• 제목/요약/키워드: $O_3$ destruction

검색결과 129건 처리시간 0.02초

박테리아 셀룰로오스의 생산 및 개질 (Production of Bacterial Cellulose and Its Modification)

  • 민두식;조남석;최태호
    • 펄프종이기술
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    • 제29권3호
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    • pp.26-33
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    • 1997
  • The bacterial celluloses are very different in its physical, chemical and morphological structures compared to wood cellulose. These fibers have many unique properties that are potentially and commercially beneficial. This study was aimed to elucidate the production of bacterial celluloses and to improve their physical properties by chemical pretreatment. Bacterial celluloses produced by static culture had gel-like pellicle structure. The pellicle thickness was increased with the increasing time, and its layer was about 1.8cm after one-month incubation. The pellicles extruded from the cells of Acetobacter had a non-crystalline structure during initial growing stages, gradually getting crystaliyzed with the incubation time elapse, and eventually fumed to the cellulose I crystals. Young's modulus of bacterial cellulose sheet was increased with increasing NaOH concentration, and resulted in the highest at 5% NaOH concentration. Similar results with NaClO3 pretreatment can be observed. Too concentrated alkali solutions induced the destruction of cellulose fibrils and changed the mechanical properties of the sheets. These alkaline pretreatment have removed non-cellulosic components(NCC) from the bacterial cellulose, and enhanced inter-abrillar bonding by direct close contact among cellulosic fibrils.

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지역별 수산물 공급지장의 경제적 파급효과 분석 - 수산업 리스크 요인을 중심으로 - (Economic Effect of The Regional Fishery Product Supply Shortage - Focusing on Fisheries Risk Factors -)

  • 엄권오;이무희
    • 수산경영론집
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    • 제53권3호
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    • pp.65-83
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    • 2022
  • In addition to simply providing quality food to the people, the fishery industry must be maintained and developed because it has various functions such as national food security, preservation of natural scenery, protection of national territory, and revitalization of the local economy. However, risk factors such as climate changes and environmental destruction have raised concerns about the sustainable development of the industry. Since these risk factors are becoming larger and more complex over time, it is time to conduct research related to the risk of the fishery industry. Therefore, the purpose of this study is to explore the risk factors facing the fisheries at this point, to analyze the economic ripple effect of regional fishery product supply shortage, and to draw implications. As a result of this study, the economic ripple effect of fishery product shortage per won was highest in Busan, followed by Gangwon, Gyeongnam, and Gyeongbuk. Considering the size of the local fishery industry, Busan had the highest supply shortage per 1% of local fisheries production. It is also necessary to prepare special risk management and countermeasures for these regions since the effect of supply shortage in regions such as Jeonnam, Gyeongnam, and Jeju is large compared to other regions.

Calcium Oxide를 이용한 N2O 분해에 관한 CO2의 영향 연구 (A Study of Nitrous Oxide Decomposition using Calcium Oxide)

