• 한국세라믹학회지
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• 제30권1호
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• pp.1-6
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• 1993

Dielectric and piezoelectric porperties of pseudoternary xPb(Al2/3W1/3)O3-(1-x)Pb(Zr0.52Ti0.48)O3 (x=1~10mol%) ceramic system have been investigated as a function of the amount of PAW[Pb(Al2/3W1/3)O3] and sintered from 110$0^{\circ}C$ to 120$0^{\circ}C$ for 1hr. As the amount of PAW increases, the c/a of tetragonal structure decreases. The grain size was reduced with increasing the amount of PAW addition. However, the density, dielectric constant and electromechanical coupling factor(kp) exhibited a maximum value at the amount of 5mol% PAW addition.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2002년도 추계총회 및 연구발표회 초록집
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• pp.160.2-160
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• 2002

• 전자공학회논문지A
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• 제30A권5호
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• pp.30-35
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• 1993

We have investigated microwave dielectric properties of TiO$_{2}$ added (Pb$_{1-x}$Ca$_{x}$)ZrO$_{3}$ Ceramics with x=0.33, 0.35, and 0.37 sintered at 1400$^{\circ}C$ for 2 h. For additions of up to 3wt% of TiO$_{2}$ in (Pb$_{0.63}$ Ca$_{0.37}$)ZrO$_{3}$ (x=0.37), TiO$_{2}$ was completely soluble in (Pb, Ca)ZrO3 phase and did not affect the grain size of ceramics. Dielectric constant and temperature coefficient of resonant frequency increased due to the formation of solid solution, whereas Q value decreased linearly as TiO$_{2}$ increased up to 1 wt%. However, the dielectric loss was very high as TiO$_{2}$ exceeded 2 wt%. It was also shown that as Ca ion content in 0.5 wt% TiO$_{2}$ added (Pb$_{1-x}$,Ca$_{x}$)ZrO$_{3}$ decreased from x=0.37 to x=0.33, dielectric constant increased and Q value decreased.

• 대한전기학회논문지
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• 제45권2호
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• pp.235-241
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• 1996

In this paper dielectric and electrostrictive strain properties of (1-y-x)Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-PbTiO$_{3}$$-yPbTiO_{3}-xSrTiO_{3}[(1-y-x)PMN-yPT-xST]$ ceramics fabricated by using columbite precursor method have been investigated with the substitution of SrTiO$_{3}$(ST). Dielectric constant of the specimens increased with the increase of ST content up to 5[m/o] and decreased with further substitution of ST. And the pyrochlore phase decreased with the increase of ST content up to 5[m/o] in XRD analysis. The elimination of the pyrochlore phase improved dielectric constants. The electrostrictive strains generated by AC electric field have the highest value at 5[m/o] SrTiO$_{3}$ addition and the hysteresis of strain ranged from 12 to 20[%]. The electrostrictive strain at various temperature investigated in the temperature range of $-50[^{\circ}C]~74[^{\circ}C].$ In higher temperature than phase transition region, it showed paraelectric property which shows very small hystersis.

• 한국결정성장학회지
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• 제7권4호
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• pp.555-559
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• 1997

lead acetate, scandium acetate, niobium isopropoxide를 전구체로 사용한 솔-젤법으로 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 분말을 제조하였다. 젤 분말에 대한 결정화 거동과 상변화가 연구되었다. 솔-젤법을 이용하여 $700^{\circ}C$에서 1시간 동안 열처리를 행하여 97 % 이상의 매우 순수한 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 상을 얻을 수 있었으며 0.2 $\mu \textrm{m}$ 이하의 평균 입자 크기를 가진 매우 미세한 분말의 제조가 가능하다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.329-330
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• 2006

