• 제목/요약/키워드: $O_3$ Generation

검색결과 993건 처리시간 0.027초

HPLC-ICPMS를 이용한 셀레늄 화학종의 연구에서 화학적 및 광화학적 수소화물 발생법의 비교 (Comparison of chemical and photochemical generation of hydrides in Se speciation study with HPLC-HG-ICPMS)

  • 지하나;박용남
    • 분석과학
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    • 제25권6호
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    • pp.339-344
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    • 2012
  • In this research, hydride generation in HPLC-ICPMS for the selenium speciation was investigated. Chemical and photochemical vapor generation techniques were compared for the effective generation of selenium vapour. $HBr/KBrO_3$ was used for the chemical reduction and a UV lamp was used for the photochemical reduction. It was found out that the photochemical reduction was more effective than the chemical reduction in all of selenium species studied. The optimum conditions for the generation of vapour are 0.4% KI, 2.5% $NaBH_4$, and 1.0 M HCl. The enhancement factor using a photochemical hydride generation was from 6.3 to 16.7 times for inorganic and organic selenium species.

A Simpler Algorithm of Generation Biconnected Rooted Outerplanar Graphs

  • Zhuang, Bingbing
    • 한국정보과학회:학술대회논문집
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    • 한국정보과학회 2011년도 한국컴퓨터종합학술대회논문집 Vol.38 No.1(B)
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    • pp.488-491
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    • 2011
  • For given g ${\geq}$ 3, this paper provides an O(1) time and O(n) space complexity algorithm for generation of biconnected rooted colored outerplanar graphs with face size bound g, where the graphs generated contain at most n vertices. The vertices are colored in such a way that each color has a corresponding degree bound. There is also a face size bound for each inner face of the graph. No duplications or isomorphic copies of a same graph are generated.

자기 온열 시스템의 열 발생 효율에 관한 실험적 연구 (The Experimental Study of Heat Generation Efficiency of Magnetic Hyperthermia System)

  • 송영진;오정환
    • 한국연소학회지
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    • 제16권2호
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    • pp.33-39
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    • 2011
  • We demonstrated heat generation efficiency of the magnetic hyperthermia system to find optimal condition using gelatin tissue phantom. Magnetic hyperthermia induction can be used to make heat generation with different concentration of $Fe_3O_4$ iron oxide inside tissue phantom and magnetically labeled cells by applying AC magntic field at a frequency of 145 kHz. It was observed that the maximum temperature achieved in the magnetic gelatin tissue phantom increased with the concentration of $Fe_3O_4$ iron oxide and alternating magnetic field intensity. Results were discussed with respect to further optimization of therapeutic technique for biomedical application with modified functional nanoparticles.

거세미나방류의 생태 및 방제에 관한 연구 (Studies on Bionomics and Control of Cutworms)

  • 김홍선;김석환;최궤문
    • 한국응용곤충학회지
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    • 제19권4호
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    • pp.243-248
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    • 1980
  • 가, 숯검은밤나방은 1회 발생으로 9월하순이 최성기였고 짐거세미나방 및 거세미나방은 년 $2\~3$회 발생으로 1화 6월중순, 2화기 8월중순, 3화기 9월하순에 최성기를 보였다. 나, 거세미나방류의 각태별 기간은 숯검은나방은 난기간 6.3일 유충기간 327.1, 용기간 25.1, 성충기간 6.5로 유충기간이 길었고 검거세미나방은 난기간 4.2일, 유충기간 29.6일, 용기간 17.5일, 성충기간 5.2일 이었고 거세미나방은 난기간 5.6일, 유충기간 38.2일, 용기간 27.3일, 성충기간 5.7일이었다. 다, 거세미나방류는 배추의 잎이 축 늘어진 잎 뒷면에 산란하였다. 라. 거세미나방 유충의 토중 잠토 시기는 3령이후였다. 마, 거세미나방류의 천적으로는 고치별 1종과 맵시벌 2종이 발견되었다. 바, 거세미나방류의 방제약제로는 모캡 및 보라톤이 효과적이었으나 보라톤은 작물체에 직접 닿으면 약해가 유발되므로 세심한 주의를 요한다.