  • 백진영;박영성;선도원;배달희
    • Korean Chemical Engineering Research
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    • 제40권6호
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    • pp.746-751
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    • 2002
  • 석탄 연소기술에서 타 연소로에 비해서 유동층 연소는 황산화물과 질소산화물 배출을 줄이는 기술이다. 석회석의 소성으로 생성되는 CaO에 의한 황산화물의 제거와 저온 연소와 공기 다단계 주입에 의한 NOx를 줄일 수 있다는 것이 유동층 연소로의 큰 장점이지만, 상대적으로 $N_2O$의 배출은 매우 높다. $N_2O$는 지구온난화 가스일 뿐만 아니라 성층권내의 오존층을 파괴하는 물질이기도 하다. CaO는 $N_2O$ 분해를 위한 촉매 물질로 알려져 있다. 본 연구는 CaO를 충진시킨 고정층 반응기에서 CaO에 의한 $N_2O$의 분해특성에 관하여 수행하였으며, 유동층 연소온도와 가스조성에서 온도변화에 대한 $N_2O$의 분해특성, CaO 충진량의 변화와 $CO_2$, NO, $O_2$ 농도변화에 따른 $N_2O$ 분해특성에 관하여 수행하였다. 또한 실험 결과로부터 CaO표면에서 $N_2O$분해반응에 대한 반응속도식을 나타낼 수 있었다. 결과로서 온도가 증가함에 따라 $N_2O$ 분해반응이 증가하였으며, $CO_2$의 농도를 변화시킬 경우 $CO_2$ 농도가 증가할수록 $N_2O$ 분해반응이 감소하였다. NO 존재시와 비교하였을 때 $N_2O$의 분해반응이 감소함을 알 수 있었다. 반응속도론적으로 해석한 결과 $CO_2$ 농도에 대한 $N_2O$ 분해반응의 반응속도식을 다음과 같이 나타내었다. 본 연구 결과 CaO는 $N_2O$분해 반응에서 좋은 촉매 기능을 지니고 있음을 알 수 있었다. $\frac{d[N_2O]}{dt}=\frac{3.86{\times}10^9{\exp}(-15841/R)K_{N_2O}[N_2O]}{(1+K_{N_2O}[N_2O]+K_{CO_2}[CO_2])}$

Haloperidol 장기 투여된 Mouse Striatum에서 cAMP양에 미치는 Opiates의 영향 (The Changes of Cyclic AMP Content by Opiates in Chronic Haloperidol Treated Mouse Striatum)

  • 김수경
    • 대한약리학회지
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    • 제30권1호
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    • pp.11-18
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    • 1994
  • Opioid수용체는 adenylate cyclase의 활성을 억제하므로써 cyclic AMP의 양을 감소시킨다. 본 연구에서는 striatum에서 dopamine과 opioid 신경전달계의 상호관계를 알아보고자 haloperidol(750ug/kg)을 10일간 복강내 투여하여 dopaminergic pathway를 차단시킨후 mouse striatum에서 선택적 opioid ${\mu},\;{\gamma}\;{\kappa}$ 수용체 agonist들에 의해 축적되는 cAMP양을 측정하여 본 결과, haloperidol단독투여에 의해서 cAMP는 유의한 증가를 나타내었으며, haloperidol 장기투여된 mouse striatum 에서 morphine(20mg/kg), DAGO(5Oug/kg), DPDPE(50ug/kg), U5O,488H (500ug/kg)투여에 의해서 haloperidol에 의한 cAMP 증가는 억제되었으며, 정상 mouse에 투여된 morphine, DAGO, DPDPE, U5O,488H에 비해서는 DAGO, DPDPE 투여군에서 증가를 나타내었다. Haloperidol장기투여로 인한 morphine, DAGO, DPDPE, U5O,488H의 영향은 naloxone에 의해서 morphine과 U5O, 488H투여군에서 길항되었으며 정상 mouse에 투여된 morphine, DAGO, DPDPE, U5O,488H에 의한 cAMP의 감소는 naloxone에 의하여 모든 실험군에서 길항되었다. 이상의 결과로 보아 dopaminergic denervation시 mouse striatum에서 ${\mu},\;{\gamma},\;{\kappa}$효현제에 의하여 축적되는 cAMP양은 ${\kappa}$수용체 효현제인 U5O,488H에서 가장 현저한 감소를 보여 각 수용체의 활성화정도는 변화되며, 그중에서 ${\kappa}$수용체는 그 기능이 가장 보존되고 있음을 알 수 있었다.

