• Title/Summary/Keyword: $OH^{\ast}$ Chemiluminescence

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Detailed Local Chemiluminescence Measurement (OH*, CH* and C2*) and Nitrogen Oxides Emissions in Laminar Partially Premixed CH4/Air Flames (메탄/공기 층류 부분예혼합화염의 상세 라디칼(OH*, CH* 그리고 C2*) 정보와 배기매출물에 관한 실험적 연구)

  • Jeong Yong Ki;Oh Jeong Seog;Jeon Chung Hwan;Chang Young June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.263-270
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $0.79{\sim}{\infty}$, on NOx emissions and chemiluminescence of excited $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ radicals in laminar partially premixed flames. the signal from the electronically excited state of $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, which are processed to the intensity ratio ($C_2^{\ast}/CH^{\ast},\;C_2^{\ast}/OH^{\ast},\;and\;CH^{\ast}/OH^{\ast}$) to reveal the correlation with local equivalence ratio. And measurements of NOx emission were made to investigate the relationship between visible flame appearance, chemiluminescence, and EINOX. The results demonstrated that (1) the flames at ${\phi}<1.59$ exhibited classical double flame structure, at ${\phi}>4.76$, the flames exhibited diffusion flame structure, and the intermediate flames at $1.59<{\phi}<4.76$ was a merged flame, (2) the $OH^{\ast}$ peak was located inside the $CH^{\ast}\;and\;C_2^{\ast}$ radical for all measured conditions and the emission intensity ratio of $C_2^{\ast}/CH^{\ast}\;and\;C_2^{\ast}/OH^{\ast}$ were identified as good marker for local equivalence ratio over a range of ${\phi}=0.79{\sim}1.2\;and\;CH^{\ast}/OH^{\ast}\;is\;0.79<{\phi}<1.9$. However, it was difficult to predict the equivalence ratio in partially premixed flames using this system for ${\phi}>2.38$, (3) the minimum NOX emission index (EINOx) is obtained for a equivalence ratio of 3.19 in the intermediate flames.

Flame Structure and NOx Emission Characteristics in Laminar Partially Premixed $CH_4$/Air Flames;Effect of Premixing Degree (메탄/공기 층류 부분 예혼합화염의 화염구조와 NOx 배출특성;예혼합 인자의 영향)

  • Oh, Jeong-Seog;Jeong, Yong-Ki;Jeon, Chung-Hwan;Chang, Young-June
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.75-81
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    • 2003
  • In this paper, the study of effects of flow variables on flame structure and NOx emission concentration was performed in co-axial laminar partially premixed methane/air flames. the objectives are to reveal its effect as parameters were varied and to understand the correlation between flame structure and NOx emission characteristics in the reaction zone. equivalence ratio(${\Phi}$), fuel split degree(${\sigma}$), and mixing distance(x/D) were defined as a premixing degree and varied within $1.36{\sim}3.17$(equivalence ratio), $50{\sim}100$(fuel split degree), and $5{\sim}20$(mixing distance). the image of $OH{\ast}$ and $CH{\ast}$, and NOx concentration were obtained with an ICCD camera and a NOx analyzer. additionally the maximum intensity location of $OH{\ast}$ chemiluminescence and $CH{\ast}$ chemiluminescence were measured to compare each flame structures. In conclusion flame structure and NOx emission characteristics were changed from diffused to premixed flame when mixing degree was on the increase. the main effect on flame structure and NOx production was at first equivalence ratio(${\Phi}$), and next fuel split degree(${\sigma}$), and finally mixing distance(x/D).

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The Study on Flame Structure and NOx Emissions by Swirl Numbers and Fuel-Air Mixing Length in a Dump Combustor Gas Turbine (모형 가스터빈 연소기에서의 스월수와 혼합길이에 따른 화염구조와 NOx배출에 관한 실험적 연구)

  • Choi, Do-Wook;Kim, Gyu-Bo;Jeon, Chung-Hwan;Song, Ju-Hun;Chang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.11
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    • pp.849-857
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    • 2009
  • The experimental study was performed to investigate the effects of partial premixing, varying the equivalence ratio, mixing degree, swirl intensity, mixing length on the characteristics of flame structure and NOx emission. Experiments were conducted in a dump combustor at 1 bar using methane as fuel. Inlet air temperature was 570K. OH chemiluminescence images were acquired with an ICCD camera. As a result of the experimental investigation of characteristics of flame and NOx emission in partial premixed combustor, we can conclude the results as below. With the increase of swirl number, The flame length decreases and the flame width increases and it helps flame stabilization. It means that lean flammability limit is extended. With the increase of mixing of fuel-air length ratio, Flame goes to be stabilized and NOx emission and $OH^{\ast}$ intensity decrease. Through the comparison of preceding results, It is possible that the exhausted NOx emission from a gas turbine combustor will be able to predict through the $OH^{\ast}$ intensity.

