• Title/Summary/Keyword: $O_3$ Generation

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Determination of photorefrative constants in LiNbO$_3$ using second harmonic generation (제2고조파발생을 이용한 LiNbO$_3$의 중요 광굴절상수측정)

  • 김봉기;이범구
    • Korean Journal of Optics and Photonics
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    • v.12 no.3
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    • pp.230-234
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    • 2001
  • We report a simple method for determining photovoltaic constant and conductivities of any photorefractive crytals which have no inversion symmetry by utilizing the electric field dependence of non-phase-matched second harmonic generation. New theoretical expression for the electric field dependence of Maker fringes is derived and space charge field can be determined using this from the observed change of intensity of second harmonic wave. The photovoltaic constant, dark conductivity and photoconductivity are easily deduced from an analysis of the measured relaxation behavior of space-charge field at two different light intensities. We demonstrate this method for $LiNbO_3$ at 514.5 nm.4.5 nm.

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Abnormal Grain Growth in Ferrites (페라이트 이상 입성장)

  • Shigeru Ito
    • Resources Recycling
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    • v.9 no.5
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    • pp.16-21
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    • 2000
  • Generation of abnormally large grains in the microstructure of small grains has been investigated on some ferrites. Some fractions of large grains were observed in the microstructue of sintered ZnFe$_2$O$_4$, Mn-ZnFe$_2$O$_4$, Fe$_3$O$_4$(in $N_2$) and MnFe$_2$O$_4$(in air). On the other hand, the large grains were not observed in $NiFe_2$$O_4$ and $CoFe_2$$O_4$, independent of calcining and sintering conditions. The large grains seem to be generated in such ferrites that are easy to very their compositions or valencies at high temperatures. as the sintering proceeded, the number of large grains was increasing to from a continuous structure consisting of large grains, while the size of large grains did not increase remarkably. In addition, the growth of small grains was also very slow during the generation of the large grains. The large grains appeared be suddenly generated after some induction periods. Avrami equation could be applied to the relation between net volume of large grains and sintering time. Thus, the grain boundaries may be strongly stabilized when the large grains are generated. The large grain is generated y the local activation of the stabilized rain boundaries, which is caused by the variation of composition or valencies during sintering. It is concluded that the essence of the abnormal gain growth is not the generation of abnormally large grains, but the abnormal stabilization and the local activation of he grain boundaries.

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Protective Effects of Ukyium(우귀음, Yougui-yin) in Zinc-induced Apoptosis of C6 Glial Cells (우귀음이 Zinc에 의한 신경교세포의 고사(Apoptosis)에 미치는 영향)

  • 이영구;문병순
    • The Journal of Korean Medicine
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    • v.22 no.3
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    • pp.63-73
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    • 2001
  • Objectives : The objective of the current study is to determine the protective effect of Ukyium(Yougui-yin) on the apoptosis induced by zinc. Methods : Zinc is known to generate reactive oxygen species (ROS), including superoxide anion ($O_2$) and hydrogen peroxide ($H_2O_2$), which eventually contribute to cytotoxicity in a variety of cell types. We investigated the viablity of cells, $H_2O_2$ generation, chromatin condensation and nuclear fragmentation in Hoechst dye staining and $IkB-{\alpha}$ degradation in C6 glial cells of $ZnCl_2$ between pretreatment- and not pretreatment-group with Ukyium. The former methods were researched by Time- and Dose-dependent manners. Results : We demonstrated that pretreatment with Ukyium prevented zinc-induced cell death of C6 glial cells and apoptotic characteristics including chromatin condensation and nuclear fragmentation. Ukyium also prevented $H_2O_2-induced$ cell death. We further confirmed that Ukyium decreased zinc-induced generation of $H_2O_2$ and inhibited degradation of $IkB-{\alpha}$ by zinc in C6 glial ceHs. Conclusions : These data indicated that Ukyium (Yougui-yin) prevents zinc-induced apoptotic death of C6 glial cells via inhibition of ROS generation, such as $H_2O_2$ as well as inhibition of $IkB-{\alpha}$ degradation.