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영가철 나노 입자가 전착된 다공성 탄소전극을 이용한 과염소산 이온의 전기화학적 환원 (Electrochemical Reduction of Perchlorate Ion on Porous Carbon Electrodes Deposited with Iron Nanoparticles)

  • 이인숙;김은영;이보경;팽기정
    • 전기화학회지
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    • 제18권2호
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    • pp.81-85
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    • 2015
  • A method for degradation of the perchlorate anion ($ClO{_4}^-$) has been studied using electrochemically generated zero-valent iron (ZVI) deposited on a porous carbon electrode. The first strategy of this study is to produce the ZVI via the electrochemical reduction of iron (II) on a porous carbon electrode coated with a conducting polymer, instead of employing expensive $NaBH_4$. The present method produced well distributed ZVI on conducting polymer (polypyrrole thin film) and increased surface area. ZVI surface can be regenerated easily for successive reduction. The second strategy is to apply a mild reducing condition (-0.3 V) to enhance the efficiency of the degradation of perchlorate with ZVI without the evolution of hydrogen. The electrochemically generated ZVI nanoparticles may offer an alternative means for the complete destruction perchlorate without evolution of hydrogen in water with high efficiency and at low cost.

금속유물의 부식화합물(I)-철제유물을 중심으로

  • 이오희
    • 보존과학연구
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    • 통권6호
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    • pp.48-57
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    • 1985
  • This report described the corrosion structure of excavated iron artifacts in terms of simple model based on the knowledge of the corrosion process. (Fig.1)(Table 1,2)In storing the objects, there are basically three ways in which they either break in wedges, flakes and dish-shaped flakes. Completely mineralized objects or those with only a small iron core tend to break into wedges and more solid objects either split small dish-shaped flakes or large flat ones.(Fig. 2,3,4)There are two ways, therefore, to prevent this from happening. One is to keep the artifacts rigorously dried in Silica-gel, never allowing the relative humidity to rise. This is feasible which the artifacts are in store but causes great difficulty if they are wanted for museum display. Because they still contain $ FeCl _2$ they are always at risk ; they contain the seeds of their own destruction. The other alternative is to use of washing process to dissolve out the $ FeCl _2$. In this connection, many different methods to stabilize the artifact have been employed; boiling iron in frequent changes of water, soaking in Na-sesquicarbonate solution, soaking in alkaline Na-sulphite solution. In this report, introduced the alkaline sulphite method by the N.A. North and C.Pearson.Finally, Let me extend my thanks to Ancient Monument Lab., Museum of London Conservation Lab., British Museum Conservation Div. and National Maritime Museum Conservation Lab. who have helped me and made many valuable suggestions.

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비예혼합 대향류 화염에서 $CO_2$ 첨가가 화염 구조에 미치는 영향 연구 (An Effects of $CO_2$ Addition on Flame Structure in a Non-premixed Counterflow Flame)

  • 이기만
    • 한국자동차공학회논문집
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    • 제15권3호
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    • pp.166-173
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    • 2007
  • A numerical study was conducted to have the effect of $CO_2$ addition to fuel on the chemical reaction mechanism with the change of the initial concentration of $CO_2$ and the axial velocity gradient. From this study, it was found that there were two serious effects of $CO_2$ addition on a non-premixed flame ; a diluent effect by the reactive species reduction and chemical effect of the breakdown of $CO_2$ by the third-body collision and thermal dissociation. Especially, the chemical effect was serious at the lower velocity gradient of the axial flow. It was certain that the mole fraction profile of $CO_2$ was deflected and CO was increased with the initial concentration of $CO_2$. It was also ascertained that the breakdown of $CO_2$ would cause the increasing of CO mole fraction at the reaction region. It was also found that the addition of $CO_2$ did not alter the basic skeleton of $H_2-O_2$ reaction mechanism, but contributed to the formation and destruction of hydrocarbon products such as HCO. The conversion of CO was also suppressed and $CO_2$ played a role of a dilution in the reaction zone at the higher axial velocity gradient.

