• 제목/요약/키워드: $SO_2$ measurement

검색결과 1,940건 처리시간 0.062초

Experimental Determination of Equilibrium Constants of Copper Complexes in Aqueous Environment

  • Cho, Young-Il
    • 한국환경과학회지
    • /
    • 제21권5호
    • /
    • pp.555-562
    • /
    • 2012
  • The experimental determination of equilibrium constants is required to estimate concentrations of reagents and/or products in environmental chemical reactions. For an example, the choice of copper (Cu) complexation reactions was motivated by their fast kinetics and the ease of measurement of Cu by an ion-sensitive electrode. Each individual titrant of sulfate ($SO{_4}^{2-}$) and oxalate ($C_2O{_4}^{2-}$) was expected to have its own unique characteristics, depending on the bonding in Culigands connected to the aqueous species. The complexation reaction of Cu with $SO{_4}^{2-}$ somewhat fast reached equilibrium status compared with $C_2O{_4}^{2-}$. The experimental equilibrium constants ($K_{eq}$) of copper sulfate ($CuSO_4$) and copper oxalate ($CuC_2O_4$) were determined $10^{2.2}$ and $10^{3{\sim}4.3}$, respectively.

석탄비산재로부터 합성한 제올라이트의 SO2 흡착특성 (Adsorption of SO2 by Zeolite Synthesized from Coal Fly Ash)

  • 김성수;이창한
    • 한국환경과학회지
    • /
    • 제21권6호
    • /
    • pp.687-694
    • /
    • 2012
  • Zeolite 4A was synthesized by fusion method from coal fly ash discharged at the thermal power plants. The synthesized zeolite(FAZ) was characterized through particle size analyzer, XRD, XRF and SEM. $N_2$ adsorption-desorption measurement was used to examine surface and pore structures. The adsorption experiments were carried out under dynamic conditions of trace $SO_2$ in $N_2$ to investigate $SO_2$ adsorption capacity of FAZ. The experiments were conducted to characterize the breakthrough characteristics of $SO_2$ in a fixed bed under different operating conditions including temperature(50-$125^{\circ}C$), concentration of $SO_2$(3000-10000 ppm) and FAZ with 4 kinds of commercial zeolite. The adsorption capacity of FAZ was 53.84 $mgSO_2/g$ adsorbent, larger than that of the same type commercial zeolite(WK4A).

Passive sampler를 이용한 공단 지역의 $NO_2$, $SO_2$ 측정 (The measurement of $NO_2$, $SO_2$ by Passive sampler in industrial complex)

  • 김성근;손찬웅;김선태;인치경
    • 한국대기환경학회:학술대회논문집
    • /
    • 한국대기환경학회 2000년도 춘계학술대회 논문집
    • /
    • pp.125-126
    • /
    • 2000
  • 현재 공단지역에서 발생하는 오염물질을 파악하기 위해서는 오염물질이 배출되는 곳에 TMS를 설치하거나 측정하고자 하는 지점에 습식법을 이용하여 오염물질을 측정하는 방법이 사용되고 있다. 하지만 이러한 TMS나 습식법을 이용하여 오염물질을 측정하기 위해서는 고가의 설치비나 인력 장비 문제로 인하여 동시에 여러 지역을 측정하기 어렵다는 단점을 가지고 있으며, 특히 공단 지역과 같은 특수한 지역의 오염물질의 경향을 파악하기 위해서는 더욱 그러하다. (중략)

  • PDF

Digital moire 형상측정 시스템의 보정에 관한 연구 (A Study on the Calibration of Shape Measurement System Using Digital moire)