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Recent Progress in Dielectric Materials for MLCC Application (MLCC용 유전체 소재의 연구개발 동향)

  • Seo, Intae;Kang, Hyung-Won;Han, Seung Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.2
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    • pp.103-118
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    • 2022
  • With the recent increase in demand for electronic devices, multi-layer ceramic capacitors (MLCCs) have become the most important core component. In particular, the next-generation MLCC with extremely high reliability is required for the 4th industrial revolution and electric vehicle applications. Therefore, it is necessary to develop dielectric ceramic materials with high dielectric properties and reliability. During the decades, electrical properties of BaTiO3 based dielectric ceramics, which have been widely used in MLCC industrial field, have been improved by microstructure and defect chemistry control. However, electrical properties of BaTiO3 have reached their limits, and new types of dielectric materials have been widely studied. Based on these backgrounds, this report presents the recent development trends of BaTiO3-based dielectric materials for the next-generation MLCCs, and suggests promising candidates to replace BaTiO3 ceramics.

Studies on the Immuno Modulating Acitivity of Fermented Artemisiae Argyi Folium Extract (애엽(艾葉) 발효 추출물의 면역활성에 관한 연구)

  • Han, Hyo-Sang;Park, Wan-Su;Lee, Young-Jong
    • The Korea Journal of Herbology
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    • v.23 no.3
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    • pp.103-112
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    • 2008
  • Objectives : This research aimed to study the cytotoxicity and immuno modulating activity of fermented Artemisia argyi Lev. et Vant.(Compositae). Methods : Effect of fermented Artemisiae Argyi Folium extracts, which were fermented by Sacchromyces cerevisiae STV89(AFS), on cell viability, generation of ROS within cells, generation of NO and the level of cytokines($TNF-{\alpha}$ and IL-6) was measured using mouse macrophage RAW 264.7 cell. Results : 1. Result of MTT assay conducted to verify the cytotoxicity of fermented Artemisiae argyi folium extract illustrated that, when fermented Artemisiae argyi folium extract was processed for each concentration, there was no excessive induction of cytoxicity in the RAW 264.7 cell. 2. Fermented Artemisiae Argyi Folium extract increased the generation of H2O2 within RAW 264.7 cell as well as significantly increased inhibition of generation of H2O2 in macrophage induced by LPS. 3. Fermented Artemisiae Argyi Folium extract inhibited generation of NO in RAW 264.7 cell, and significantly inhibited increase in generation of NO of macrophage induced by LPS. 4. Fermented Artemisiae Argyi Folium extract, AFS has significantly reduced the increase in the generation of $TNF-{\alpha}$ above 10 ${\mu}g/mL$. 5. Fermented Artemisiae Argyi Folium extract, AFS has significantly reduced the increase in generation of IL-6 above 50 ${\mu}g/mL$. Conclusions : AFS fermented extract produced from Artemisiae Argyi Flium, have increased generation of ROS and reduced generation of NO in RAW 264.7 cell without excessively inducing cytotoxicity of RAW 264.7 cell. In addition, they displayed significant immuno modulating activities including inhibition of generation of $TNF-{\alpha}$ and IL-6 in macrophage, induced by LPS.

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Crystal Growth and Second Harmonic Generation of YCa$_4$O$({BO_3})_3$ (YCa$_4$O$({BO_3})_3$ 단결정 성장 및 2차고조파 발생)

  • Yu, Young-Moon;A. Ageyev;Jeong, Suk-Jong
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.88-89
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    • 2000
  • The properties for self-frequency doubling (SFD) is unique phenomena for a small number of special single crystals. It is known that there are serious limitations to vary the concentration of active ions, for example high doping of active ions from 1 to 50 atomic %, in nonlinear materials. Until now, the Nd:YAl$_3$(BO$_3$)$_4$ (YAB) and Nd:(Ce,Gd)Sc$_3$(BO$_3$)$_4$ (CSB) crystals with high doping rates are well studied for the application of SFD purpose. They have much useful SFD properties, but also have big problems in crystal growth. In case of YAB crystal, it can be grown by solution melt method with very low growth rates and easy occurrence of inclusions. In case of CSB crystal, it has optically heterogeneity problems because of disarrangement of ions in huntite structure [1]. These problems make above crystals not so attractive for optical applications. Some popular nonlinear materials, such as LiNbO$_3$(LN), KTiOPO$_4$(KTP), LiB$_3$O$_{5}$ (LBO) crystals, are impossible to substitute by Rare Earth activators because of their crystallo-chemical problems of structure. When we dope active ions with the requisite concentrations for laser generation, it results in decreasing of optical quality of crystals or destroying of acentrosymmetric structure. (omitted)d)

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Study on the Ozone Generation and Decomposition of Trichloroethylene Using Dielectric Ball Materials filled Barrier Discharge (유전체 볼 충진 배리어 방전을 이용한 오존 생성 및 TCE 분해처리에 관한 연구)

