3N4 content in case the Si/Na mole rtio was 1.12. Density (p), chemical durability, hardness (Hv), and fracture toughness (KIC) increased with increasing Si3N4 content. In cae the Si/Na mole ratio was 1.12, the increment of properties was remarkable but hardness and fracture toughness did not increase no longer owing to precipitation of $\beta$-Si3N4.

• Bulletin of the Korean Chemical Society
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• 제18권8호
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• pp.880-886
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• 1997

Ab initio calculations were carried out on the gas phase acid-catalyzed hydrolysis reactions of sulfinamide using the 3-21G* basis sets. Single point calculations were also performed at the MP2/6-31G* level. The first step in the acid-catalyzed hydrolysis of N-methylmethanesulfinamide, Ⅰ, involves protonation. The most favorable form is the O-protonated one, Ⅱ, which is then transformed into a sulfurane intermediate, Ⅲ, by addition of a water molecule. The reaction proceeds further by an intramolecular proton transfer from O to N (TS2), which is followed by N-S bond cleavage (TS3) leading to the final products. The rate determining step is the N-S bond cleavage (TS3) at the RHF/3-21G* level, whereas it becomes indeterminable at the MP2/6-31G*//3-21G* level of theory. However, the substituent effect studies with N-protonated N-arylmethanesulfinamide, ⅩⅢ, at the MP2/6-31G*//3-21G* level support the N-S bond breaking step as rate limiting.

• 대한수학회보
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• 제56권3호
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• pp.681-689
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• 2019

The $M{\ddot{o}}bius$ homogeneous submanifold in ${\mathbb{S}}^{n+1}$ is an orbit of a subgroup of the $M{\ddot{o}}bius$ transformation group of ${\mathbb{S}}^{n+1}$. In this note, We prove that a compact $M{\ddot{o}}bius$ homogeneous submanifold in ${\mathbb{S}}^{n+1}$ is the image of a $M{\ddot{o}}bius$ transformation of the isometric homogeneous submanifold in ${\mathbb{S}}^{n+1}$.

• 한국축산시설환경학회지
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• 제7권2호
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• pp.111-118
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• 2001

This study was performed for measuring the emission of greenhouse gases, $CH_4,\;N_2O$, from the composting process for pig slurry. For the experiment the benchscale pilot plant was designed by 1$m^3$ volume reactor with a closed type and operated; sawdust 142kg filled before input slurry, slurry about 10~20l inputed per day (total 380l), air supplied 5l/min for 24 hours, mixing time 10 min./day and 1 time a day. From the total experiment period(30days), the amount of VS degradation and emission $CH_4$, $N_2O$ were 10.9kg-VS and 1,582.4g-$CH_4$, 68.1g-$N_2O$ respectively. Based on VS inputed the emission of $CH_4$, $N_2O$ were 15.3(g-$CH_4$/kg-V $S_{input}$), 0.7(g-$N_2O$ /kg-V $S_{input}$), and based on VS degradated were 145.2(g-$CH_4$/kg-V $S_{removed}$), 6.2(g-$N_2O$ /kg-V $S_{removed}$).