• 제목/요약/키워드: $O_2$ partial pressure

검색결과 488건 처리시간 0.024초

Effect of the oxygen flow ratio on the structural and electrical properties of indium zinc tin oxide (IZTO) films prepared by pulsed DC magnetron sputtering

  • Son, Dong-Jin;Nam, Eun-Kyoung;Jung, Dong-Geun;Ko, Yoon-Duk;Choi, Byung-Hyun;Kim, Young-Sung
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.168-168
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    • 2010
  • Transparent conduction oxides (TCOs) films is extensively reported for optoelectronic devices application such as touch panels, solar cells, liquid crystal displays (LCDs), and organic light emitting diodes(OLEDs). Among the many TCO film, indium tin oxide(ITO) is in great demand due to the growth of flat panel display industry. However, indium is not only high cost but also its deposits dwindling. Therefore, many studies are being done on the transparent conductive oxides(TCOs). We fabricated a target of IZTO(In2O3:ZnO:SnO2=70:15:15 wt.%) reduced indium. Then, IZTO thin films were deposited on glass substrates by pulsed DC magnetron sputtering with various oxygen flow ratio. The substrate temperature was fixed at the room temperature. We investigated the electrical, optical, structural properties of IZTO thin films. The electrical properties of IZTO thin films were dependent on the oxygen partial pressure. As a result, the most excellent properties of IZTO thin films were obtained at the 3% of oxygen flow rate with the low resistivity of $7.236{\times}10^{-4}{\Omega}cm$. And also the optical properties of IZTO thin films were shown the good transmittance over 80%. These IZTO thin films were used to fabricated organic light emitting diodes(OLEDs) as anode and the device performances studied. The OLED with an IZTO anode deposited at optimized deposition condition showed good brightness properties. Therefore, IZTO has utility value of TCO electrode although it reduced indium and we expect it is possible for the IZTO to apply to flexible display due to the low processing temperature.

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Methemoglobinemia caused by a low dose of prilocaine during general anesthesia

  • Shibuya, Makiko;Hojo, Takayuki;Hase, Yuri;Kimura, Yukifumi;Fujisawa, Toshiaki
    • Journal of Dental Anesthesia and Pain Medicine
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    • 제21권4호
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    • pp.357-361
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    • 2021
  • Methemoglobinemia is a blood disorder in which an abnormal amount of methemoglobin is produced, and prilocaine is one of the drugs that can cause this disorder. The maximum recommended dose of prilocaine is 8 mg/kg. We report a case of methemoglobinemia caused by the administration of 4.2 mg/kg of prilocaine without other methemoglobinemia-inducing drugs during general anesthesia. A 17-year-old girl with hyperthyroidism and anemia was scheduled to undergo maxillary sinus floor elevation and tooth extraction. The patient's peripheral oxygen saturation (SpO2) decreased from 100% at arrival to 95% after receiving prilocaine with felypressin following induction of general anesthesia. However, the fraction of inspired oxygen was 0.6. Blood gas analysis showed that the methemoglobin level was 3.8% (normal level, 1%-2%), fractional oxygen saturation was 93.9%, partial pressure of oxygen was 327 mmHg, and arterial oxygen saturation was 97.6%. After administration of 1 mg/kg of methylene blue, her SpO2 improved gradually to 99%, and the methemoglobin value decreased to 1.2%. When using prilocaine as a local anesthetic, it is important to be aware that methemoglobinemia may occur even at doses much lower than the maximum recommended dose.

니켈기 합금 Alloy 617의 950℃ 대기/헬륨 분위기에서 산화거동 고찰 (Investigation of Oxidation Behavior of Alloy 617 under Air/Helium Environments at 950℃)

  • 정수진;이경근;김동진
    • Corrosion Science and Technology
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    • 제17권5호
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    • pp.218-224
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    • 2018
  • Alloy 617 is a candidate Ni-based superalloy for intermediate heat exchanger (IHX) of a high-temperature gas reactor (VHTR), because of its good creep strength and corrosion resistance at high temperature. Small amount of impurities such as $H_2O$, $H_2$, CO and $CH_4$ are introduced inevitably in helium, as a coolant during operation of a VHTR. Reactions of material and impurities are accelerated with increase of temperature to $950^{\circ}C$ of operating temperature of a VHTR, leading to material corrosion aggravation. In this circumstance, high-temperature corrosion tests were performed at $950^{\circ}C$ in air and impure helium environments, up to 250 hours in this study. Oxidation rate of $950^{\circ}C$ in an air environment was higher than that of impure helium, explained by difference in outer oxide morphology and microstructure as a function of oxygen partial pressure. An equiaxed Cr-rich surface oxide layer was formed in an air environment, and a columnar Cr-rich oxide was formed in an impure helium environment.

