• Title/Summary/Keyword: $O_3$ sensitivity

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Gas Sensing Properties of $MgO-Cr_2O_3-TiO_2$ Oxide ($MgO-Cr_2O_3-TiO_2$ 산화물의 가스감지 특성)

  • 양천회;홍필선;유일증;임병오
    • Journal of the Korean Society of Safety
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    • v.1 no.1
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    • pp.21-26
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    • 1986
  • Gas sensing materials for detecting inflammable gas such as alcohol, propane, acetic acid, carbon monoxide, hydrogen were developed by utiliting $MgO-Cr_2O_3-TiO_2$ system. Between 30$0^{\circ}C$ and 50$0^{\circ}C$, reversible chemisorption becomes dominant and the electrical canduction of P-type semiconductive with the gas chemisorption. The ceramic sensor exhibits a high sensitivity to particular reducing gas such as alcohol, whereas propane and butane have little effect on the resistivity. The time response of adsorption is estimated to be about 20 sec. On the other hand, the desorption process, which corresponds to oxidation due to oxygen adsorption, take more than 60 sec. Thus the ceramic sensor can be used as a alcohol sensor in an ambient aunosphere. As the oxygen concentration is increased from 0.1 to 10 precent($10^3-10^6ppm$), the resistance decreases rapidly but stabilizes at higher concentration.

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The CO Gas Sensing Properties of ZnO-WO$_3$Composite Ceramics (ZnO-WO$_3$복합체의 일산화탄소 가스 감응특성)

  • 김태원;정승우;최우성;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.401-404
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    • 1997
  • We prepared 0~20mo1% WO$_3$added ZnO composite ceramics in order to promote a CO gas sensitivity. Using SE,. we observed the microstructure of sample. The resistances of sample were measured by High Voltage Measure/source Unit in the temperature range of +5V~-5V. The measured 1000ppm CO sensitivities of pure ZnO were about 1~4.3, and the measured 1000ppm CO sensitivities of ZnO-WO$_3$composite ceramics were about 1~8.2. Therefore, the 1000ppm CO sensitivities of ZnO-WO$_3$composite ceramics were about 2 times larger than that of pure ZnO.

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Effects of Additives on Gas Sensing Properties of In2O3 Ethanol Gas Sensor (In2O3 에탄올 가스 센서의 가스 감응 특성에 미치는 첨가물 효과)

  • Choi, Dong-Han
    • Journal of Sensor Science and Technology
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    • v.23 no.3
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    • pp.192-196
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    • 2014
  • The effects of additives on gas sensing properties of $In_2O_3$ ethanol gas sensor were investigated. Gas sensors were fabricated by the painting method. The $In_2O_3-La_2O_3-Pt$ sensor heat treated $400^{\circ}C$ displayed fast response and recovery behavior with a maximum sensitivity to ethanol gas in air at an operating temperature of $300^{\circ}C$.

High $T_c$ SQUID system for biological immunoassays

  • Enpuku, K.
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.7-7
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    • 2000
  • A high $T_c$ SQUID system is developed for the application to biological immunoassay. In this application, magnetic nanoparticles are used as magnetic markers to perform immunoassay, i.e., to detect binding reaction between an antigen and its antibody. The antibody is labeled with ${\gamma}-Fe_2O_3\;(or\;Fe_3O_4)$ nanoparticles, and the binding reaction can be magnetically detected by measuring the magnetic field from the nanoparticles. Design and set up of the system is described. The system consists of (1) SQUID magnetometer or gradiometer made of 30-deg. bicrystal junctions, (2) field and compensation coils to apply the magnetic field of about 1 mT, (3) special Dewar to realize a 2 mm-distance between the SQUID and the sample, (4) two layers of cylindrical shielding to reduce the extemal magnetic noise to about 1/100, and (5) an electric slider to move the sample with a speed of 10 mm/sec. The sensitivity of the system is studied in terms of detectable magnetic flux. For the measurement bandwidth from 0.2 Hz to 10 Hz, minimum-detectable amplitude of the magnetic flux is $0.8\;m\;{\Phi}_o$ and $0.25\;m{\Phi}_o$ for the magnetometer and the gradiometer, respectively, when the magnetic field of 1 mT is applied. The difference between them is due to the residual environmental noise, and the applied magnetic field does not increase the system noise. The corresponding weight of the magnetic markers is 1 ng and 310 pg, respectively. An experiment is also conducted to measure antigen-antibody reaction with the present system. It is shown that the sensitivity of the present system is 10 times better than that of the conventional method using an optical marker. A one order of magnitude improvement of sensitivity will be realized by the sophistication of the present system.