  • 김도훈;유원재;박낙규;강영준
    • 한국공작기계학회:학술대회논문집
    • /
    • 한국공작기계학회 2003년도 춘계학술대회 논문집
    • /
    • pp.255-259
    • /
    • 2003
  • Moire topography method isa well-known non-contacting 3-D measurement method as afast non-contact test for three-dimension shape measuring method. Recently, it's important to study the automatic three-dimension measurement by moire topography because it is frequently applied to the reverse engineering , the medical , the entertainment fields. Three-dimension measurement using projection of moire topography is very attractive because of its high measuring speed and high sensitivity. In this paper, the classical moire method is computerized-so called digital moire when a virtual grating pattern is projected on a surface, the captured image by the CCD camera has three-dimension information of the objects. The moire image can be obtained through a simple image processing and a reference grating pattern. and it provides similar results without physical grating pattern. digital projection moire topography turn out to be very effective for the three-dimension measurement of objects. Using different N-bucket algorithm method of digital projection moire topography is tested to measuring object with the 2-ambiguity problem. Experimental results prove that the proposed scheme is capable of finding measurement errors that decreased more by using the four-three step algorithm method instead of the same step in the phase shifting of different pitch.

  • PDF

대기중(大氣中) 배출(排出)된 일산화탄소(一酸化炭素)와 아황산(亞黃酸)가스의 지속시간(持續時間) (On Effluent Concentration and Time of Fading Out of Carbon Monoxide and Sulful Dioxide in Atmosphere)

  • 김두희
    • Journal of Preventive Medicine and Public Health
    • /
    • 제7권2호
    • /
    • pp.373-375
    • /
    • 1974
  • 일산화(一酸化) 탄소(炭素)에 대한 피해와 대기오염(大氣汚染) 기준을 아황산(亞黃酸)까스를 기준으로 한다는 데의 관심을 가지고 가정에서 많이 사용하고 인는 연탄을 중심으로 관찰한 결과 CO는 연소온도와 비례하나 $SO_2$는 비례하지 않으며 일단 발생된 CO는 적어도 24시간(時間) 이내에는 변화가 거의 없으며 비교적 장시간 유지한다. $SO_2$는 대기중에서 곧 변화를 일으켜 ($H_{2}SO_{4}$로 전환) 30분이내에 극소량으로 되므로 대기중의 황화물 측정은 $SO_2$보다 유황자체나 $H_{2}SO_{4}$를 측정함이 더욱 효과적이라 하겠다.

  • PDF

Distribution Channel Performance Measurement: Valid Measures From Customers' Perspective

  • Kim, Sang-Youl
    • 한국항해항만학회지
    • /
    • 제32권2호
    • /
    • pp.141-148
    • /
    • 2008
  • This paper is structured into three main parts and a conclusion. The main section provide definitions of efficiency, effectiveness and performance in terms of the distribution channel, followed by a review of related performance measurement, before discussing difficulties of measurement. According to the theoretical approach, it appears that key theroretical issues are centered around customer service, logistics excellence, time compression, the use of IT, and a move towards integrated logistics. The empirical approach shows that in the past, various financial performance indicators were regarded as relevant management information. However, today, management needs additional performance indicators. Therefore, external assessments of effectiveness must be performed to measure customers' satisfaction with the physical flow of product through the distribution channel network. So, what is needed is to take previous normative and explorative research and progress through a framework by developing valid measures of distribution channel's effectiveness and efficiency, and identifying research methodologies suited to the data collection requirements.

CO2 EMISSION MEASURING METHODOLOGY DEVELOPMENT FOR ACCURACY IMPROVEMENT OF CO2 EMISSION OF CONSTRUCTION EQUIPMENT

  • Won-Suk Jang;Sun-Chan Bae;Sang-Dae Park;Suk-Hyun Kwon;Byung-Soo Kim
    • 국제학술발표논문집
    • /
    • The 5th International Conference on Construction Engineering and Project Management
    • /
    • pp.204-208
    • /
    • 2013
  • CO2 emission makes up more than 80% of whole green gas. Therefore CO2 is recognized as the main culprit of global warming. IPCC (Intergovernmental Panel on Climate Change) is advising the 3 methods measuring CO2 emission. TIER1 is measured CO2 emission by criteria the energy consumption, TIER2 measure by criteria the emission factor according to the emission control technique each kind of vehicle, TIER3 is measured by criteria the distance each kind of vehicle. Currently, the most of CO2 emission measurement is used by TIER1. But it is not standardized that CO2 emission measurement method have the factor as work condition each distance. Specially, it is not suggest that methodology has the condition changing load of equipment according to site condition and the same position work as construction equipment. So, this study is suggested the CO2 emission measurement methodology of construction equipment.