  • Han, Sang-Bo
    • Journal of IKEEE
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    • v.23 no.2
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    • pp.431-437
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    • 2019
  • This work was carried out ozone generation and TCE decomposition characteristics using dielectric ball materials filled barrier discharge reactor and catalyst's reactor for ozone decomposition. Ozone concentration generated from $Al_2O_3$ or $TiO_2$ filled barrier discharge reactor was so high compared with non-filled discharge reactor. This reactor is good discharge structure for generating the high ozone concentration. In addition, TCE decomposition rate and COx conversion rate increased using $MnO_2$ filled discharge reactor, because ozone was decomposed at the same discharge space on the surface of $MnO_2$ catalysts. To identify the $MnO_2$ catalytic effects, TCE decomposition rate reached to 100[%] by the decomposition of ozone at $MnO_2$ catalyst's reactor by the arrangement of $Al_2O_3$ filled discharge reactor and $MnO_2$ catalyst reactor. Finally, $MnO_2$ catalyst is good materials for the decomposition of ozone and this process will be useful for decomposing VOCs such as TCE.

The influence of $O_2$ concentration on the generation of $NO_2$ by using the wire-plate reactor (선대 평판형 반응기에서 $NO_2$ 생성에 미치는 $O_2$의 영향)

  • Park, Jae-Youn;Kim, Sung-Jin;Kim, Jong-Dal;Lee, Sun-Jae;Ha, Sang-Tae;Han, Sang-Bo;Lee, Dong-Hoon
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2050-2052
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    • 2000
  • In this paper, the effect of $O_2$ concentration on NO removal and $NO_2$ generation by corona discharge from simulated flue gas was measured and estimated for the wire-plate reactor. $NO_2$ removal rate was 0$\sim$30[%] under about 3.4[%] of oxygen concentration, however, it was difficult to remove NOx over 3.4[%] of oxygen concentration. It may be due to generate $NO_2$ from $N_2$ and $O_2$ molecules and converse NO to $NO_2$ by 0 and $O_3$. Magnetic field applied to electric field in plasma was very effective for NOx removal under 2[%] of $O_2$ concentration.

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The Design of Oxide Module for High Temperature Thermoelectric Power Generation (고온 발전용 산화물 열전모듈의 설계)

  • Park, Jong-Won;Yoon, Sun-Ho;Cha, Jeong-Eui;Choi, Seung-Chul
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.93-100
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    • 2008
  • The one and two pair of oxide modules for high temperature thermoelectric power generation were fabricated with $Ca_{2.7}Bi_{0.3}Co_4O_9$(p-type) and $Ca_{0.96}Bi_{0.04}Mn_{0.96}Nb_{0.04}O_3$(n-type) on $Al_2O_3$ substrate. For the optimizing of the design process, contact resistance was derived from the results of the one pair modules, and then the resistance of two pair modules were calculated to use the derived data. Those values were compared with the measured values for the optimizing of this design process. The resistance of calculated and measured two pairs modules was 0.956 $\Omega$ and 1.110 Q $\Omega$ $T_h$=833 K, respectively, the difference of resistance was about 0.15 $\Omega$. From the result, proposed design process is effective for high temperature thermoelectric oxide modules fabrication.

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Discharge Area Characteristics of Ozonizer with $Al_2O_3$ Dielectric ($Al_2O_3$ 세라믹 유전체 오존발생기의 방전면적 특성)

  • Park, Hyun-Mi;Song, Hyun-Jig;Lee, Sang-Gun;Lim, Chang-Ho;Yoon, Bung-Han;Kim, Jong-Hyun;Lee, Kwang-Sik
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2214-2216
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    • 2005
  • This paper is researched discharge and ozone generation characteristics of ozonizer using $Al_2O_3$ Ceramic dielectric. The discharge characteristics with variation of the discharge electrode area is studied. The characteristics of ozone concentration. ozone generation and ozone yield were measured to discharge power, discharge electrode area and supplied gas flux for oxygen and air. The solubility of ozone for water concentrations and ozone generations proportional to discharge power and discharge electrode area. Ozone yield has slowly increase with Increasing discharge power at high flow-rate. As the result, the maximum values of ozone characteristics ozone generation and ozone yield, can be obtained 5817[ppm] and 36[g/kWh]. We make enough the ozone concentration as the air in the home. An electric discharge electrode area is apt to shrink gradually into a miniaturization trend of the ozonizer but the enlargement of the occurrence flight of the electric discharge area gives the characteristic enhance the aid in the identity condition through the structure improvement.

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