GaAs/Ge/Si 구조를 위하여 PAE법을 이용한 Si 기판위에 Ge결정성장 (Ge Crystal Growth on Si Substrate for GaAs/Ge/Si Structure by Plasma-Asisted Epitaxy)

  • 박상준;박명기;최시영
    • 대한전자공학회논문지
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    • 제26권11호
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    • pp.1672-1678
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    • 1989
  • Major problems preventing the device-quality GaAs/Si heterostructure are the lattice mismatch of about 4% and difference in thermal expansion coefficient by a factor of 2.64 between Si and GaAs. Ge is a good candidate for the buffer layer because its lattice parameter and thermal expansion coefficient are almost the same as those of GaAs. As a first step toward developing heterostructure such as GaAs/Ge/Si entirely by a home-built PAE (plasma-assisted epitaxy), Ge films have been deposited on p-type Si (100)substrate by the plasma assisted evaporation of solid Ge source. The characteristics of these Ge/Si heterostructure were determined by X-ray diffraction, SEM and Auge electron spectroscope. PAE system has been successfully applied to quality-good Ge layer on Si substrate at relatively low temperature. Furthermore, this system can remove the native oxide(SiO2) on Si substrate with in-situ cleaning procedure. Ge layer grown on Si substrate by PAE at substrate temperature of 450\ulcorner in hydrogen partial pressure of 10mTorr was expected with a good buffer layer for GaAs/Ge/Si heterostructure.

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Annealing condition dependence of the superconducting property and the pseudo-gap in the protect-annealed electron-doped cuprates

  • Jung, Woobeen;Song, Dongjoon;Cho, Su Hyun;Kim, Changyoung;Park, Seung Ryong
    • 한국초전도ㆍ저온공학회논문지
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    • 제18권2호
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    • pp.14-17
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    • 2016
  • Annealing as-grown electron-doped cuprates under a low oxygen-partial-pressure condition is a necessary step to achieve superconductivity. It has been recently found that the so-called protect annealing results in much better superconducting properties in terms of the superconducting transition temperature and volume fraction. In this article, we report on angle-resolved photoemission spectroscopy studies of a protect-annealed electron-doped cuprate $Pr_{0.9}La_{1.0}Ce_{0.1}CuO_4$ on annealing condition dependent superconducting and pseudo-gap properties. Remarkably, we found that the one showing a better superconducting property possesses almost no pseudo-gap while others have strong pseudo-gap feature due to an anti-ferromagnetic order.

크라프크 펄프 표백의 과산화수소 표백시 첨가제의 이용 (Use of Additive in Peroxide Bleaching with Unbleached Kraft Pulp)

  • 김용식;김세종;윤병호
    • 펄프종이기술
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    • 제32권1호
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    • pp.78-85
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    • 2000
  • Due to environmental proessures there is increasing use of hydrogen peroxide as a total or partial substitute for chlorine based bleaching agents within ECF or TCF sequences. However, to aceive satifactory brightness using peroxide alone, stages having a combination of high temperature, pressure, pH or residence time are required. It may also have negative impact on fiber quality . Therefore, it would be of advantage if vertain means could be found to make hydrogen peroxide more effective in bleacing , via shortening treaction time and allevaiating the need for such forcing reaction conditions. This can be achieve by converting the peroxide in-situ to stronger oxidant through the use of 손 bleach activator. In this study to investigate the influence of additives, such as tetraacetylethylenediamine (TAED) and Molybdate (MO) . addition on peroxide bleaching were carried out. Under alkaline conditions the bleching additives. TAED and Mo. can react H2O2 to form peracetic acid and peroxomolybdate respectively and these generated activators can improve deliginification,. The activators make it possible to bleach the pulp efficiently at low temperature in the range 50 to 7$0^{\circ}C$. Also, addition of TAED and Mo is an environmentally friendly way of enhancing the performance of peroxide bleaching can be incorporated into TCF and ECF sequences.

