• 한국분무공학회지
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• 제6권3호
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• pp.1-7
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• 2001

In this study, quantitative measurement of nitric oxide concentration distributions visualization were investigated in the laminar $CH_4/O_2N_2$ nixed flame by Planar laser-induced fluorescence(PLIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and $O_2$ fluorescence. The measurements were taken in $CH_4/O_2N_2$ premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flow rate of 3slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to MO formation in $CH_4/O_2N_2$ premixed flame. Furthermore, this trend was well matched with previous works.

• 한국물환경학회지
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• 제22권4호
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• pp.585-589
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• 2006

Comparison between photocatalysis and sonophotocatalysis were performed in lab-scale experiments for the treatment of benomyl. The effect of operational parameters, i.e., initial benomyl concentration, $TiO_2$ concentration, $H_2O_2$ concentration on the degradation rate of aqueous solution of benomyl has been examined. The optimal conditions for photocatalysis and sonophotocatalysis processes were determined: initial Benomyl concentration was 3 mg/L, the concentration of $TiO_2$ was 2 g/L and $H_2O_2$concentration was 1.5 mM. Under the optimal conditions, sonophotocatalysis was effective for inducing faster degradation of the benomyl.

• 대한환경공학회지
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• 제27권10호
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• pp.1108-1113
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• 2005

본 연구는 1,4-dioxane을 함유한 폐수를 $O_3/H_2O_2$ 고급산화공정에서 1,4-dioxane의 제거율 및 생물학적분해 가능성을 실험하였다. 산화공정에 사용한 반응기는 bubble column 형태이며, 초기 pH 및 과산화수소의 초기농도를 달리하여 14-dioxane의 제거특성을 실험하였다. $H_2O_2$의 초기농도는 $40{\sim}120\;mg/L$로 조절하였으며, 초기 pH는 6과 9로 조절하여 산화반응에 의한 1,4-dioxane의 제거율 및 $BOD_5$, TOC 등을 분석하였다. 실험 결과 동일한 초기 pH에서 $H_2O_2$의 초기농도가 높을수록 1,4-dioxane의 제거율은 증가하였다. 오존의 소비량과 과산화수소의 초기농도 사이에는 직선적인 제거율을 나타내었으며, 이러한 이유는 높은 초기 $H_2O_2$ 농도에서 hydroxyl radical($OH{\cdot}$) 및 hydroperoxy ions(${HO_2}^-$)의 생성을 가속화 시킨 것에 기인한다고 판단되었다. $O_3/H_2O_2$ 고급산화공정에서 과산화수소의 초기농도는 1,4-dioxane의 제거와 생물학적 분해가능성을 높이는 것으로 관찰되었다.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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• pp.321-335
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• 1999

Erbium(Er) doped LiNbO3(Er:LiNbO3) single crystal gibers were grown free of cracks along the c-axis by micro-pulling down method. the Er3+ concentration was distributed homogeneously along the growth axis. The samples for optical characterization were cut from as-grown single crystal fibers and polished. When the 980 nm light was incident on the sample, upconversion phenomena were observed at the green range of wavelength 510~570 nm. In addition, the intensity of upconversion was remarkably increased by increasing the concentration of Er2O3 dopant in as-grown Er:LiNbO3 crystals.

• 한국재료학회지
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• 제31권10호
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• pp.582-585
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• 2021

Y₂O₃:Eu_x (x = 0.005, 0.01, 0.02, 0.03, 0.05, 0.1 mol) phosphors are synthesized with different concentrations of Eu³⁺ ions by solvothermal method. The crystal structure, surface and optical properties of the Eu doped Y₂O₃ phosphors are investigated using X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL) and photoluminescence excitation (PLE) analyses. From X-ray diffraction (XRD) results, the crystal structure of the Eu doped Y₂O₃ phosphor is found to be cubic. The maximum emission spectra of the Eu doped Y₂O₃ phosphors are observed at 0.05 mol Eu³⁺ concentration. The photoluminescence of 615 nm in the Eu doped Y₂O₃ phosphors is associated with ⁵D₀ → ⁷F₂ transition of Eu³⁺ ions. The decrease in emission intensity of 0.1 mol Eu doped Y₂O₃ is interpreted by concentration quenching. The International Commission on Illumination (CIE) coordinates of 0.05 mol Eu doped Y₂O₃ phosphor are X = 0.6547, Y = 0.3374.

• The Korean Journal of Ceramics
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• 제1권2호
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• pp.86-90
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• 1995

Theoretical predictions for thermodynamically stable phases which formed when alkali(sodium and potassium) vapors reacted with alumina-chromia refractories under coal gasifying atmosphere were confirmed experimentally using a laboratory-scale coal gasifying reaction system and a commercial alumina-chromia refractory using SEM, XRD, and EDAX. Alkali concentration profiles in the refractory as a function of time were also determined. The results showed that the compounds that formed were $X_2O{\cdot}Al_2O_3, X_2O{\cdot}Cr_2O_3, X_2O{\cdot}5Al_2O_3, X_2O{\cdot}7Al_2O_3, X_2O{\cdot}11Al_2O_3(X=Na^+ \;or\; K^+)$, depending upon the alkali concentration and time of exposure at high temperatures. The presence of sulfur in gasifying atmospheres did not appear to affect the alkali reaction produces. Alkali pentration into the alumina-chromia refractory was deep and the formation of the $Na_2O{\cdot}Al_2O_3/K_2O{\cdot}Al_2O_3$ compunds resulted in the serious deformation of the refractory due to the large volume expansion at the reaction surface. The hot face of the alumina-chromia refractory in service under an alkali environment is prone to failure by alkali attack.

