• Title/Summary/Keyword: $O_3$ destruction

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Production of Bacterial Cellulose and Its Modification (박테리아 셀룰로오스의 생산 및 개질)

  • 민두식;조남석;최태호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.3
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    • pp.26-33
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    • 1997
  • The bacterial celluloses are very different in its physical, chemical and morphological structures compared to wood cellulose. These fibers have many unique properties that are potentially and commercially beneficial. This study was aimed to elucidate the production of bacterial celluloses and to improve their physical properties by chemical pretreatment. Bacterial celluloses produced by static culture had gel-like pellicle structure. The pellicle thickness was increased with the increasing time, and its layer was about 1.8cm after one-month incubation. The pellicles extruded from the cells of Acetobacter had a non-crystalline structure during initial growing stages, gradually getting crystaliyzed with the incubation time elapse, and eventually fumed to the cellulose I crystals. Young's modulus of bacterial cellulose sheet was increased with increasing NaOH concentration, and resulted in the highest at 5% NaOH concentration. Similar results with NaClO3 pretreatment can be observed. Too concentrated alkali solutions induced the destruction of cellulose fibrils and changed the mechanical properties of the sheets. These alkaline pretreatment have removed non-cellulosic components(NCC) from the bacterial cellulose, and enhanced inter-abrillar bonding by direct close contact among cellulosic fibrils.

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Economic Effect of The Regional Fishery Product Supply Shortage - Focusing on Fisheries Risk Factors - (지역별 수산물 공급지장의 경제적 파급효과 분석 - 수산업 리스크 요인을 중심으로 -)

  • Um, Kwon-O;Lee, Mu-Hui
    • The Journal of Fisheries Business Administration
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    • v.53 no.3
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    • pp.65-83
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    • 2022
  • In addition to simply providing quality food to the people, the fishery industry must be maintained and developed because it has various functions such as national food security, preservation of natural scenery, protection of national territory, and revitalization of the local economy. However, risk factors such as climate changes and environmental destruction have raised concerns about the sustainable development of the industry. Since these risk factors are becoming larger and more complex over time, it is time to conduct research related to the risk of the fishery industry. Therefore, the purpose of this study is to explore the risk factors facing the fisheries at this point, to analyze the economic ripple effect of regional fishery product supply shortage, and to draw implications. As a result of this study, the economic ripple effect of fishery product shortage per won was highest in Busan, followed by Gangwon, Gyeongnam, and Gyeongbuk. Considering the size of the local fishery industry, Busan had the highest supply shortage per 1% of local fisheries production. It is also necessary to prepare special risk management and countermeasures for these regions since the effect of supply shortage in regions such as Jeonnam, Gyeongnam, and Jeju is large compared to other regions.

A Study of Nitrous Oxide Decomposition using Calcium Oxide (Calcium Oxide를 이용한 N2O 분해에 관한 CO2의 영향 연구)

  • Paek, Jin-Young;Park, Yeong-Sung;Shun, Dowon;Bae, Dal-Hee
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.746-751
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    • 2002
  • Fluidized bed combustion is a coal combustion technology that can reduce both SOx and NOx emission; SOx is removed by limestone that is fed into the combustion chamber and the NOx is reduced by low temperature combustion in a fluidized bed combustor and air stepping, but $N_2O$ generation is quite high. $N_2O$ is not only a greenhouse gas but also an agent of ozone destruction in the stratosphere. The calcium oxide(CaO) is known to be a catalyst of $N_2O$ decomposition. This study of $N_2O$ decomposition reaction in fixed bed reactor packed over CaO bed has been conducted. Effects of parameters such as concentration of inlet $N_2O$ gas, reaction temperature, CaO bed height and effect of $CO_2$, NO, $O_2$ gas on the decomposition reaction have been investigated. As a result of the experiment, it has been shown that $N_2O$ decomposition reaction increased with the increasing fixed bed temperature. While conversion of the reaction was decreased with increasing $CO_2$ concentration. Also, under the present of NO, the conversion of $N_2O$ decomposition is decreased. From the result of kinetic study gained the heterogeneous reaction rate on $N_2O$ decomposition. In the case of $N_2O$ decomposition over CaO, heterogeneous reaction rate is. $\frac{d[N_2O]}{dt}=\frac{3.86{\times}10^9{\exp}(-15841/R)K_{N_2O}[N_2O]}{(1+K_{N_2O}[N_2O]+K_{CO_2}[CO_2])}$. In this study, it is found that the calcium oxide is a good catalyst of $N_2O$ decomposition.

