• 제목/요약/키워드: $Pr^{3+}$

검색결과 1,588건 처리시간 0.027초

$ZnO-Pr_6/O_{11}-CoO-Er_2O_3$계 세라믹스의 바리스터 특성 (Varistor Characteristics of $ZnO-Pr_6/O_{11}-CoO-Er_2O_3$-Based Ceramics)

  • 윤한수;박춘현;남춘우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.308-311
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    • 1999
  • The varistor characteristics of $ZnO-Pr_6O_11-CoO-Er_2O_3$-based ceramics were investigated. $ZnO-Pr_6O_11-CoO-Er_2O_3$-based ceramics were sintered at $1300^{\circ}C$ and $1350^{\circ}C$in the addition range 0.0~2.0mol% $Er_2O_3$, respectively. $ZnO-Pr_6O_11-CoO-Er_2O_3$-based ceramics, which are added with 0.5mol% $Er_2O_3$ at $1300^{\circ}C$ and l.Omol% $Er_2O_3$ at $1350^{\circ}C$ sintering temperature, exhibited the bestexcellent varistor characteristics, namely, the nonlinear exponent was better 52.78 at $1300^{\circ}C$ thanat 13$1350^{\circ}C$ and the leakage current was better 6.57$\mu\textrm$A at $1350^{\circ}C$ than at $1300^{\circ}C$. Consequently, it is estimated that $ZnO-Pr_6O_11-CoO-Er_2O_3$-based ceramics, which $Er_2O_3$ is added in the range 0.5~l.Omol% will begin to be used as a predominant basic composition of $PR_6O_11$-based ZnO varistors.

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$Dy_2$$O_3$가 첨가된 $Pr_6$$O_{11}$계 ZnO 바리스터의 전기적 성질 및 안정성 (The Electrical Properties and Stability of $Pr_6$$O_{11}$-Based ZnO Varistors Doped with $Dy_2$$O_3$)

  • 남춘우;윤한수
    • 한국전기전자재료학회논문지
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    • 제13권5호
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    • pp.402-410
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    • 2000
  • The electrical properties and stability of Pr$_{6}$/O$_{11}$-based ZnO wvaristors consisting of ZnO-Pr$_{6}$/O$_{11}$-CoO-Dy$_{2}$/O$_{3}$ based ceramics were investigated in the Dy$_{2}$/O$_{3}$ additive content range o 0.0 to 2.0 mol%. The density was nearly constant 5.62 g/cm$^3$corresponding to 97% of theoretical density as Dy$_{2}$/O$_{3}$ additive content increases up to 0.5 mol%. However the density decreased as Dy$_{2}$/O sub 3/ additive content is further additive content. Pr$_{6}$/O$_{11}$-based ZnO varistors doped with 0.5mol% Dy$_{2}$/O$_{3}$ exhibited a good nonlinearity, which is 37.76 in the nonlinear exponent and 5.36 $mutextrm{A}$ in the leakage current. And they exhibited very stress (0.80 V$_{1mA}$/9$0^{\circ}C$/12h)+(0.85 V$_{1mA}$/115$^{\circ}C$/12h)+(0.95 V$_{1mA}$/1$25^{\circ}C$/12h). Consequently it was estimated that ZnO-0.5 mol% Pr$_{6}$/O$_{11}$-1.0 mol% CoO-0.5 mol% Dy$_{2}$/O$_{3}$ based ceramics will be sufficiently used as a basic composition to develop the advanced Pr$_{6}$/O$_{11}$-based ZnO varistors in the future.he future.uture.he future.

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$SrTiO_3$: $Pr^{3+}$,$Ga^{3+}$의 발광특성 (Photoluminescence of $SrTiO_3$: $Pr^{3+}$,$Ga^{3+}$)

  • 변재동;이용제;장보윤;이현덕;유영문;류선윤
    • 한국세라믹학회지
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    • 제38권8호
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    • pp.705-709
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    • 2001
  • SrTiO$_3$에 Pr$^{3+}$ 이온, 또는 Pr$^{3+}$ 이온과 Ga$^{3+}$ 이온을 첨가하여 합성한 형광체와 floating zone method로 성장시킨 단결정의 PL 특성을 조사하였다. 분말 형광체와 단결정에서 모두 Ga$^{3+}$ 이온이 함께 첨가되었을 때 적색 발광 세기가 크게 증가하였다. XRF(X-Ray Fluorescence) 측정결과 Ga$^{3+}$ 이온이 함께 첨가되었을 때 SrTiO$_3$결정 격자내의 Pr$^{3+}$ 이온의 농도가 증가하였다. Ga$^{3+}$ 이온이 함께 첨가되었을 때 적색 발광 세기가 증가하는 것은 첨가된 Ga$^{3+}$ 이온이 결정내 발광 center인 Pt$^{3+}$ 이온의 농도가 증가시켰기 때문이며, 또한 Ga$^{3+}$ 이온이 hole trap center로 작용하기 때문인 것으로 생각된다.