• 한국재료학회지
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• 제14권5호
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• pp.328-333
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• 2004

Transparent ZnO:Al conductor films for the optoelectronic devices were deposited by using the capacitively coupled DC magnetron sputtering method. The effect of Al doping concentration and discharge power on the electrical and optical properties of the films was studied. The film resistivity of $8.5${\times}$10^{-4}$ $\Omega$-cm was obtained at the discharge power of 40 W with the ZnO target doped with 2 wt% $Al_2$$_O3$. The transmittance of the 840 nm thick film was 91.7% in the visible waves. Increasing doping concentration of 3 wt% $Al_2$$O_3$ in ZnO target results in significant decrease of film resistivity, which may be due to the formation of $Al_2$$O_3$ particles in the as-deposited ZnO:Al film and the reduced ZnO grain sizes. Increasing DC power from 40 to 60 W increases deposition rate by more than 50%, but can induce high defect density in the film, resulting in higher film resistivity.

• 한국재료학회지
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• 제22권7호
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• pp.368-373
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• 2012

Glasses were prepared with compositions of $(13-x)BaO-80B2_O_3-7Li_2O{\cdot}xSm_2O_3$, BBLSx(x=0.5, 0.4, 0.3) by melting the starting materials of boron oxide(99.9%), lithium oxide(99.9%), barium carbon oxide(99.9%), and samarium oxide(99.9%) and then quenching the melt at $1350^{\circ}C$. This led to good-quality BBLSx(x=0.4, 0.3) and poor-quality BBLSx(x=0.5) glasses. The physical and structural properties of the BBLSx glasses were studied by means x-ray diffraction, scanning electron microscopy(SEM), differential scanning calorimetry(DSC), and dielectric spectroscopy. From the x-ray diffraction and SEM results, the quality of the BBLSx glasses significantly depends on the $Sm_2O_3$ concentration. The x-ray diffraction pattern showed that the crystallites in the BBLSx glasses after heat treatment at $700^{\circ}C$ may be $LiBaB_9O_{15}$. From the DSC results, the glass transition temperatures($T_g$), crystallization temperatures($T_c$), and the maximum temperatures of the crystallized($T_p$) BBLSx glasses all changed with the $Sm_2O_3$ concentration. According to the dielectric spectroscopy results, the values of the real dielectric constant and Tan ${\delta}$ of the BBLSx glasses depended on the $Sm_2O_3$ concentration. The values of the real dielectric constant and Tan ${\delta}$ were also shown to depend on the measuring temperature, possibly due to the ion migration in the bulk of the BBLSx glasses.

• 한국분말재료학회지
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• 제27권5호
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• pp.394-400
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• 2020

Molybdenum trioxide (MoO₃) is used in various applications including sensors, photocatalysts, and batteries owing to its excellent ionic conductivity and thermal properties. It can also be used as a precursor in the hydrogen reduction process to obtain molybdenum metals. Control of the parameters governing the MoO₃ synthesis process is extremely important because the size and shape of MoO₃ in the reduction process affect the shape, size, and crystallization of Mo metal. In this study, we fabricated MoO₃ nanoparticles using a solution combustion synthesis (SCS) method that utilizes an organic additive, thereby controlling their morphology. The nucleation behavior and particle morphology were confirmed using ultraviolet-visible spectroscopy (UV-vis) and field emission scanning electron microscopy (FE-SEM). The concentration of the precursor (ammonium heptamolybdate tetrahydrate) was adjusted to be 0.1, 0.2, and 0.4 M. Depending on this concentration, different nucleation rates were obtained, thereby resulting in different particle morphologies.

• 한국염색가공학회지
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• 제14권3호
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• pp.11-18
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• 2002

The preparations of deodorizing fibers using $\textrm{TiO}_2$ have been investigated. $\textrm{TiO}_2$ is known to be an excellent photocatalyst for the degradation of organic and inorganic contaminants in water. $\textrm{TiO}_2$ catalyst have been supported on the glass fiber by a dip-coating procedure. The resulting materials have been characterized by XRD and SEM. The immobilized catalysts were tested in the photocatalytic degradation of $\textrm{NH}_3$, $\textrm{CH}_3\textrm{SH}$ and $\textrm{CH}_3\textrm{CHO}$. The deodorant activity(D.A.) of these deodorizing fibers was measured by chromogenic gas detector tubes. The efficient deodorant activity results have been achieved through the increase of $\textrm{TiO}_2$ sol concentration.