The Changes of Cyclic AMP Content by Opiates in Chronic Haloperidol Treated Mouse Striatum (Haloperidol 장기 투여된 Mouse Striatum에서 cAMP양에 미치는 Opiates의 영향)

  • Kim, Soo-Kyung
    • The Korean Journal of Pharmacology
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    • v.30 no.1
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    • pp.11-18
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    • 1994
  • Cyclic adenosine 3'5'-monophosphate (cyclic AMP) has been frequently accepted as an intracellular messenger for receptor-mediated action of opioids. In this experiment, it was designed to determine the interaction of dopaminergic and opioidergic system in the mouse striatum in normal and chronic haloperidol treated groups. Haloperidol 750ug/kg I.P. for 10 days was performed for dopamine denervation. The morphine, DAGO, DPDPE, and U5O,488H inhibited the increase of haloperidol-induced cyclic AMP content in chronic haloperidol treated mouse striatum. The inhibition of DAGO and DPDPE showed significant increase compared to normal mouse striatum. Naloxone showed antagonistic effect on the morphine and U5O,488H in chronic haloperidol treated group, and showed antagonistic effect on morphine, DAGO, DPDPE, and U5O, 488H in normal mouse striatum. These findings support that there is a functional interrelationship of dopaminergic and opioidergic pathway in the striatum. This result provides an evidence that following destruction of striatal dopaminergic neuron, there are some changes of cAMP content on the ${\mu},\;{\gamma},\;and\;{\kappa}$ opioid receptor, but the ${\kappa}$ opioid receptor still has its function.

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Electrochemical Reduction of Perchlorate Ion on Porous Carbon Electrodes Deposited with Iron Nanoparticles (영가철 나노 입자가 전착된 다공성 탄소전극을 이용한 과염소산 이온의 전기화학적 환원)

  • Rhee, Insook;Kim, Eun Yong;Lee, Bokyoung;Paeng, Ki-Jung
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.81-85
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    • 2015
  • A method for degradation of the perchlorate anion ($ClO{_4}^-$) has been studied using electrochemically generated zero-valent iron (ZVI) deposited on a porous carbon electrode. The first strategy of this study is to produce the ZVI via the electrochemical reduction of iron (II) on a porous carbon electrode coated with a conducting polymer, instead of employing expensive $NaBH_4$. The present method produced well distributed ZVI on conducting polymer (polypyrrole thin film) and increased surface area. ZVI surface can be regenerated easily for successive reduction. The second strategy is to apply a mild reducing condition (-0.3 V) to enhance the efficiency of the degradation of perchlorate with ZVI without the evolution of hydrogen. The electrochemically generated ZVI nanoparticles may offer an alternative means for the complete destruction perchlorate without evolution of hydrogen in water with high efficiency and at low cost.

금속유물의 부식화합물(I)-철제유물을 중심으로

  • Lee, O-Hui
    • 보존과학연구
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    • s.6
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    • pp.48-57
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    • 1985
  • This report described the corrosion structure of excavated iron artifacts in terms of simple model based on the knowledge of the corrosion process. (Fig.1)(Table 1,2)In storing the objects, there are basically three ways in which they either break in wedges, flakes and dish-shaped flakes. Completely mineralized objects or those with only a small iron core tend to break into wedges and more solid objects either split small dish-shaped flakes or large flat ones.(Fig. 2,3,4)There are two ways, therefore, to prevent this from happening. One is to keep the artifacts rigorously dried in Silica-gel, never allowing the relative humidity to rise. This is feasible which the artifacts are in store but causes great difficulty if they are wanted for museum display. Because they still contain $ FeCl _2$ they are always at risk ; they contain the seeds of their own destruction. The other alternative is to use of washing process to dissolve out the $ FeCl _2$. In this connection, many different methods to stabilize the artifact have been employed; boiling iron in frequent changes of water, soaking in Na-sesquicarbonate solution, soaking in alkaline Na-sulphite solution. In this report, introduced the alkaline sulphite method by the N.A. North and C.Pearson.Finally, Let me extend my thanks to Ancient Monument Lab., Museum of London Conservation Lab., British Museum Conservation Div. and National Maritime Museum Conservation Lab. who have helped me and made many valuable suggestions.

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An Effects of $CO_2$ Addition on Flame Structure in a Non-premixed Counterflow Flame (비예혼합 대향류 화염에서 $CO_2$ 첨가가 화염 구조에 미치는 영향 연구)

  • Lee, Kee-Man
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.166-173
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    • 2007
  • A numerical study was conducted to have the effect of $CO_2$ addition to fuel on the chemical reaction mechanism with the change of the initial concentration of $CO_2$ and the axial velocity gradient. From this study, it was found that there were two serious effects of $CO_2$ addition on a non-premixed flame ; a diluent effect by the reactive species reduction and chemical effect of the breakdown of $CO_2$ by the third-body collision and thermal dissociation. Especially, the chemical effect was serious at the lower velocity gradient of the axial flow. It was certain that the mole fraction profile of $CO_2$ was deflected and CO was increased with the initial concentration of $CO_2$. It was also ascertained that the breakdown of $CO_2$ would cause the increasing of CO mole fraction at the reaction region. It was also found that the addition of $CO_2$ did not alter the basic skeleton of $H_2-O_2$ reaction mechanism, but contributed to the formation and destruction of hydrocarbon products such as HCO. The conversion of CO was also suppressed and $CO_2$ played a role of a dilution in the reaction zone at the higher axial velocity gradient.