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자외선-C 발광 YPO4:Pr3+ 분말제조 및 YPO4:Pr3+-PVDF 전계 발광소자 특성 연구 (Fabrication of UV-C Emitting YPO4:Pr3+ Powder and Properties of YPO4:Pr3+-PVDF Electroluminescence Device)

  • 백경도;아판디 모하메드;박재홍;김종수;정용석
    • 반도체디스플레이기술학회지
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    • 제21권2호
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    • pp.15-18
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    • 2022
  • The ultraviolet-C emitting praseodymium doped yttrium phosphate (YPO4:Pr3+) powder was synthesized by conventional solid-state reaction. The electroluminescence device was fabricated by simple screen-printing method using the synthesized YPO4:Pr3+ powder, especially, polyvinylidene fluoride as an insulating layer was applied on the printed YPO4:Pr3+ powder for stable performance of the electroluminescence. The electroluminescence properties were investigated under alternating current power system of 400 Hz. The device starts to emit at 350 V, which showed the ultraviolet-C emission peaking at the 233, 245, 264, 273 nm attributed to electronic transition of the Pr3+ ions. The electroluminescence intensity was increased as increasing the operating voltage and the device revealed stable performance up to 600 V due to the polyvinylidene fluoride serve as a protective layer.

Pechini 법을 이용한 FED용 Al 및 Pr 첨가 $SrTiO_3$ 적색 형광체의 제조와 물성

  • 박정규;류호진;박희동;최승철
    • 한국결정성장학회지
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    • 제9권5호
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    • pp.480-485
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    • 1999
  • FED용의 적색 형광체로 Al과 Pr이 첨가된 $SrTiO_3$의 제조와 형광특성에 대하여 연구하였다. 이 형광체는 metallic nitrates, ethylene glycol, citric acid를 출발물질로 하여 polymeric complex를 형성하는 Pechini 법으로 합성하였다. 본 실험에서 합성된 분말의 성장기구는 $900^{\circ}C$를 경계로 서로 다른 경향을 보이고 있으며, $600^{\circ}C$의 저온에서도 $SrTiO_3$상이 형성됨을 확인하였다. 또한 빛 발광특성의 경우는 Pr 이온에 의한 359 nm에서의 여기 스펙트럼과 저전압 음극선 발광의 경우 617 nm에서 최대 피크를 갖고 575 nm와 650 nm 사이에서 적색의 발광 스펙트럼이 관찰되었다. Pechini 법으로 합성된 $SrTiO_3$:Al, Pr 형광체의 경우 FED의 적색 형광체에 적용될 수 있을 것이다.

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한국인 성씨에 따른 이하선 탕개 내 Pr,Db,Pa의 유전자빈도에 관한 연구 (A Study of Gene Frequency of Proline-rich Protein, Double-band Protein and Pa Protien in Patotic Saliva according to Family Name of Korean People)

  • Chong-Youl Kim
    • Journal of Oral Medicine and Pain
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    • 제15권1호
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    • pp.55-60
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    • 1991
  • After dividing 372 Korean people of 47 different family names into 307 people of 28 indigenous family name groups and 65 people of 19 immigrated family name groups and investigating Pr. Db, Pa gene frequency of each family name groups based on phenotype of parotid saliva character the author have got following conclusions. 1. The gene frequencies of indigenous family name groups were Pr1=0.686, Pr2=0.314, Pr gene frequencies of immigrated family name groups were Pr1=0.7, Pr2=0.3. 2. The gene frequencies of indigenous family name groups were Db==0.021, Db-=0.979, Pr gene frequencies of immigrated family name groups were Db+=0.023, Db-=0.977. 3. The gene frequencies of indigenous family name groups were Pa+=0.248, Pa-=0.752, Pr gene frequencies of immigrated family name groups were Pa+=0.206, Pa-=0.794. 4. The Pr gene frequencies of immigrated family name groups were in the middle of those of Chinese people and indigenous people groups. 5. There was no significant difference of Db gene frequencies between indigenous and immigrated family name groups. 6. Pa gene frequencies of immigrated family name groups were similar to those of Chinese people.