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Analysis of critical fluid velocity and heat transfer in temperature-dependent nanocomposite pipes conveying nanofluid subjected to heat generation, conduction, convection and magnetic field

  • Fakhar, Mohammad Hosein;Fakhar, Ahmad;Tabatabaei, Hamidreza
    • Steel and Composite Structures
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    • 제30권3호
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    • pp.281-292
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    • 2019
  • In this paper, analysis of critical fluid velocity and heat transfer in the nanocomposite pipes conveying nanofluid is presented. The pipe is reinforced by carbon nanotubes (CNTs) and the fluid is mixed by $AL_2O_3$ nanoparticles. The material properties of the nanocomposite pipe and nanofluid are considered temperature-dependent and the structure is subjected to magnetic field. The forces of fluid viscosity and turbulent pressure are obtained using momentum equations of fluid. Based on energy balance, the convection of inner and outer fluids, conduction of pipe and heat generation are considered. For mathematical modeling of the nanocomposite pipes, the first order shear deformation theory (FSDT) and energy method are used. Utilizing the Lagrange method, the coupled pipe-nanofluid motion equations are derived. Applying a semi-analytical method, the motion equations are solved for obtaining the critical fluid velocity and critical Reynolds and Nusselt numbers. The effects of CNTs volume percent, $AL_2O_3$ nanoparticles volume percent, length to radius ratio of the pipe and shell surface roughness were shown on the critical fluid velocity, critical Reynolds and Nusselt numbers. The results are validated with other published work which shows the accuracy of obtained results of this work. Numerical results indicate that for heat generation of $Q=10MW/m^3$, adding 6% $AL_2O_3$ nanoparticles to the fluid increases 20% the critical fluid velocity and 15% the Nusselt number which can be useful for heat exchangers.

순산소 순환유동층에서 로내 탈황 및 탈질법 적용에 따른 오염물질 거동특성 (Pollutants Behavior in Oxy-CFBC by Application of In-Furnace deSOx/deNOx Method)

  • 최경구;나건수;신지훈;길상인;이정규;허필우;윤진한
    • 청정기술
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    • 제24권3호
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    • pp.212-220
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    • 2018
  • 순산소 연소기술은 화력발전에 적용 가능한 유망한 온실가스 감축 기술로 평가되고 있다. 본 연구는 환경적 관점에서 순환유동층을 활용한 순산소 연소조건에 로 내 탈황 및 탈질법을 적용하여 NO 및 $SO_2$의 거동을 살펴보는 한편, $SO_3$, $NH_3$, 그리고 $N_2O$의 발생 경향도 관측하였다. 이를 위해, 연소로 내 석회석 및 요소수를 투입하였다. 로 내 탈황법은 연소가스 내 $SO_2$ 농도를 ~403에서 ~41 ppm까지 저감하였다. 또한 $SO_3$ 형성의 주원료인 $SO_2$가 저감되면서 연소가스 내 $SO_3$ 농도도 ~3.9에서 ~1.4 ppm까지 감소되었다. 그러나 석회석 내 $CaCO_3$가 NO의 발생을 촉진하는 현상도 관측되었다. 연소가스 내 NO 농도는로 내 탈질법을 적용하여 ~26 - 34 ppm까지 저감되었다. 요소수 투입량 증가에 따라 연소가스 내 $NH_3$ 농도가 증가하여 최대 ~1.8 ppm으로 나타났으며, $N_2O$의 농도도 ~61에서 ~156 ppm까지 증가하였다. $N_2O$ 발생량 증가 현상은 요소수의 열분해 과정에서 생성된 HNCO가 $N_2O$로 전환되어 나타난다. 본 연구의 결과를 통해 로 내 연소가스 세정법을 적용할 경우 $NO_x$$SO_x$의 저감뿐만 아니라, 다른 오염물질의 발생에 대한 주의가 필요할 것으로 보인다.