  • PDF

High Atmospheric Loading for $SO_2$ and Sulfate Observed in the Kanto Area, Japan During the Miyakejima Volcanic Eruption

  • Ma, Chang-Jin;Cao, Renqiu;Tohno, Susumu;Kasahara, Mikio
    • Journal of Korean Society for Atmospheric Environment
    • /
    • 제22권E2호
    • /
    • pp.69-77
    • /
    • 2006
  • Combined gas and aerosol measurements at a downwind area of the volcanic plume would be essential for helping to access the impact of the volcanic eruption on the local ecosystem and residents. An intensive and the fine time resolution measurement of $SO_2$, sulfate and PM2.5 was made to estimate their distribution in the Kanto area of Japan during the Miyakejima volcanic eruption period. In Tokyo, the 1 hr average $SO_2$ concentration observed before the eruption was 23.9 ppbv, while that of after eruption was 140.4 ppbv. In the Saitama Prefecture, the average concentration of $SO_2$ marked in the present study was two times higher than the average before the volcanic eruption. The PM2.5 mass concentrations in Sitama ranged from 3.8 to $136{\mu}g\;m^{-3}$. Sulfate accounts for $4.4{\sim}39.6%$ of PM2.5 in Sitama. The good correlationship between the concentrations of $SO_2$ and sulfate was obtained. The results of the VAFTAD and HYSPLIT models indicate that $SO_2$, sulfate, and PM2.5 measured in the present study would be expected to be significantly affected by the Miyakejima volcanic plume.

카메라 모델과 투시 변환에 의한 레일 마모도 측정 시스템 개발 (Development of the Railway Abrasion Measurement System using Camera Model and Perspective Transformation)

  • 안성혁;강동은;문형득;박소연;김만철
    • 한국철도학회:학술대회논문집
    • /
    • 한국철도학회 2008년도 추계학술대회 논문집
    • /
    • pp.1069-1077
    • /
    • 2008
  • 레이저와 카메라를 이용한 레일 마모도 측정 시스템은 정확한 마모도 측정을 위하여 레일에 조사된 레이저의 영역을 왜곡 없이 획득하고 이를 레일 단면과 정밀하게 일치시키는 과정이 매우 중요하다. 그러나 기존의 레일 마모도 측정 시스템은 빗물 등의 레일 위에 이물질이 있을 경우와 온도와 같은 측정 환경에 민감하게 반응하는 레이저의 특성으로 인하여 오차가 발생할 수 있으며 특히 외부에서 유입되는 태양광, 등과 같이 레일에 조사된 레이저와 같은 파장을 가지는 빛의 간섭에 의하여 레일에 조사된 레이저 영역 추출에 한계를 가진다. 또한, 2차원 상의 좌표 값으로 표현되는 추출된 레이저 영역을 레일단면에 맵핑시키는 과정에서 발생하는 기하학적 왜곡과 변형으로 측정 정밀도에 대한 한계가 발생하는 문제점을 가지고 있다. 본 논문에서는 레일 마모도 측정을 위하여 카메라로부터 입력되는 1메가급 해상도의 영상을 초당 480 프레임의 속도로 실시간 처리할 수 있는 DSP와 FPGA가 탑재된 고성능 영상처리보드를 개발하고 이를 기반으로 각 프레임에 대한 2D 영상 데이터를 3차원 상의 데이터로 맵핑함으로써 정밀한 레일 마모도 측정 방법을 제안하고자 한다. 획득한 영상으로부터 레일에 조사된 레이저의 영역을 정확하게 추출하기 위하여 웨이브렛 기반의 영상 알고리즘을 적용하고 2차원 상의 좌표값으로 표현된 레이저 영역을 카메라 모델과 투시 변환을 이용하여 레일의 단면에 정확하게 위치시킴으로서 ${\pm}0.5mm$ 이하의 오차범위를 가지는 고정밀 레일 마모도 측정 시스템을 개발하였다.

  • PDF