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The Electrical and CO Gas Sensing Properties of SnO$_2$-WO$_3$Composite Ceramics (SnO$_2$-WO$_3$복합체의 전기적특성과 일산화탄소 가스 감응특성)

  • 김태원;정승우;최우성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.347-349
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    • 1997
  • In order to investigate CO sensing property of a SnO$_2$-WO$_3$composite ceramic. we prepared pure SnO$_2$and WO$_3$added SnO$_2$compostie ceramics. Using XRD and SEM, a phase analysis and microstructure were investigated. The resistances as a function of gas atmosphere were measured by High Voltage Measure/source Unit. The measured 1000ppm CO gas sensitivity of SnO$_2$-WO$_3$composite ceramics were smaller than that of pure SnO$_2$.

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Micromachined MoO3 Gas Sensor with Low Power Consumption of 0.5 Watt

  • Jang, Gun-Eik;Wu Q.H.;Liu C.C.
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.4
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    • pp.173-176
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    • 2005
  • A new $MoO_3$ based microsensor with low power consumption was presented. Typical size of sensor was 5mm in width and 8mm in length. As a sensitive electrode, $MoO_3$ was successfully fabricated by IC technology on pyrex glass of $250{\mu}m$ in thickness. After annealing at $550^{\circ}C$ for 3hrs, the film was fully crystallized and demonstrated as pure $MoO_3$ structure. The grain size of $MoO_3$ was plat like and typical size was about $1{\mu}m$. Based on the results of sensitivity measurement, $MoO_3$ microsensor shows especially high selectivity to $H_2$ reducing gas atmosphere. The applied heater power was lower than 0.5 Watt.

Calculation of the Neutron Sensitivity in Rh Self-Powered Detector

  • Lee, Wanno;Gyuseong Cho;Kim, Ho kyung;Hur, Woo-Sung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.101-106
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    • 1996
  • For the application of the neutron flux mapping, an accurate calculation of the sensitivity is required because the sensitivity is proportional to the neutron flux density. Sensitivity is defined as the current per unit length per unit neutron flux and it mainly depends on the depression factor(f), the escape probability from the emitter($\varepsilon$1) and the charge build-up factor of the insulator layer(c). A Monte Carlo simulation was accomplished to calculate the sensitivity of rhodium emitter material and alumina(Al$_2$O$_3$) insulator with a cylindrical geometry, based on the (n,${\beta}$) interaction and on other interaction including the secondary electron generation for the more accurate estimation of the sensitivity. From the simulation results, factors fur the sensitivity were accurately calculated and compared with other theoretical and experimental values. In addition, the sensitivity linearly increases and saturates as the emitter radius increases. The accomplished method is useful in the analysis for the change of SPND sensitivity as a function of burn-up and in the optimum design of SPND.