Effect of annealing temperature on the electrical characteristics of P-doped ZnO thin films

  • Kim, Jun-Kwan;Lim, Jung-Wook;Kim, Hyun-Tak;Kim, Sang-Hun;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1622-1624
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    • 2007
  • In order to realize effective p-type doping in ZnO thin films, ZnO films were deposited on P-doped Silayers by RF-magnetron sputter deposition technique and annealed at various temperatures. The result indicated that ZnO film annealed at $700^{\circ}C$ showed p-type conduction with a high carrier concentration in the order of $10^{19}\;cm^{-3}$.

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에너지 발생소자응용을 위한 수열합성법기반 ZnO 나노로드/Polystylene 하이브리드 나노구조 제조 (Fabrication of ZnO Nanorod/polystyrene Nanosphere Hybrid Nanostructures by Hydrothermal Method for Energy Generation Applications)

  • 백성호;박일규
    • 한국분말재료학회지
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    • 제22권6호
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    • pp.391-395
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    • 2015
  • We report on the successful fabrication of ZnO nanorod (NR)/polystyrene (PS) nanosphere hybrid nanostructure by combining drop coating and hydrothermal methods. Especially, by adopting an atomic layer deposition method for seed layer formation, very uniform ZnO NR structure is grown on the complicated PS surfaces. By using zinc nitrate hexahydrate $[Zn(NO_3)_2{\cdot}6H_2O]$ and hexamine $[(CH_2)_6N_4]$ as sources for Zn and O in hydrothermal process, hexagonal shaped single crystal ZnO NRs are synthesized without dissolution of PS in hydrothermal solution. X-ray diffraction results show that the ZnO NRs are grown along c-axis with single crystalline structure and there is no trace of impurities or unintentionally formed intermetallic compounds. Photoluminescence spectrum measured at room temperature for the ZnO NRs on flat Si and PS show typical two emission bands, which are corresponding to the band-edge and deep level emissions in ZnO crystal. Based on these structural and optical investigations, we confirm that the ZnO NRs can be grown well even on the complicated PS surface morphology to form the chestnut-shaped hybrid nanostructures for the energy generation and storage applications.

The interfaces between Alq3 and ZnO substrates with various orientations

  • 이정한;이연진
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.343-343
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    • 2011
  • ZnO has been introduced as one of the good candidates for next generation opto-electronics. Recently, ZnO is known to be suitable for the transparent electrode in organic solar cells and light emitting devices. The contact with n-type organic material has been studied due to the n-type properties of ZnO. However, the surface of ZnO has shown different electronic property with respect to its surface orientation. Therefore, it is presumed that there are differences in the interfacial electronic structures between organic materials and ZnO with different orientation. Therefore, it is required to classify the interfacial electronic structures according to the surface orientation of ZnO. In this study, we measured the interfacial electronic structures between the ZnO substrate having various orientations and a typical n-type organic material, tris-(8-hydroxyquinoline) aluminum (Alq3). In-situ x-ray and ultraviolet photoelectron spectroscopy measurements revealed the interfacial electronic structures. We found the changes in the electronic structures with respect to the orientation of ZnO substrate and it could be used to improve the contact between ZnO and Alq3.

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NiFe2O4를 이용한 열화학 사이클 H2 제조 (Thermal Behavior of NiFe2O4 for Hydrogen Generation)

  • 한상범;강태범;주오심;정광덕
    • 한국수소및신에너지학회논문집
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    • 제14권4호
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    • pp.298-304
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    • 2003
  • The thermal behavior of $NiFe_2O_4$ prepared by a solid-state reaction was investigated for $H_2$ generation by the thermochemical cycle. The reduction of $NiFe_2O_4$ started from $800^{\circ}C$, and the weight loss was 0.2-0.3 wt% up to $1000^{\circ}C$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidation of reduced $NiFe_2O_4$. The crystal structure of $NiFe_2O_4$ maintained during the redox reaction of 5 cycles. From this observation, the lattice oxygen in $NiFe_2O_4$ is released without the structural change during the thermal reduction and oxygen deficient $NiFe_2O_4$ can be restored to the spinel structure of $NiFe_2O_4$.