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넓은 수평 환형 공간에서의 중간 Prandtl수 유체의 자연 대류의 천이 (Free Convective Transition of Intermediate Prandtl-Number Fluids in a Wide-Gap Horizontal Annulus)

  • 유주식
    • 대한기계학회논문집B
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    • 제24권2호
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    • pp.169-176
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    • 2000
  • Natural convection in a wide-gap horizontal annulus is considered, and the transition of flows and the bifurcation phenomenon are investigated for the fluids with Pr=0.2 and 0.3. At Pr=0.2, a bicellular flow pattern is observed at high Rayleigh number, and the solution is unique. At Pr=0.3, both the steady unicellular and bicellular flows exist above a certain critical Rayleigh number. For the fluids of Pr=0.2, the bicellular flow can be obtained by the impulsive heating of the inner cylinder, but it is not obtained from the zero initial condition for Pr=0.3. Hysteresis phenomena have not been observed. A transition from a bicellular flow to a unicellular flow occurs for Pr=0.3.

PR Shape된 SQAM의 오율에 반송파위상오차가 미치는 영향에 대한 연구 (A Study on the PR shaped SQAM error rate with carrier phase error)

  • 박용우;이형재
    • 한국통신학회논문지
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    • 제9권1호
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    • pp.11-17
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    • 1984
  • 本論文에서는 帶域幅效率을 높이기 위해서 Partial Response Signaling(PRS)을 利用한 PR shaped된 SQAM(staggered quadrature amplitude modulation)에 대하여 硏究하였다. 硏究過程에 있어서 誤率의 上限値를 구하여 서로 比較하였으며 그 結果 誤差가 3$^{\circ}$보다 작으면(Class I, II, IV)PR 시스템을 使用目的에 따라 別差異없이 使用할 수 있지만 3以上이 되면 Class I을 使用해야 한다는 結論을 얻었다.

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Enhanced Luminescence of $SrTiO_3:Pr^{3+}$by Incorporating with $Li^+$ or $Na^+$Ion

  • Tian, Lianhua;Mho, Sun-Il;Bae, Hyun-Sook;Yu, Byung-Yong;Pyun, Chong-Hong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.819-821
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    • 2002
  • Photoluminescenc (PL) and low-voltage cathodoluminescence (CL) characteristics of $[xSrTiO_3+(1-x)Li_2TiO_3]:Pr^{3+}$ and $[xSrTiO_3+(1-x)Na_2TiO_3]:Pr^{3+}$ systems were investigated. The red luminescence intensities of these compounds are enhanced remarkably by the incorporation of $Li^+$ or $Na^+$ ion as compared to that of $SrTiO_3:Pr^{3+}$. The enhanced luminescence is speculated to result from both the charge compensation of $Pr^{3+}$ site and oxygen vacancies generated in the lattices by $Li^+$ or $Na^+$ ion.

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Infrared-to-Visible Up-conversion in Er-Pr-Yb Triply Doped Oxyfluoride Glass Ceramics

  • Song, Su-A;Lim, Ki-Soo
    • Journal of the Optical Society of Korea
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    • 제20권6호
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    • pp.778-783
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    • 2016
  • We synthesized $Er^{3+}-Yb^{3+}$, $Pr^{3+}-Yb^{3+}$, and $Er^{3+}-Pr^{3+}-Yb^{3+}$ -doped oxyfluoride glass ceramics containing $CaF_2$ nanocrystals by proper thermal treatments. Spectral characteristics of down- and up-converted emissions in three kinds of glass ceramics under 365-nm and 980-nm excitations were compared and explained by cross relaxations, excited-state absorptions, and energy-transfer processes between different ions. The huge reduction of up-conversion emission in the triply doped glass ceramics under 980-nm excitation compared to the $Er^{3+}-Yb^{3+}$ codoped one was explained by the split pump power and the direct energy transfer from $Er^{3+}$ to $Pr^{3+}$ ions. Increasing $Yb^{3+}$ concentration from 2% to 10% in the triply doped glass ceramics showed more than quadratic enhancement of the absorbed power, and we explained it by the enhanced energy-transfer efficiency from $Yb^{3+}$ to $Er^{3+}$ ions. We also observed enhanced up-converted emissions of $Er^{3+}$ and $Pr^{3+}$ ions in three kinds of glass ceramics under simultaneous excitation at 980 nm and 1550 nm, and suggested detailed up-conversion mechanisms.