PMDA/MDA-Phenylene diamine 계열의 공중합체막에서의 산소, 질소 투과 특성의 정성적 고찰 (A Qualitive Research of N2, O2 Permeation Property in PMDA/ MDA- Phenylene Diamine Copolyimide)

  • 이경록;나성순;김종표;민병렬
    • 공업화학
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    • 제9권1호
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    • pp.13-19
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    • 1998
  • Pyromellitic dianhydride(PMDA)와 methylenedianiline(MDA)을 기본으로 하고 이에 meta-phenylendiamine(MPD), para-phenylendiamine(PPD), 2,4,6-trimethyl-1,3-phenylenediamine(TriMeMPD)을 첨가하여 열적 이미드화법으로 서로 다른 화학적 구조를 갖는 폴리이미드 공중합체막을 합성하여 제조된 막들의 물성치들을 측정하고, 산소와 질소의 투과 특성을 막의 물성과 관련시켜 정성적으로 고찰하였다. PMDA-MDA막을 기준으로 PPD, MPD의 첨가는 막의 밀도를 증가시켰고, 이에 따라 막의 자유용적과 d-spacing 값의 감소를 나타내어 산소, 질소의 투과량을 감소시켰으며, TriMeMPD의 첨가는 반대의 경향을 나타내었다. 따라서 d-spacing값과 자유용적은 질소, 산소의 투과특성과 정성적 상관성을 가짐을 알 수 있었다. 모든 막에서 압력에 상관없이 투과 계수는 거의 일정한 값을 나타내었고, 막의 기체 투과계수가 증가하면 산소/질소의 이상분리인자는 감소하였다. 온도가 증가하면 투과량도 증가하였으며 이상분리인자는 감소하였으며, 질소 투과량의 상승비가 산소보다 더 크게 나타났다.

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개심수술후 혈량 증가를 위한 10% Pentastarch와 5% Albumin 용액의 비교연구 (10% Pentastarch Versus 5% Albumin Solution for Volume Expansion Following Cariopulmonary Bypass in Patients Undergoing Open Heart Surgery)

  • 장병철
    • Journal of Chest Surgery
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    • 제27권3호
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    • pp.177-186
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    • 1994
  • Pentastarch is a hydroxyethyl starch similar to hetastarch, but lower average molecular weight and fewer hydroxyethyl groups which result in enhanced enzymatic hydrolysis and faster renal elimination.This report was performed to compare the clinical efficacy and safety of 10 % pentastarch[Pentaspan , group I] for plasma volume expansion after open heart surgery with that of 5% albumin[Plasmanate, group II]. There were no statistically significant differences between the group I [n=18] and group II [n:19] in the preoperative parameters [age, sex, body weight] and operative parameters[bypass time, aorta cross clamping time]. During the first 24 hours after arrival of the patient in the surgical intensive care unit, colloid solution [500--1000 ml] was infused to maintain left atrial pressure of more than 8 mmHg, or cardiac index of 2.0 L/min/M2 of more. In results, there were 3 complications of hypotension immediately after infusion of 5 % albumin solution and 2 among the 3 patients were excluded for the study. However there was no complication after infusion of 10 % pentastarch solution. Hemodynamic responses to infusion was similar for both groups, although in group I a greater increase in both left atrial pressure[mean 1.8 versus 0.7 mmHg, p< 0.05] and right atrial pressure [mean 2.2 versus 1.7 mmHg, p < 0.05] was observed during infusion of the first 500 ml. There were no significant differences in any of the measured respiratory parameters[PaO2, intrapulmonary shunt, and effective lung compliance]. Homodilution with colloid significantly reduced hemoglobin [mean 1.2 versus 0.8 gm/dl], and serum protein and albumin level[total protein;4.8$\pm$ 0.5 versus 5.2 $\pm$0.5 gm/dl, p < 0.05: albumin: 3.2 $\pm$0.4 versus 3.6 $\pm$0.6 gm/dl, p < 0.05] by 6:00 AM on 1 day postoperatively, however there were no significant differences on 7 day postoperatively. The mean serum colloid osmotic pressure and osmolarity was similar in both group.There were no abnormal findings of liver function and kidney function in all the patients. There were no significant between-group differences in bleeding time, platelets, prothrombin time, activated partial thromboplastin time and amount of chest tube output measured on 1st and 7th postoperative day. These findings demonstrated that 10% pentastarch is more effective and safe for plasma volume expension than 5 % albumin solution with no adverse effects on coagulation. Also 10 % pentastarch is less expensive than 5 % albumin and it would appeare to be a reasonable first choice for plasma volume expansion.

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Sol-gel 법에 의한 고온 초전도체 $YBa_2Cu_3O_{7-{\sigma}}$ 선재 합성에 관한 연구 (High Tc Superconductor Fiber $YBa_2Cu_3O_{7-{\sigma}}$ Synthesized by the Sol-gel Process)