The Characterization of Surface Ozone Concentrations in Seoul, Koera

  • Heo, Jeong-Sook;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E3호
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    • pp.129-142
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    • 2002
  • This paper provides a long-term perspective for ozone concentrations at 20 national air quality monitoring sites in Seoul from 1989 to 1998, which were managed by the Korean Ministry of Environment. Ozone episodes occurred more frequently in the east areas (Bangi, Guui, Seongsu, and Ssangmun) than in the west area (Guro and Oryu). When an ozone episode happened, hourly ozone concentrations over 80 ppb continued for an average of 4.0 hours at all sites. Annual variations in daily mean and maximum oBone concentrations showed broadly consistent upward trends at Ssangmun and Gwanaksan. Monthly mean ozone concentrations were the highest from May to June and the 99$^{th}$ and 95$^{th}$ percentile levels appeared higher during June, July, and August. The diurnal patterns of hourly mean ozone levels in urban areas showed typical photochemical formation and destruction, while the flat diurnal shape before 1996 at Gwanaksan indicated few significant photochemical reactions due to a lack of precursors of ozone. The occurrence of ozone over 80 ppb was ascribed to meteorological conditions such as high temperature, strong solar radiation, low relative humidity, and low wind speed with winds most frequently in a westerly direction.

Ginsenoside Rg3 from Red Ginseng Prevents Damage of Neuronal Cells through the Phosphorylation of the Cell Survival Protein Akt

  • Joo, Seong-Soo;Won, Tae-Joon;Lee, Yong-Jin;Hwang, Kwang-Woo;Lee, Seon-Gu;Yoo, Yeong-Min;Lee, Do-Ik
    • Food Science and Biotechnology
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    • 제15권2호
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    • pp.244-247
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    • 2006
  • Neuronal cell death significantly contributes to neuronal loss in neurological injury and disease. Typically, neuronal loss or destruction upon exposure to neurotoxins, oxidative stress, or DNA damage causes neurodegenerative diseases such as Alzheimer's disease. In this study, we attempted to determine whether ginsenoside Rg3 from red ginseng has a neuroprotective effect via an anti-apoptotic role induced by S-nitroso-N-acetylpenicillamine (SNAP) at the molecular level. We also investigated the antioxidant effect of Rg3 using a metal-catalyzed reaction with $Cu^{2+}/H_2O_2$. Our results showed that Rg3 ($40-100\;{\mu}g/mL$) protected SK-N-MC neuroblastoma cells under cytotoxic conditions and effectively protected DNA from fragmentation. In the signal pathway, caspase-3, and poly (ADP-ribose) polymerase (PARP) were kept at an inactivated status when pretreated with Rg3 in all ranges. In particular, the important upstream p-Akt signal pathway was increased in a dose-dependent manner, which indicates that Rg3 may contribute to cell survival. We also found that oxidative stress can be mitigated by Rg3. Therefore, we have concluded that Rg3 plays a certain role in neurodegenerative pathogenesis via an anti apoptotic, antioxidative effect.

온도조건에 따른 단감의 호흡특성 및 포장재 조건 선정 (Respiration of Fresh Sweet Persimmon and Its Use for Packaging Film Selection)

  • 김환기;김해진;안덕순;안광환;이동선
    • 한국포장학회지
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    • 제15권2호
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    • pp.43-47
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    • 2009
  • 0, 5, 15, $25^{\circ}C$의 네 온도에서 단감의 경시적 호흡과 품질변화를 측정하고, 호흡률로부터 최적포장 기체조성을 유지할 수 있는 산소 및 이산화탄소 투과도의 범위를 계산하고 이용가능한 플라스틱 필름의 기체투과도 값과 대비하여 다양한 온도조건에서 적응할 수 있는 포장필름의 요건을 검토하였다. $O_2$ 소비와 $CO_2$ 생산은 온도에 따라 크게 증가하였고 서로간에 거의 비슷한 수준을 유지하였고, 초기를 지나면서 일정한 수준을 나타내었다. 저장 중 주요 품질 변화로는 ascorbic acid 함량변화와 경도 감소가 두드러졌으며, $25^{\circ}C$에서가 다른 온도에 비하여 현저하였다. 온도가 높을수록 요구되는 $O_2$$CO_2$ 투과도는 증가하였고, 보편적인 플라스틱 필름은 요구수준의 기체투과도를 제공하기에 부족하였다. 여러 온도 조건에서 적용될 수 있는 포장조건을 만족시키기 위해서는 silicone rubber나 미세공성 필름과 같은 고투과성 필름이나 도구의 결합적 설계가 필요한 것으로 평가되었다.

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