본연구에서는 초음파 모터 등의 고출력 액츄에이터에 응용 가능한 $0.4Pb(Ni_{1/3}Nb_{2/3})O_3$-$0.6Pb(Zr_{0.405}Ti_{0.595})O_3$ + 0.25wt% $Fe_2O_3$ 조성시스템에 $MnO_2$ (0~1 wt.%)첨가하여 압전, 유전특성 및 미세구조에 관해 고찰하였다. 본조성을 $1125{\sim}1175^{\circ}C$ 온도에서 2시간 소결하여 시편을 제조하였으며 이의 결정구조 및 미세조직을 분석하였다. $MnO_2$ 첨가량 증가에 따라 압전 상수와 전기기계결함계수는 감소하였으며, 기계적 품질계수는 0.5 wt% 첨가시까지 증가하였으나 첨가량이 그 이상 증가함에 따라 감소하였다. 압전특성은 $1125^{\circ}C$에서 소결한 $MnO_2$ 0.5wt%조성에서 ${\varepsilon}r$ = 2040, kp = 0.66, $d_{33}$ = 504, Qm=438의 우수한 특성을 나타내었다.

• 한국진공학회지
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• 제17권4호
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• pp.317-321
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• 2008

세라믹 강유전체 $0.65Pb(Mg_{1/3}Ta_{2/3})O_3-0.35PbTiO_3$ 고용체에 $ZrO_2$를 첨가하여 유전 및 초전 특성을 관찰하였다. 유전상수, 유전손실 및 초전계수의 측정온도는 상온에서 $250^{\circ}C$사이에서 측정되었다. 유전상수와 초전계수는 $0.2\;mol%ZrO_2$ 첨가에서 최대값을 얻었다. $ZrO_2$의 첨가량이 증가할수록 각 시료의 유전상수와 초전계수의 최대값은 낮은 온도로 이동하였고, 최대유전상수의 퍼짐현상은 증가하였다.

• 한국세라믹학회지
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• 제17권2호
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• pp.80-88
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• 1980

The sintering phenomena and piezoelectric properties of PZT ceramics of composition $Pb(Zr_{0.54} Ti_{0.46})O_3$ were investigated when a small quantity of $La_2O_3$ , $LaMnO_3$, $LaCrO_3$ were added. The unwanted chemical composition change in PZT during sinterin porces du to PbO evaporation poses a severe problem in PZt manufacturinig. It is observed tat an addition of small amount of $LaMnO_3$ to PZT markedly decreases the evaporation of PbO during sintering . The green compact of (1-x) PZT.xLaMnO3(x=0.02~0.10) could be sintered of under O2 atmosphere alone with no significant loss of PbO. The planar coupling factor kp of the sintered $0.98Pb(Zr_{0.54} Ti_{0.46})O_{3.0.02}LaMnO}3$ is similar to that of commercial PZT 6A. Microstructure investigation shows that part of sintering process of $Pb(Zr, Ti)O_3$.$LaMnO_3$ system progresses via liquid phase sintering. It is believed that the evaporation of PbO in PZT sintering is restricted by the addition of $LaMnO_3$ due to the above phenomena. Furthermore the solid solution of $LaMnO_3$ in PZT causes diffuses phase transition.

• 한국세라믹학회지
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• 제28권6호
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• pp.471-477
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• 1991

Effects of ZnO, PbO and SiO2 on the grain growth and magnetic properties of Sr-ferrite were investigated. (1) Addition of ZnO to Sr-ferrite increased remanence, but decreased coercivity and maximum energy product. (2) Addition of PbO up to 0.5 wt% increased (B$.$H)max of Sr-ferrite, but addition more than 0.5 wt% decreased (B$.$H)mzx (3) SiO2 addition to the 0.5 wt% PbO doped Sr-ferrite decreased remanence and increased coercivity. The coercivity increase in due to the grain refinement effect of SiO2. But addition of SiO2 more than 0.5 wt% invoked a decrease of coercivity and (B$.$H)max of Sr-ferrite due to abnormal grain growth. Sr-ferrite magnet having maximum energy product of 3.7MGOe was fabricated by using the roasting product of Pyrrhotite.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.524-525
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• 2005

The principal problems in development of dielectric paste materials for PDP(plasma display panel)are PbO free paste and low melting temperature. We prepared PbO free paste from glasses in the system $ZnO-B_2O_3-Bi_2O_3-SiO_2$, DTA, and XRD were used to characterize $ZnO-B_2O_3-Bi_2O_3-SiO$ glasses. In this present study, PbO free paste had thermal expansion of $74\times10^{-7}/^{\circ}C$, DTA transformation point of $470^{\circ}C$, and firing condition of $540^{\circ}C$, 20min.