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[ SnO2 ] Gas Sensors Using LTCC (Low Temperature Co-fired Ceramics) (LTCC 를 이용한 SnO2 가스 센서)

  • Cho, Pyeong-Seok;Kang, Chong-Yun;Kim, Sun-Jung;Kim, Jin-Sang;Yoon, Seok-Jin;Hieu, Nguyen Van;Lee, Jong-Heun
    • Korean Journal of Materials Research
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    • v.18 no.2
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    • pp.69-72
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    • 2008
  • A sensor element array for combinatorial solution deposition research was fabricated using LTCC (Low-temperature Co-fired Ceramics). The designed LTCC was co-fired at $800^{\circ}C$ for 1 hour after lamination at $70^{\circ}C$ under 3000 psi for 30 minutes. $SnO_2$ sol was prepared by a hydrothermal method at $200^{\circ}C$ for 3 hours. Tin chloride and ammonium carbonate were used as raw materials and the ammonia solution was added to a Teflon jar. 20 droplets of $SnO_2$ sol were deposited onto a LTCC sensor element and this was heat treated at $600^{\circ}C$ for 5 hours. The gas sensitivity ($S\;=\;R_a/R_g$) values of the $SnO_2$ sensor and 0.04 wt% Pd-added $SnO_2$ sensor were measured. The 0.04 wt% Pd-added $SnO_2$ sensor showed higher sensitivity (S = 8.1) compared to the $SnO_2$ sensor (S = 5.95) to 200 ppm $CH_3COCH_3$ at $400^{\circ}C$.

Sensitivity Analysis of Pipeline Rehabilitation Model According to Initial Year Break Rate and Growth Rate Coefficient (초기파손율과 성장계수에 따른 상수관 개량모델의 민감도 분석)

  • Chung, Won-Sik;Kim, I-Tae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.1302-1306
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    • 2005
  • This study has Performed to develop rehabilitation model for determination of optimal rehabilitation time on the Cast Iron Pipes (CIP) with diameter less than 300 mm in water pipeline network and to analysis the sensitivity on the rehabilitation times of developed model. In the result from the application of the field, the renovation time was faster about 10 years than the replacement time. Especially, as the difference between rehabilitation and replacement time on E-CIP was about from 3 to 5 years, and it was thought that the replacement was effective on E-CIP. To sensitivity analysis, the discount rate of coefficient was fixed at 0.08, and the values of initial year break rate(N($t_o$) and growth rate coefficient(A) were adjusted in values of 0.0009, 0.0018, 0.0027, and 0.05, 0.10, 0.15 respectively. When the values of N($t_o$) and A was increased, the results from the time of rehabilitation and replacement was faster It was thought that N($t_o$), 0.018 was reliable values on the applied pipeline through the result of the study. In case of A, the values of A above 0.1 was thought to be Proper.

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$\textrm{CO}_2$ Gas Sensor Based on $\textrm{Li}_2\textrm{ZrO}_3$ System ($\textrm{Li}_2\textrm{ZrO}_3$ 계를 이용한 $\textrm{CO}_2$ 가스 센서)

  • Park, Jin-Seong;Kim, Si-Uk;Lee, Eun-Gu;Kim, Jae-Yeol;Lee, Hyeon-Gyu
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.896-899
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    • 1999
  • A carbon dioxide gas sensor was studied as a function of temperature and $CO_2$concentration in the Li$_2$ZrO$_3$ system. Lithium zirconate(Li$_2$ZrO$_3$) was synthesized by the heat-treatment of zirconia(ZrO$_2$)and Lithium carbonate(Li$_2$CO$_3$). The specimens were prepared both as bulk disk, 10mm in diameter and 1.0mm thickness, and thick films on an alumina substrate. Lithium zirconate readily responded to $CO_2$concentration from 0.1% to 100% in the range of 45$0^{\circ}C$ to $650^{\circ}C$. The sensitivity to $CO_2$ was dependent on the measuring temperature. Lithium zirconate(Li$_2$ZrO$_3$) decomposes into Li$_2$CO$_3$ and ZrO$_2$after the reaction with $CO_2$in the range of 45$0^{\circ}C$ to $650^{\circ}C$. Li$_2$CO$_3$ changes into Li$_2$O and $CO_2$ above $650^{\circ}C$. The material showed difficulty with reversibility and recovery. The optimum temperature for the highest sensitivity is around 55$0^{\circ}C$.

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