• 제목/요약/키워드: $RuO_6$ rotation

검색결과 2건 처리시간 0.017초

Temperature Dependent Octahedral Tilting Behaviors of Monoclinic and Tetragonal SrRuO3 Thin Films

  • Lee, Sung Su;Seo, Okkyun;Kim, Jaemyung;Song, Chulho;Hiroi, Satoshi;Chen, Yanna;Katsuya, Yoshio;Sakata, Osami
    • Journal of the Korean Physical Society
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    • 제73권10호
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    • pp.1529-1534
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    • 2018
  • We used in-situ synchrotron X-ray scattering to investigate phase transformations of octahedral tilted monoclinic $SrRuO_3$ (MSRO) and tetragonal SRO (TSRO) thin films on $SrTiO_3$ (STO) substrates. The octahedral tilted MSRO thin films were highly crystalline and the monoclinic distortion angle was $0.45^{\circ}$. The phase transition temperature from the MSRO to TSRO phase occurred at approximately $200^{\circ}C$ as a second order transition. Conversely, no phase transformations of the TSRO thin film occurred within the range from RT to $250^{\circ}C$. The octahedral $RuO_6$ rotation was strongly affected by the phase transformation in the SRO thin films.

질소 열처리에 따른 $RuSr_2(EuCe)Cu_2O_z$ 계의 구조 및 자기적 특성 (Effect of Nitrogen Treatment on the Structure and Magnetic Properties of $RuSr_2(EuCe)Cu_2O_z$ Compound)

  • 이호근;김용일;김영철
    • Progress in Superconductivity
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    • 제13권3호
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    • pp.178-183
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    • 2012
  • Two $RuSr_2(EuCe)Cu_2O_z$ samples (as prepared and after $N_2$ treatment) have been investigated by thermogravimetric (TC) analysis, high-resolution x-ray powder diffraction and magnetization measurements. TG measurements which were carried out in $H_2/Ar$ atmosphere showed that the $N_2$ treatment of the as-prepared sample at $650^{\circ}C$ for 2h leads to a decrease in the oxygen content z by about 0.25. This oxygen depletion was accompanied by an increase in the magnetic transition temperature from 54.0 K to 114.9 K. This magnetic behavior is discussed in connection with the results of Rietveld analysis of the x-ray diffraction data which showed that the $N_2$ treatment resulted in both a significant increase in the rotation angle of the $RuO_6$ octahedra and a decrease in c-lattice parameter of the sample.