  • 최진호;유종석;김배환;홍승태
    • 대한화학회지
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    • 제33권3호
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    • pp.326-331
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    • 1989
  • Sol-gel법으로 고온 초전도체인 $YBa_2Cu_3O_{7-{\sigma}}$의 세선을 제작하였다. Y, Ba, Cu 질산염을 1:2:3의 몰비로 수용액을 제조한 후 구연산 수용액을 첨가하고, 암모니아 수용액을 첨가하여 pH를 $5.8{\sim}6.2$로 조절함으로써 균일한 colloid sol을 제조할 수 있었다. 이를 358K 로 가열하면 점차 점도가 증가하면서 gel화 반응이 진행되고 이 gel화 반응이 완결되기 전에 구연산염 precursor gel fiber를 임의의 길이 및 두께로 뽑을 수 있었다. 이 precursor를 1223K, $Po_2$=1atm. 하에서 8시간 열처리한 후 723K로 서냉하고 13시간 동안 annealing 하여 약 95K에서 전기저항이 급격히 감소($T_c$, onset), 약 82K에서는 저항 0($T_c$, offset)을 나타내었고 액체질소 비등점에서 Meissner-effect를 보임으로써 초전도체 임을 확인하였다.

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산소분압(酸素分壓)에 따른 Carboxyhemoglobin의 해리양상(解離樣相) -성인혈(成人血)과 태아혈(胎兒血)의 비교(比較)- (Carboxyhemoglobin Dissociation at the Various Partial Pressures of Oxygen -Comparison between Adult and Fetal Bloods-)

  • 박병주
    • Journal of Preventive Medicine and Public Health
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    • 제15권1호
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    • pp.145-151
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    • 1982
  • 산모(産母)와 태아(胎兒)에서의 CO 배출양상(排出樣相)의 차이(差異)가 hemoglobin의 CO와의 결합력(結合力)의 차이(差異)에서 기인(起因)된 것인지의 여부(與否)를 산소분압(酸素分壓)에 따른 HbCO의 해리양상(解離樣相)으로써 규명(糾明)하고 이를 토대(土臺)로 임신부(姙娠婦) 및 영아가 CO에 중독(中毒)되었을 때의 적절(適切)한 산소치료방식(酸素治療方式)을 모색(模索)하고자 본(本) 실험(實驗)을 실시(實施)하여 다음과 같은 성적(成績)을 얻었다. 1. 성인혈(成人血)과 태아혈(胎兒血)의 total hemoglobin량(量)은 각각(各各) $16.1{\pm}0.50gm%,\;15.7{\pm}0.32gm%$였으며 fetal hemoglobin 비율(比率)은 각각(各各) $1.2{\pm}0.15%,\;72.7{\pm}3.01%$ 였다. 2. 성인혈(成人血)과 태아혈(胎兒血)을 100% HbCO로 포화(飽和)시킨 뒤 일반대기(一般大氣), 100% $O_2$, 3기압산소(氣壓酸素)에 30분간(分間) 폭로(曝露)시킨 직후(直後)의 혈중(血中) HbCO 포화도(飽和度)는 성인혈(成人血)에서 각각(各各) 96.7%, 70.9% 및 52.8%였으며 태아혈(胎兒血)에서 각각(各各) 98.5%, 76.1% 및 62.2%로 감소(減少)하여 3기압산소(氣壓酸素)에서 가장 현저(顯著)한 감소(減少)를 보여 HbCO의 해리(解離)는 산소분압(酸素分壓)에 비례(比例)함이 확인(確認)되었으며 또 전(全) 실험군(實驗群)에서 성인혈(成人血)보다 태아혈(胎兒血)의 HbCO 해리(解離)가 늦은 양상(樣相)을 보였다. 3. 실험군(實驗群)에 대(對)한 각(各) 산소분압별(酸素分壓別) 폭로(曝露)가 끝난 후(後) $36.5^{\circ}C$의 일반대기하(一般大氣下)에서 시간경과(時間經過)에 따른 성인혈(成人血)과 태아혈중(胎兒血中) HbCO의 해리양상(解離樣相)은 거의 비슷하게 완만(緩慢)하였다. 4. 이상(以上)의 소견(所見)으로 미루어 볼 때 임신부(姙娠婦)의 CO 중독(中毒)은 산모(産母)보다 태아(胎兒)에서 더 큰 위해(危害)를 초래(招來)할 가능성(可能性)이 크며 또 HbF의 구성점유율(構成占有率)이 높은 6개월(個月) 이하(以下)의 영아에서도 그 위해도(危害度)가 클 것으로 간주(看做)된다. 따라서 임신부(姙娠婦) 또는 생후(生後) 6개월(個月) 이하(以下)의 영아가 CO 중독(中毒)되었을 때는 고압산소요법(高壓酸素療法)이 효과적(效果的)인 치료법(治療法)으로 보이며 그 치료시간(治療時間)을 성인환자(成人患者)에 있어서의 그것보다 좀 더 길게하는 것이 CO 중독(中毒)에 의한 위해(危害)를 감소(減少)시켜 줄 것으로 기대(期待) 된다.

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