An Experimental Investigation of the Characteristic of Radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and Pollutant Emission in Partially Premixed Swirling Methane-air Flames. (스월을 강화한 메탄/공기 부분 예혼합화염에서 자발광($OH^{\ast}$, $CH^{\ast}$, 그리고 $C_2^{\ast}$) 배출특성과 배기배출물에 관한 실험적 연구)

  • Ahn, Kyuong-Min;Jeong, Yong-Ki;Chang, Young-June;Jeon, Chung-Hwan
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.320-327
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $1.36{\sim}{\infty}$, and swirlers with swirl numbers of 0, 0.28, 0.64, and 1.32, on the characteristic of radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and pollutant emission in partially premixed swirling flames. The signal from the electronically excited state of $OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, and flow fields images were detected through a schlieren system. The results demonstrated that the flame height decreases and jet spreading angle increase with increasing a swirl number. The more momentum ratio and swirl number increase, the more decrease flame height, and the generation of sooting flame is promoted.

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An Experimental Study on the Measurement of Radicals in Flame for Real TIme Combustion Control (실시간 연소제어를 위한 화염 내 라디칼 계측기법 연구)

  • Kwon, Seung-Jin;Kim, Se-Won;Shin, Myung-Chul;Ryu, Tae-U;Kim, Yong-Mo
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.53-59
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    • 2006
  • This study is measurement of radicals in gas & light oil diffusion flame focused on burner exit. The goal of this study is to analyse the relationship between flame chemiluminescence($OH^{\ast}$, $CH^{\ast}$, $C_2^{\ast}$) intensities and flame conditions. The investigation performed turbulent diffusion flame of commercial burner in varying the excess air ratio from 1.0 to 1.8. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The effects of excess air ratio and NOx emission characteristics on the radical emission intensities were investigated experimentally.

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Laminar Lifted Methane Jet Flames in Co-flow Air

  • Sapkal, Narayan P.;Lee, Won June;Park, Jeong;Lee, Byeong Jun;Kwon, Oh Boong
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.83-86
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    • 2015
  • The Laminar lifted methane jet flames diluted with helium and nitrogen in co-flow air have been investigated experimentally. The chemiluminescence intensities of $OH^{\ast}$ and $CH_2O^{\ast}$ radicals and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera, monochromator and digital video camera. The product of $OH^{\ast}$ and $CH_2O^{\ast}$ is used as a excellent proxy of heat release rate. These methane jet flames could be lifted in buoyancy and jet dominated regimes despite the Schmidt number less than unity. Lifted flames were stabilized due to buoyancy induced convection in buoyancy-dominated regime. It was confirmed that increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration caused an increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime lifted flames were observed even for nozzle exit velocities much higher than stoichiometric laminar flame speed. An increase in radius of curvature in addition to the increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration stabilizes such lifted flames.

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Flame Structure and Light Emission Characteristics in Coaxial Laminar Partially Premixed $CH_{4}/Air$ Flames;Effect of Central Fuel Injection (이중동축 메탄/공기 층류 부분 예혼합화염에서의 화염구조와 자발광 배출 특성;안쪽관 연료주입의 영향)

  • Oh, Jeong-Seog;Jeong, Yong-Ki;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1116-1121
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    • 2004
  • In this study, the effect of central fuel injection on a coaxial laminar $CH_{4}/air$ flame was experimented at the defined premixing condition(${\Phi}=1.90$, ${\sigma}=50/75/100%$, x/D=10). The partial premixing parameter are the equivalence ratio that total fuel is fixed at 200cc/min, the fuel split degree which means the percentage of fuel entering the outer tube to the total amount, and the mixing distance indicating the nonreactant mixture's homogeneity between inner tube top and burner exit. The object is to investigate the flame structure and chemiluminescence characteristics of laminar partial premixed flame as changing mixing parameters. The radical signal was acquired from ICCD camera and PMT. Each intensity was compared with Abel inverted value for measuring the effect of background light on the peak signal location and the intensity at central preheat zone. The results show that the peak location of each radical was broaden as the fuel split degree increasing because the mixing quality was enhanced. and $OH^{\ast}$ is a good indicator for flame front between reaction and preheat zone. At last $CH_{2}^{\ast}$ has the same tendency with $CH^{\ast}$ but a thinner reaction zone than $CH^{\ast}$ due to a rapid decay on the burned gas side.

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Experimental Study on Combustion Instability Mechanism in a Lean Premixed Model Gas Turbine Combustor using OH Chemiluminescence Images (희박 예혼합 모형 가스터빈 연소기의 OH 자발광을 이용한 연소불안정성에 대한 실험적 연구)

  • Lee Jae Ho;Lee Jong Ho;Chang Young June;Jeon Chung Hwan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.259-264
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    • 2005
  • Measurements of heat release are very important for controling combustion instabilities, which are closely connected with combustion instabilities. $OH^{\ast}$ images were acquired through a ICCD in this study, which were in use as indicating index of the reacting region, global and local heat release rate in the lean premixed combustion. The objectives of this study are to see the effect of equivalence ratio on global heat release rate and local Rayleigh index distribution. The local Rayleigh index distribution was acquired by information from central section of flame. This information was from the line-of-sight images which were inverted by the Abel de-convolution. In each condition, the mean value of heat release increased exponentially with equivalence for a periodic time. Local Rayleigh index distribution cleary showed the region of amplifying or damping the combustion instability as the equivalence ratio increased. This could provide an insight on the region of combustion instability and the structure of flames on the equivalence ratio.

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Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor (희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Jong-Ho;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.356-361
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    • 2003
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence ($OH{\ast}$) image and its Abel inversion image at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure. Also NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ${\sim}341.8$ Hz, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between $OH{\ast}$ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

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