The Characterization of Surface Ozone Concentrations in Seoul, Koera

  • Heo, Jeong-Sook;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E3
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    • pp.129-142
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    • 2002
  • This paper provides a long-term perspective for ozone concentrations at 20 national air quality monitoring sites in Seoul from 1989 to 1998, which were managed by the Korean Ministry of Environment. Ozone episodes occurred more frequently in the east areas (Bangi, Guui, Seongsu, and Ssangmun) than in the west area (Guro and Oryu). When an ozone episode happened, hourly ozone concentrations over 80 ppb continued for an average of 4.0 hours at all sites. Annual variations in daily mean and maximum oBone concentrations showed broadly consistent upward trends at Ssangmun and Gwanaksan. Monthly mean ozone concentrations were the highest from May to June and the 99$^{th}$ and 95$^{th}$ percentile levels appeared higher during June, July, and August. The diurnal patterns of hourly mean ozone levels in urban areas showed typical photochemical formation and destruction, while the flat diurnal shape before 1996 at Gwanaksan indicated few significant photochemical reactions due to a lack of precursors of ozone. The occurrence of ozone over 80 ppb was ascribed to meteorological conditions such as high temperature, strong solar radiation, low relative humidity, and low wind speed with winds most frequently in a westerly direction.

Ginsenoside Rg3 from Red Ginseng Prevents Damage of Neuronal Cells through the Phosphorylation of the Cell Survival Protein Akt

  • Joo, Seong-Soo;Won, Tae-Joon;Lee, Yong-Jin;Hwang, Kwang-Woo;Lee, Seon-Gu;Yoo, Yeong-Min;Lee, Do-Ik
    • Food Science and Biotechnology
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    • v.15 no.2
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    • pp.244-247
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    • 2006
  • Neuronal cell death significantly contributes to neuronal loss in neurological injury and disease. Typically, neuronal loss or destruction upon exposure to neurotoxins, oxidative stress, or DNA damage causes neurodegenerative diseases such as Alzheimer's disease. In this study, we attempted to determine whether ginsenoside Rg3 from red ginseng has a neuroprotective effect via an anti-apoptotic role induced by S-nitroso-N-acetylpenicillamine (SNAP) at the molecular level. We also investigated the antioxidant effect of Rg3 using a metal-catalyzed reaction with $Cu^{2+}/H_2O_2$. Our results showed that Rg3 ($40-100\;{\mu}g/mL$) protected SK-N-MC neuroblastoma cells under cytotoxic conditions and effectively protected DNA from fragmentation. In the signal pathway, caspase-3, and poly (ADP-ribose) polymerase (PARP) were kept at an inactivated status when pretreated with Rg3 in all ranges. In particular, the important upstream p-Akt signal pathway was increased in a dose-dependent manner, which indicates that Rg3 may contribute to cell survival. We also found that oxidative stress can be mitigated by Rg3. Therefore, we have concluded that Rg3 plays a certain role in neurodegenerative pathogenesis via an anti apoptotic, antioxidative effect.

Respiration of Fresh Sweet Persimmon and Its Use for Packaging Film Selection (온도조건에 따른 단감의 호흡특성 및 포장재 조건 선정)

  • Kim, Hwan-Ki;Kim, Hae-Jin;An, Duck-Soon;Ahn, Gwang-Hwan;Lee, Dong-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.15 no.2
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    • pp.43-47
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    • 2009
  • Respiration and quality of persimmon fruits were monitored through the storage at 0, 5, 15 and $25^{\circ}C$. Respiration rate data at different temperatures were used for determining the $O_2$ and $CO_2$ permeabilities required to maintain the optimal package atmosphere (1~3% $O_2$, 4~7% $CO_2$). The estimated gas permeabilities were then compared to those of available plastic films for examining their potential application at various temperature conditions. $O_2$ consumption and $CO_2$ production were at similar order and leveled at stable value after initial time span with higher rates measured at higher temperatures. Major quality indexes during storage were observed to be ascorbic acid content change and firmness destruction with the most significant changes at $25^{\circ}C$ Higher $O_2$ and $CO_2$ permeabilites were required at higher temperatures, and common plastic films were shown to be unable to satisfy those requirements. Films or devices of high permeation property such as silicone rubber or microporous film may be combined to increase the permeation properties satisfying the required high gas permeabilities.

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